Photochemical reaction system
US-2015252483-A1 · Sep 10, 2015 · US
US2016032470A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2016032470-A1 |
| Application number | US-201414449771-A |
| Country | US |
| Kind code | A1 |
| Filing date | Aug 1, 2014 |
| Priority date | Aug 1, 2014 |
| Publication date | Feb 4, 2016 |
| Grant date | — |
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The embodiments described herein pertain generally to an amalgam electrode, and a producing method of the amalgam electrode, and an electrochemical reduction method of carbon dioxide using the amalgam electrode.
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1 . An amalgam electrode comprising a member selected from the group consisting of Hg, Ag, Sn, Cu, Zn and combinations thereof. 2 . The amalgam electrode of claim 1 , wherein the amalgam electrode includes Hg of from 35 wt % to 55 wt %, Ag of from 14 wt % to 34 wt %, Sn of from 7 wt % to 17 wt %, and Cu of from 4 wt % to 24 wt %. 3 . The amalgam electrode of claim 1 , wherein the amalgam electrode is a rod or planar shape. 4 . The amalgam electrode of claim 1 , wherein the amalgam electrode further comprises a copper or tin electrode on one side thereof. 5 . A producing method of an amalgam electrode, comprising: forming an electrode by using amalgam including a member selected from the group consisting of Hg, Ag, Sn, Cu, Zn and combinations thereof. 6 . The producing method of an amalgam electrode of claim 5 , further comprising: forming a copper or tin electrode on one side of the amalgam electrode. 7 . An electrochemical reduction method of carbon dioxide, by using the amalgam electrode of claim 1 . 8 . The electrochemical reduction method of carbon dioxide of claim 7 , supplying a solution containing carbon dioxide into a reduction electrode unit in an electrochemical reactor; and applying current to a working electrode including the amalgam electrode and a counter electrode to reduce carbon dioxide. 9 . The electrochemical reduction method of carbon dioxide of claim 8 , wherein the solution includes a member selected from the group consisting of KHCO 3 , NaHCO 3 , K 2 SO 4 , NaCl, KCl and combinations thereof. 10 . The electrochemical reduction method of claim 8 , wherein the current ranges from 2 mA/cm 2 to 50 mA/cm 2 .
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