Cooling/heating method and device based on metal-organic frameworks and induced by pressure modifications
US-2024336821-A1 · Oct 10, 2024 · US
US2016084544A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016084544-A1 |
| Application number | US-201514860338-A |
| Country | US |
| Kind code | A1 |
| Filing date | Sep 21, 2015 |
| Priority date | Mar 27, 2012 |
| Publication date | Mar 24, 2016 |
| Grant date | — |
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A system for heating/cooling includes a plurality of thermoelastic modules. Each of the modules includes one or more structures formed of shape memory alloy, which converts from austenite to martensite upon application of a first stress and release latent heat from the conversion. During a first part of a heating/cooling cycle, a first module is stressed to cause conversion. The latent heat released from the first module is rejected to a heat sink while a second unstressed module absorbs heat from a heat source. During a second part of the heating/cooling cycle, the first and second modules are connected together to transfer heat therebetween for heat recovery. The cycle can be repeated indefinitely with the first and second modules alternating roles. Structures of the thermoelastic cooling material and specific applications thereof are also disclosed.
Opening claim text (preview).
1 . A heating/cooling system comprising: a plurality of modules, each of the modules comprising one or more structures formed of shape memory alloy, the shape memory alloy being constructed to convert from a first crystal phase to a second crystal phase upon application of a first stress and to release latent heat in converting from the first crystal phase to the second crystal phase; at least one loading device coupled to the modules and configured to apply a force thereto; a fluid network coupled to a heat source and a heat sink; at least one pump configured to move heat transfer fluid through the fluid network; and a controller operatively coupled to the fluid network, the at least one loading device, and the at least one pump and configured to control the heating/cooling system such that: during a first part of a cycle, a first of the plurality of modules rejects heat to the heat sink while a second of the plurality of modules absorbs heat from the heat source, and during a second part of the cycle, the first and second modules are connected together to transfer heat therebetween. 2 . The heating/cooling system of claim 1 , wherein the controller is further configured to control the heating/cooling system during the second part of the cycle to generate a thermal wave temperature profile in a portion of the fluid network connecting the first and second modules together such that a temperature difference between each module and the heat transfer fluid entering the respective module is minimized throughout said second part of the cycle. 3 . The heating/cooling system of claim 2 , wherein the controller is configured to control the heating/cooling system during the second part of the cycle such that a non-dimensional heat recovery duration, t*, is greater than 1, and t* is given by a ratio of a duration of the second part of the cycle (t HR ) to a time for any particle in the fluid network to travel a distance equal to a length of either of the first or second modules and a conduit of the fluid network connecting the first and second modules together (t travel ). 4 . The heating/cooling system of claim 3 , wherein the controller is configured to control the heating/cooling system such that the non-dimensional heat recovery duration, t*, is approximately 1.25. 5 . The heating/cooling system of claim 2 , wherein the controller is configured to control the heating/cooling system during the second part of the cycle such that a non-dimensional length, l*, is less than 1, and l* is given by a ratio of time for any particle in the fluid network to travel through either the first or second modules to a time for the particle to travel a distance equal to a length of either of the first or second modules and a conduit of the fluid network connecting the first and second modules together (t travel ). 6 . The heating/cooling system of claim 5 , wherein the controller is configured to control the heating/cooling system such that the non-dimensional length, l*, is between 0.05 and 0.3. 7 . The heating/cooling system of claim 2 , wherein the controller is configured to control the heating/cooling system during the second part of the cycle such that a velocity for the heat transfer fluid in the fluid network is less than 0.1 m/s. 8 . The heating/cooling system of claim 2 , wherein the portion of the fluid network connecting the first and second modules together comprises a first conduit connecting an outlet of the first module to an inlet of the second module and a second conduit connecting an inlet of the first module to an outlet of the second module, and the first and second conduits have about the same length, diameter, and wall thickness and are formed of the same material. 9 . The heating/cooling system of claim 1 , wherein the loading device and the first and second modules are constructed such that force unloaded from one of the first and second modules is recovered by the loading device in applying force to the other of the first and second modules. 10 . The heating/cooling system of claim 1 , wherein each module comprises a holder supporting the one or more structures of shape memory alloy therein and an insulating material disposed between the one or more structures and an interior wall of the holder. 11 . The heating/cooling system of claim 10 , wherein the insulating material is separate from the holder or applied as a film to the interior wall of the holder. 12 . The heating/cooling system of claim 1 , wherein the at least one loading device comprises a loading head for each module, each loading head disposed at an end of the respective holder and configured to deliver the force to the one or more structures within the holder, each loading head further comprising one or more conduits connecting the one or more structures to the fluid network. 13 . The heating/cooling system of claim 12 , wherein insulating material is disposed between inner walls of the one or more conduits and fluid flowing to the one or more structures. 14 . The heating/cooling system of claim 13 , wherein the insulating material comprises tubes inserted into said conduits and/or a film applied to inner walls of the conduits. 15 . The heating/cooling system of claim 1 , wherein the at least one loading device comprises a loading head for each module, each loading head disposed at an end of the respective holder and configured to deliver the force to the one or more structures within the holder, the respective holder including inlet and outlet ports along one or more sidewalls thereof, the ports connecting the one or more structures to the fluid network. 16 . The heating/cooling system of claim 1 , wherein the one or more structures comprises a plurality of tubes, each tube having an interior volume through which the heat transfer fluid can flow. 17 . The heating/cooling system of claim 16 , wherein: each of the plurality of tubes has at least one additional tube disposed in the interior volume thereof, each additional tube being formed of the shape memory alloy and having a respective interior volume sealed such that heat transfer fluid does not flow therethrough; or each of the plurality of tubes has at least one solid rod disposed in the interior volume thereof, each solid rod being formed of the shape memory alloy. 18 . The heating/cooling system of claim 1 , wherein the one or more structures comprises a lattice of hollow tubes, each hollow tube having an interior volume through which the heat transfer fluid can flow, the lattice having spaces between the hollow tubes such that a second fluid can flow through the lattice without passing through said interior volumes. 19 . The heating/cooling system of claim 1 , wherein each of the first and second modules has been pre-stressed prior to application of any force by the at least one loading device. 20 . The heating/cooling system of claim 1 , wherein the plurality of modules comprises more than two modules connected together in a cascade arrangement. 21 - 39 . (canceled)
Solid materials, e.g. powdery or granular · CPC title
by evaporation of water in the air · CPC title
Machines, plants or systems, with a single mode of operation not covered by groups F25B1/00 - F25B21/00, e.g. using selective radiation effect · CPC title
for pumping or compressing fluids · CPC title
characterised by the activation arrangement · CPC title
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