Integrated Calcium Looping Combined Cycle for Sour Gas Applications

Patent metadata

Field	Value
Publication number	US-2016017798-A1
Application number	US-201414334047-A
Country	US
Kind code	A1
Filing date	Jul 17, 2014
Priority date	Jul 17, 2014
Publication date	Jan 21, 2016
Grant date	—

Abstract

A chemical looping combustion (CLC) process for sour gas combustion is integrated with a gas turbine combined cycle and a steam generation unit, and is configured to provide in-situ removal of H 2 S from the sour gas fuel by reacting the H 2 S with a oxygen carrier at a location within the fuel reactor of the CLC unit. The process is also configured such that oxygen-rich exhaust gases from the gas turbine combined cycle is used to feed the air reactor of the CLC unit and re-oxidize oxygen carriers for recirculation in the CLC unit.

First claim

What is claimed is:

1 . A process for utility and power generation using sour gas fuel integrating a chemical looping process, a gas turbine, and a steam generation unit, comprising the steps of:
injecting an oxygen carrier and a sour gas fuel into a fuel reactor; reforming the sour gas fuel in the fuel reactor to produce syngas and a reduced oxygen carrier; separating the reduced oxygen carrier from the syngas; cooling the syngas by passing the syngas through the steam generation unit; combusting the cooled syngas in a combustion chamber of the gas turbine whereby exhaust gases are produced; cooling at least a first portion of the exhaust gases by passing the first portion of the exhaust gases through the steam generation unit; and injecting the cooled first portion of the exhaust gases into an air reactor to oxidize the reduced oxygen carrier which was separated from the syngas resulting in formation of oxygen-depleted exhaust gases.

2 . The process of claim 1 , wherein the fuel reactor is one of a turbulent bed, fluidized bed, and circulating fluidized bed.

3 . The process of claim 1 , wherein the air reactor is one of a turbulent bed, fluidized bed, and circulating fluidized bed.

4 . The process of claim 1 , wherein the cooled syngas is compressed prior to delivery to the combustion chamber of the gas turbine for combustion thereof.

5 . The process of claim 4 , wherein compressed air is injected into the combustion chamber of the gas turbine for combustion of the cooled syngas.

6 . The process of claim 1 , wherein a second portion of the exhaust gases is passed through the steam generation unit resulting in generation of steam, wherein the first and second portions of exhaust gases are kept separated within the steam generation unit.

7 . The process of claim 1 , wherein the gas turbine comprises a multistage turbine, wherein the first portion of the exhaust gases comprises an oxygen-rich gas that is extracted from a medium pressure stage of the multistage turbine.

8 . The process of claim 1 , wherein the gas turbine comprises a multistage turbine, wherein the first portion of the exhaust gases comprises an oxygen-rich gas that is extracted from the last stage of the multistage turbine.

9 . The process of claim 8 , further including the step of compressing the extracted first portion of exhaust gases to reach the injection pressure of the air reactor.

10 . The process of claim 8 , further including the step of compressing the oxygen-depleted exhaust gases.

11 . The process of claim 1 , further including the step of injecting an air stream into the air reactor to oxidize the reduced oxygen carrier.

12 . The process of claim 1 , wherein the reduced oxygen carrier contains sulfur.

13 . The process of claim 12 , wherein the reduced oxygen carrier comprises CaS.

14 . The process of claim 1 , further including the step of transporting the oxidized oxygen carrier from the air reactor to the fuel reactor into which the oxidized oxygen carrier is injected.

15 . The process of claim 14 , further including the step of separating the oxidized oxygen carrier from the oxygen-depleted exhaust gases and delivering at least a portion of the oxidized oxygen carrier to the fuel reactor.

16 . The process of claim 1 , wherein the cooled first portion of the exhaust gases enters an inlet of the air reactor to entrain and oxidize the reduced oxygen carrier.

17 . The process of claim 16 , wherein the reduced oxygen carrier comprises CaS and the oxidized oxygen carrier comprises CaSO 4 .

18 . The process of claim 5 , wherein the air compressor comprises a multistage compressor with intercooling, the intercooler being part of a steam generation block.

19 . The process of claim 1 , wherein the exhaust gases produced by the combustion in the combustion chamber of the gas turbine is expanded due to a multistage construction of the gas turbine.

20 . The process of claim 1 , wherein the steam generation unit includes a stack through which cooled exhaust gases passes after exchanging heat in the steam generation unit.

21 . The process of claim 1 , wherein the cooled exhaust gases from the gas turbine combustion chamber comprises the only means for oxidizing the reduced oxygen carrier that is injected into the air reactor.

22 . A utility and power generation system that utilizes a chemical looping combustion process comprising:
a source of sour gas fuel; a fuel reactor in which the sour gas fuel and an oxygen carrier are introduced, the sour gas is reformed to form a product stream, and the oxygen carrier is reduced; a steam generation unit that is in fluid communication with the fuel reactor and receives the product stream through a first conduit, the steam generation unit being configured to act as a heat transfer unit that cools the product stream; a gas turbine that is in fluid communication with the steam generation unit and receives the cooled product stream through a second conduit, the gas turbine including a combustion chamber for combusting the cooled product stream to generate exhaust gases; a third conduit that fluidly connects the gas turbine to the steam generation unit such that at least a first portion of the exhaust gases is transported from the gas turbine to the steam generation unit which acts to cool the exhaust gases; an air reactor that is fluidly connected to the gas turbine by the third conduit and a fourth conduit such that the cooled exhaust gases are delivered to the air reactor, the fourth conduit being fluidly connected between the steam generation unit and the air reactor, the air reactor being in fluid communication with the fuel reactor such that the reduced oxygen carrier is received from the fuel reactor and is oxidized by the cooled exhaust gases from the combustion chamber of the gas turbine resulting in formation of oxygen-depleted exhaust gases; and wherein the air reactor is fluidly connected to the steam generation unit which acts to cool the oxygen-depleted exhaust gases exiting the air reactor.

23 . The system of claim 22 , further including a gas compressor for compressing the cooled product stream which comprises syngas prior to delivery to the combustion chamber of the gas turbine for combustion thereof.

24 . The system of claim 22 , further including a fifth conduit that fluidly connects the gas turbine to the steam generation unit such that a second portion of the exhaust gases is transported from the combustion chamber to the steam generation unit which acts to cool the second portion of the exhaust gases prior to being vented from the steam generation unit.

25 . The system of claim 24 , wherein the first and second portions of exhaust gases are maintained separate from one another as they flow through the steam generation unit.

26 . The system of claim 22 , wherein the gas turbine comprises a multistage turbine, wherein the exhaust gases comprises an oxygen-rich gas that is extracted from a medium pressure stage of the multistage turbine.

27 . The system of claim 22 , wherein the reduced oxygen carrier contains sulfur.

28 . The system of claim 27 , wherein the reduced oxygen carrier comprises CaS.

29 . The system of claim 22 , further including a fifth conduit fluidly connecting the air reactor to the fuel reactor for transporting the oxidized oxyge

Assignees

• Saudi Arabian Oil Co

Inventors

• Younes Mourad
• Hoteit Ali
• Jamal Aqil

Classifications

• F23C13/06

  in which non-catalytic combustion takes place in addition to catalytic combustion, e.g. downstream of a catalytic element · CPC title

• C01B2203/1235

  Hydrocarbons · CPC title

• F02C3/22 Primary

  the fuel or oxidant being gaseous at standard temperature and pressure (F02C3/28 takes precedence) · CPC title

• F02C3/34

  with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle · CPC title

• C01B2203/0211

  containing a non-catalytic reforming step · CPC title