Composite separation membrane including graphene oxide coating layer and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-2016074814-A1
Application number	US-201314786757-A
Country	US
Kind code	A1
Filing date	Sep 27, 2013
Priority date	Apr 24, 2013
Publication date	Mar 17, 2016
Grant date	—

Abstract

The present invention relates to a composite separation membrane including a graphene oxide coating layer. The composite separation membrane of the present invention has both high carbon dioxide permeability and high selectivity for carbon dioxide over nitrogen, hydrogen or methane gas, is free of surface defects, and exhibits remarkably increased selectivity for carbon dioxide over other gases (hydrogen, nitrogen, methane, etc.) without any change in carbon dioxide permeability, particularly even when exposed to water. Due to these advantages, the composite separation membrane of the present invention can be applied to industrial fields involving carbon dioxide separation and recovery processes. The present invention also relates to a method for manufacturing the composite separation membrane.

First claim

1 . A composite separation membrane comprising a porous polymer support and a graphene oxide coating layer formed on the porous polymer support.

2 . The composite separation membrane according to claim 1 , wherein the coating layer consists of a plurality of graphene oxide layers, each of which comprises pores through which gases pass.

3 . The composite separation membrane according to claim 2 , wherein the pores present in one of the graphene oxide layers are spaced at an average distance of 0.5 to 1.0 nm apart from the pores present in the graphene oxide layers formed on one or both sides of the one of the graphene oxide layers.

4 . The composite separation membrane according to claim 2 , wherein the pores have an average diameter of 0.5 to 1.0 nm.

5 . The composite separation membrane according to claim 1 , wherein the porous polymer support is made of a polymer selected from the group consisting of polysulfone, polyethersulfone, polyimide, polyetherimide, polyimide, polyacrylonitrile, cellulose acetate, cellulose triacetate, and polyvinylidene fluoride.

6 . The composite separation membrane according to claim 5 , wherein the porous polymer support comprises pores whose size is from 10 nm to 100 nm.

7 . The composite separation membrane according to claim 1 , wherein the graphene oxide has a size in the range of 0.1 μm to 5 μm.

8 . The composite separation membrane according to claim 1 , wherein the graphene oxide is functionalized graphene oxide prepared by the conversion of the hydroxyl, carboxyl, carbonyl or epoxy groups present in the graphene oxide to ester, ether, amide or amino groups.

9 . The composite separation membrane according to claim 1 , wherein the graphene oxide coating layer has a thickness of 3 to 20 nm.

10 . A method for manufacturing a composite separation membrane, comprising: 1) dispersing graphene oxide in distilled water to obtain a dispersion; and 2) coating the dispersion on a porous polymer support to form a coating layer.

11 . The method according to claim 10 , wherein the concentration of the graphene oxide in the dispersion obtained in step 1) is from 0.5 to 1.5 g/L.

12 . The method according to claim 10 , wherein the coating is performed by spin coating.

13 . The method according to claim 10 , wherein the coating layer formed in step 2) has a thickness of 3 to 20 nm.

14 . The method according to claim 10 , further comprising subjecting the dispersion to ultrasonic disruption after step 1).

15 . The method according to claim 10 , wherein the porous polymer support is made of a polymer selected from the group consisting of polysulfone, polyethersulfone, polyimide, polyetherimide, polyamide, polyacrylonitrile, cellulose acetate, cellulose triacetate, and polyvinylidene fluoride.

16 . The method according to claim 15 , wherein the porous polymer support comprises pores whose size is from 10 nm to 100 nm.

17 . The method according to claim 10 , wherein the graphene oxide has a size in the range of 0.1 μm to 5 μm.

18 . The method according to claim 10 , wherein the graphene oxide is functionalized graphene oxide prepared by the conversion of the hydroxyl, carboxyl, carbonyl or epoxy groups present in the graphene oxide to ester, ether, amide or amino groups.

19 . A membrane for water treatment comprising the composite separation membrane according to claim 1 .

20 . A memory device comprising the composite separation membrane according to claim 1 .

21 . An electrode material comprising the composite separation membrane according to claim 1 .

Assignees

• Iucf Hyu

Inventors

• Park Ho Bum
• Kim Hyo Won
• Yoon Hee Wook
• Yoo Byung Min

Classifications

• B01D2325/04

  Characteristic thickness · CPC title

• B01D53/228 Primary

  characterised by specific membranes · CPC title

• B01D2325/02

  Details relating to pores or porosity of the membranes · CPC title

• B01D71/024 Primary

  Oxides · CPC title

• B01D69/12

  Composite membranes; Ultra-thin membranes · CPC title