Actinic-radiation-curable resin composition, primer contianing the same, and shaped article

Patent metadata

Field	Value
Publication number	US-2016017177-A1
Application number	US-201414772206-A
Country	US
Kind code	A1
Filing date	Jul 29, 2014
Priority date	Aug 7, 2013
Publication date	Jan 21, 2016
Grant date	—

Abstract

Provided are an actinic-radiation-curable resin composition that has high storage stability and that combines high levels of ease of application and adhesion to various substrates and high levels of coating appearance and heat resistance after curing, an actinic-radiation-curable primer for metallization that contains such an actinic-radiation-curable resin composition, and a shaped article including an undercoat layer for metallization that has good adhesion to various substrates. Specifically, an actinic-radiation-curable resin composition is used that contains an oil-modified alkyd resin (A) and a (meth)acryloyl-containing compound (B). The oil-modified alkyd resin (A) is prepared using two or more oils (al) having iodine values of 100 or more and has an oil length of 30 to 70 and a mass average molecular weight of 30,000 to 200,000.

First claim

1 - 10 . (canceled)

11 . An actinic-radiation-curable resin composition comprising an oil-modified alkyd resin (A) and a (meth)acryloyl-containing compound (B), the oil-modified alkyd resin (A) being prepared using two or more oils (a1) having iodine values of 100 or more, a polyol (a2) having an ether linkage in a molecule thereof, and a polybasic acid (a3) having a cyclic unsaturated group in a molecule thereof,
the oil-modified alkyd resin (A) having an oil length of 30 to 70 and a mass average molecular weight of 30,000 to 200,000.

12 . The actinic-radiation-curable resin composition according to claim 11 , wherein the oil-modified alkyd resin (A) has a hydroxyl value of 60 to 140.

13 . The actinic-radiation-curable resin composition according to claim 11 , wherein the oils (a1) having iodine values of 100 or more are selected from the group consisting of linseed oil, soybean oil, safflower oil, and tall oil.

14 . The actinic-radiation-curable resin composition according to claim 11 , wherein the polyol (a2) having an ether linkage in a molecule thereof comprises a polyalkylene glycol.

15 . The actinic-radiation-curable resin composition according to claim 11 , wherein the (meth)acryloyl-containing compound (B) is at least one compound selected from the group consisting of (meth)acrylate monomers, urethane (meth)acrylates, epoxy (meth)acrylates, polyester (meth)acrylates, and acrylic acrylates containing acryloyl groups pendant to an acrylic copolymer.

16 . The actinic-radiation-curable resin composition according to claim 11 wherein the oil-modified alkyd resin (A) and the (meth)acryloyl-containing compound (B) are present in a mass ratio ((A)/(B)) of 20/80 to 80/20.

17 . The actinic-radiation-curable resin composition according to claim 11 , further comprising a photoinitiator (C).

18 . An actinic-radiation-curable primer for metallization comprising the actinic-radiation-curable resin composition according to claim 11 .

19 . A shaped article comprising an undercoat layer comprising the primer according to claim 18 .

Assignees

• Dainippon Ink & Chemicals

Inventors

• Umino Akio
• Uno Seiichi

Classifications

• C09D167/08 Primary

  Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids · CPC title

• C08G63/48

  by unsaturated higher fatty oils or their acids; by resin acids · CPC title

• C08F222/103

  of trialcohols, e.g. trimethylolpropane tri(meth)acrylate · CPC title

• C08F2/48

  by ultraviolet or visible light · CPC title

• C08F220/343

  in the form of urethane links · CPC title