Fungicidal 3--heterocycle derivatives

Patent metadata

Field	Value
Publication number	US-2016016944-A1
Application number	US-201414771973-A
Country	US
Kind code	A1
Filing date	Mar 6, 2014
Priority date	Mar 7, 2013
Publication date	Jan 21, 2016
Grant date	—

Abstract

The present invention provides 3-{phenyl[(heterocyclylmethoxy)imino]methyl}-heterocyclyl derivatives of formula (I)

Wherein A, X 1 to X 3 , Y 1 to Y 5 represent various substituents.

First claim

1 . A compound of formula (I)

wherein
X 1 represents a hydrogen atom, a formyl group, substituted or non-substituted C 1 -C 8 -alkyl, substituted or non-substituted C 3 -C 8 -cycloalkyl, a substituted or non-substituted C 2 -C 8 -alkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, or substituted or non-substituted C 1 -C 8 -alkylcarbonyl;
X 2 and X 3 independently represents O, S, C═O, C═S, C═NR, S(═O), SO 2 , or S(═O)(═NR), provided that when X 2 represents O, X 3 cannot represent C═O and when X 2 represents C═O, X 3 cannot represent O
wherein R represents a cyano group, a nitro group, substituted or unsubstituted C 1 -C 8 -alkyl, substituted or unsubstituted aryl, or substituted or unsubstituted C 1 -C 8 -alkylsulfonyl;
A is selected in the list consisting of A 1 to A 27 :

wherein
Z 1 represents a hydrogen atom, a halogen atom, a nitro group, an amino group, an hydroxyamino group, a carboxylic acid, a hydroxy group, a cyano group, a sulfenyl group, a formyl group, a substituted or non-substituted carbaldehyde O—(C 1 -C 8 -alkyl)oxime, a formyloxy group, a carbamoyl group, a N-hydroxycarbamoyl group, sulfenylthioylamino, a pentafluoro-λ 6 -sulfenyl group, substituted or non-substituted C 1 -C 8 -alkoxyamino group, substituted or non-substituted N—C 1 -C 8 -alkyl-(C 1 -C 8 -alkoxy)-amino group, substituted or non-substituted (C 1 -C 8 -alkylamino)-amino group, substituted or non-substituted N—C 1 -C 8 -alkyl-(C 1 -C 8 -alkylamino)-amino group, a substituted or non-substituted (hydroxyimino)-C 1 -C 6 -alkyl group, substituted or non-substituted C 1 -C 8 -alkyl, substituted or non-substituted C 3 -C 8 -cycloalkyl, substituted or non-substituted C 2 -C 8 -alkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, substituted or non-substituted aryl-C 2 -C 8 -alkynyl, substituted or non-substituted C 3 -C 8 -cycloalkyl-C 2 -C 8 -alkynyl, substituted or non-substituted C 1 -C 8 -alkoxy, substituted or non-substituted C 2 -C 8 -alkenyloxy, substituted or non-substituted C 3 -C 8 -alkynyloxy, substituted or non-substituted C 1 -C 8 -alkylcarbonyl, substituted or non-substituted N—(C 1 -C 8 -alkoxy)-C 1 -C 8 -alkanimidoyl, substituted or non-substituted N—C 1 -C 8 -alkyl-carbamoyl, substituted or non-substituted N,N′-di-C 1 -C 8 -alkyl-carbamoyl, substituted or non-substituted N—C 1 -C 8 -alkyloxycarbamoyl, substituted or non-substituted C 1 -C 8 -alkoxycarbamoyl, substituted or non-substituted N—C 1 -C 8 -alkyl-C 1 -C 8 -alkoxycarbamoyl, substituted or non-substituted C 1 -C 8 -alkoxycarbonyl, substituted or non-substituted C 1 -C 8 -alkylcarbonyloxy, substituted or non-substituted N—C 1 -C 8 -alkylaminocarbonyloxy, substituted or non-substituted N,N′-di-C 1 -C 8 -alkylaminocarbonyloxy, substituted or non-substituted N—C 1 -C 8 -alkylcarbamothioyl, substituted or non-substituted N,N′-di-C 1 -C 8 -alkylcarbamothioyl, substituted or non-substituted N—C 1 -C 8 -alkyloxycarbamothioyl, substituted or non-substituted C 1 -C 8 -alkoxycarbamothioyl, substituted or non-substituted N—C 1 -C 8 -alkyl-C 1 -C 8 -alkoxycarbamothioyl, substituted or non-substituted (C 1 -C 8 -alkyl-carbamothioyl)-oxy, substituted or non-substituted substituted or non-substituted (di-C 1 -C 8 -alkyl-carbamothioyl)-oxy, substituted or non-substituted C 1 -C 8 -alkylsulfenyl, substituted or non-substituted C 1 -C 8 -halogenoalkylsulfenyl having 1 to 5 halogen atoms, substituted or non-substituted C 1 -C 8 -alkylsulfinyl, substituted or non-substituted C 1 -C 8 -alkylsulfonyl, substituted or non-substituted C 1 -C 8 -alkylaminosulfamoyl, substituted or non-substituted (C 1 -C 6 -alkoxyimino)-C 1 -C 6 -alkyl, substituted or non-substituted (C 1 -C 6 -alkenyloxyimino)-C 1 -C 6 -alkyl, substituted or non-substituted (C 1 -C 6 -alkynyloxyimino)-C 1 -C 6 -alkyl, substituted or non-substituted (benzyloxyimino)-C 1 -C 6 -alkyl, substituted or non-substituted phenoxy, substituted or non-substituted phenylsulfenyl, substituted or non-substituted aryl, substituted or non-substituted tri(C 1 -C 8 -alkyl)-silyloxy, substituted or non-substituted C 1 -C 8 -alkylsulfenylamino, substituted or non-substituted C 1 -C 8 -alkylsulfonylamino, substituted or non-substituted C 1 -C 8 -alkoxysulfonylamino, substituted or non-substituted tri(C 1 -C 8 -alkyl)-silyl, substituted or non-substituted (C 1 -C 6 -alkylideneamino)oxy, substituted or non-substituted (C 1 -C 6 -alkenylideneamino)oxy, substituted or non-substituted (C 1 -C 6 -alkynylideneamino)oxy, substituted or non-substituted (benzylideneamino)oxy, substituted or non-substituted (N-hydroxy-C 1 -C 6 -alkanimidoyl)amino, substituted or non-substituted (N—C 1 -C 6 -alkoxy-C 1 -C 6 -alkanimidoyl)amino, substituted or non-substituted C 1 -C 8 -alkylamino, substituted or non-substituted C 3 -C 10 -cycloalkylamino, substituted or non-substituted C 3 -C 10 -cycloalkenylamino, substituted or non-substituted C 5 -C 12 -fused bicycloalkylamino, substituted or non-substituted C 5 -C 12 -fused bicycloalkenylamino, substituted or non-substituted di-C 1 -C 8 -alkylamino, substituted or non-substituted phenylamino, substituted or non-substituted heterocyclylamino, substituted or non-substituted C 3 -C 10 -cycloalkyl-C 1 -C 8 -alkylamino, substituted or non-substituted aryl-C 1 -C 8 -alkylamino, substituted or non-substituted C 1 -C 8 -alkoxy-C 1 -C 8 -alkylamino, or a group of formula QC(═U)NR a —
wherein:
Q represents a hydrogen atom, substituted or non-substituted C 1 -C 8 -alkyl, substituted or non-substituted C 3 -C 8 -cycloalkyl, a substituted or non-substituted C 2 -C 8 -alkenyl, substituted or non-substituted C 3 -C 8 -cycloalkenyl, substituted or non-substituted C 2 -C 8 -alkynyl, substituted or non-substituted C 1 -C 8 -alkoxy, substituted or non-substituted C 2 -C 8 -alkenyloxy, substituted or non-substituted C 2 -C 8 -alkynyloxy, substituted or non-substituted C 1 -C 8 -alkylamino, substituted or non-substituted C 1 -C 8 -alkylsulfenyl, substituted or non-substituted C 2 -C 8 -alkenylsulfenyl, substituted or non-substituted C 2 -C 8 -alkynylsulfenyl, substituted or non-substituted arylsulfenyl, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted C 5 -C 12 -fused bicycloalkyl, substituted or non-substituted C 5 -C 12 -fused bicycloalkenyl, substituted or non-substituted C 5 -C 12 -benzofused carbocyclyl, substituted or non-substituted C 5 -C 12 -benzofused heterocyclyl, substituted or non-substituted cycloalkoxy; substituted or non-substituted cycloalkenyloxy, substituted or non-substituted aryloxy; substituted or non-substituted heterocyclyloxy, substituted or non-substituted C 5 -C 12 -fused bicycloalkoxy, substituted or non-substituted C 5 -C 12 -fused bicycloalkenyloxy, substituted or non-substituted C 5 -C 12 -benzofused carbocyclyloxy, substituted or non-substituted C 5 -C 12 -benzofused heterocyclyloxy, substituted or non-substituted C 3 -C 8 -cycloalkyl-C 1 -C 8 -alkyl, substituted or non-substituted C 3 -C 8 -cycloalkyl-C 1 -C 8 -alkoxy, substituted or non-substituted C 3 -C 8 -cycloalkoxy-C 1 -C 8 -alkyl, substituted or non-substituted heterocyclyl-C 1 -C 8 -alkyl, substituted or non-substituted aryl-C 1 -C 8 -alkyl, substituted or non-substituted aryl-C 1 -C 8 -alkoxy, substituted or non-substituted aryloxy-C 1 -C 8 -alkyl, substituted or non-substituted C 1 -C 8 -alkoxy-C 1 -C 8 -alkyl, substituted or non-substituted C 1 -C 8 -alkoxy-C 1 -C 8 -alkoxy, substituted or non-substituted aryloxy-C 1 -C 8 -alkoxy, substituted or non-substituted C 1 -C 8 -alkoxyaryloxy, su

Assignees

• Bayer Cropscience Ag

Inventors

• Rebstock Anne-Sophie
• Dubost Christophe
• Coqueron Pierre-Yves
• Maechling Simon
• Lachaise Helene
• Rinolfi Philipe
• Wachendorff-Neumann Ulrike

Classifications

• A01N47/20

  N-Aryl derivatives thereof · CPC title

• A01N47/40

  the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides · CPC title

• C07D417/12

  linked by a chain containing hetero atoms as chain links · CPC title

• A01N47/18

  containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring · CPC title

• A01N43/82

  five-membered rings with three ring hetero atoms · CPC title