Printable Composition for an Ionic Gel Separation Layer For Energy Storage Devices

Patent metadata

Field	Value
Publication number	US-2015357677-A1
Application number	US-201514831659-A
Country	US
Kind code	A1
Filing date	Aug 20, 2015
Priority date	Jul 16, 2012
Publication date	Dec 10, 2015
Grant date	—

Abstract

Representative embodiments provide a composition for printing a liquid or gel separator utilized to separate and space apart first and second conductors or electrodes of an energy storage device, such as a battery or a supercapacitor. A representative composition comprises a plurality of particles, typically having a size (in any dimension) between about 0.5 to about 50 microns; a first, ionic liquid electrolyte; and a polymer or polymeric precursor. In another representative embodiment, the plurality of particles comprise diatoms, diatomaceous frustules, and/or diatomaceous fragments or remains. Another representative embodiment further comprises a second electrolyte different from the first electrolyte; the plurality of particles are comprised of silicate glass; the first and second electrolytes comprise zinc tetrafluoroborate salt in 1-ethyl-3-methylimidalzolium tetrafluoroborate ionic liquid; and the polymer comprises polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”). Additional components, such as additional electrolytes and solvents, may also be included.

First claim

It is claimed:

1 . A composition for fabricating a liquid or gel separator for separating and spacing apart at least two conductors, the composition comprising:
a plurality of particles having a size between 5 microns to 15 microns and present in an amount between 40 to 60 percent of the total weight of the composition; an ionic liquid as a first electrolyte, the ionic liquid comprising 1-ethyl-3-methylimidazolium; a second electrolyte comprising zinc tetrafluoroborate salt, the first and second electrolytes present in an amount between 15 to 30 percent of the total weight of the composition; a polymer present in an amount between 0.5 to 10 percent of the total weight of the composition and comprising polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”); and N-methyl-2-pyrrolidinone present in an amount between 10 to 30 percent of the total weight of the composition.

2 . The composition of claim 1 , wherein the plurality of particles comprise silicate glass.

3 . The composition of claim 2 , wherein the plurality of particles are hollow.

4 . The composition of claim 1 , wherein the plurality of particles are solid.

5 . The composition of claim 1 , wherein the plurality of particles are selected from the group consisting of: diatoms, diatomaceous frustules, diatomaceous fragments, diatomaceous remains, and mixtures thereof.

6 . The composition of claim 1 , wherein the first electrolyte further comprises one or more ionic liquid cations selected from the group consisting of: butyltrimethylammonium, 1-ethyl-3-methylimidazolium, 1-butyl-3-methylimidazolium, 1-methyl-3-propylimidazolium, 1-hexyl-3-methylimidazolium, choline, ethylammonium, tributylmethylphosphonium, tributyl(tetradecyl)phosphonium, trihexyl(tetradecyl)phosphonium, 1-ethyl-2,3-methylimidazolium, 1-butyl-1-methylpiperidinium, diethylmethylsulfonium, 1-methyl-3-propylimidazolium, 1-methyl-1-propylpiperidinium, 1-butyl-2-methylpyridinium, 1-butyl-4-methylpyridinium, 1-butyl-1-methylpyrrolidinium, and mixtures thereof.

7 . The composition of claim 1 , wherein the first electrolyte further comprises one or more ionic liquid anions selected from the group consisting of: tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, hexafluorophosphate, tetrafluoroborate, ethyl sulfate, methyl sulfate, dimethyl phosphate, trifluoromethanesulfonate, methanesulfonate, triflate, tricyanomethanide, dibutylphosphate, bis(trifluoromethylsulfonyl)imide, bis-2,4,4-(trimethylpentyl) phosphinate, iodide, chloride, bromide, nitrate, thiocyanate, and mixtures thereof.

8 . The composition of claim 1 , further comprising a third electrolyte different from the first and second electrolytes, the third electrolyte comprising one or more electrolytes selected from the group consisting of: potassium hydroxide, sodium hydroxide, ammonium hydroxide, lithium hydroxide, nickel hydroxide, cadmium hydroxide, magnesium hydroxide, sulfuric acid, hydrochloric acid, fluoroboric acid, ammonium chloride, zinc chloride, zinc bis(trifluoromethanesulfonyl)imide, aluminium chloride, chromium chloride, magnesium perchloride, barium chromate, lithium chromate, lithium-thyonyl chloride, lithium perchlorate, lithium bromide, lithium triflate, lithium hexafluorophosphate, lithium tetrafluoroborate, lithium bis-oxalato borate, lithium bis(trifluoromethanesulfonyl)imide, lithium bisoxalatoborate, lithium iodide, lithium tetrachloroaluminate, potassium carbonate, potassium fluoride, potassium borate, silver nitride, silver tetrafluoroborate; salts of bis(trifluoromethylsulfonyl)imide, tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, hexafluorophosphate, tetrafluoroborate, ethyl sulfate, dimethyl phosphate, trifluoromethanesulfonate, triflate, tricyanomethanide, dibutylphosphate; and mixtures thereof.

9 . A method of using the composition of claim 1 , the method comprising:
printing the composition to form a liquid or gel separator.

10 . A method of fabricating a liquid or gel separator for separating and spacing apart at least two conductors, the method comprising:
depositing a composition over a first conductor of the at least two conductors, the composition comprising: a plurality of particles having a size between 5 microns to 15 microns and present in an amount between 40 to 60 percent of the total weight of the composition; an ionic liquid as a first electrolyte, the ionic liquid comprising 1-ethyl-3-methylimidazolium; a second electrolyte comprising zinc tetrafluoroborate salt, the first and second electrolytes present in an amount between 15 to 30 percent of the total weight of the composition; a polymer present in an amount between 0.5 to 10 percent of the total weight of the composition and comprising polyvinyl alcohol (“PVA”) or polyvinylidene fluoride (“PVFD”); and N-methyl-2-pyrrolidinone present in an amount between 10 to 30 percent of the total weight of the composition.

11 . The method of claim 10 , wherein the step of depositing comprises printing the composition.

12 . The method of claim 10 , wherein the step of depositing further comprises arranging substantially all of the plurality of particles as a monolayer.

13 . The method of claim 10 , wherein the plurality of particles comprise silicate glass.

14 . The method of claim 13 , wherein the plurality of silicate glass particles are less than 10 microns in any dimension.

15 . The method of claim 13 , wherein the plurality of silicate glass particles have a size of 7 microns, plus or minus 2 microns, in any dimension.

16 . The method of claim 10 , wherein the plurality of particles are hollow.

17 . The method of claim 10 , wherein the plurality of particles are selected from the group consisting of: diatoms, diatomaceous frustules, diatomaceous fragments, diatomaceous remains, and mixtures thereof.

18 . The method of claim 10 , wherein the first electrolyte of the composition further comprises one or more ionic liquid cations selected from the group consisting of: butyltrimethylammonium, 1-ethyl-3-methylimidazolium, 1-butyl-3-methylimidazolium, 1-methyl-3-propylimidazolium, 1-hexyl-3-methylimidazolium, choline, ethylammonium, tributylmethylphosphonium, tributyl(tetradecyl)phosphonium, trihexyl(tetradecyl)phosphonium, 1-ethyl-2,3-methylimidazolium, 1-butyl-1-methylpiperidinium, diethylmethylsulfonium, 1-methyl-3-propylimidazolium, 1-methyl-1-propylpiperidinium, 1-butyl-2-methylpyridinium, 1-butyl-4-methylpyridinium, 1-butyl-1-methylpyrrolidinium, and mixtures thereof.

19 . The method of claim 10 , wherein the first electrolyte of the composition further comprises one or more ionic liquid anions selected from the group consisting of: tris(pentafluoroethyl)trifluorophosphate, trifluoromethanesulfonate, hexafluorophosphate, tetrafluoroborate, ethyl sulfate, methyl sulfate, dimethyl phosphate, trifluoromethanesulfonate, methanesulfonate, triflate, tricyanomethanide, dibutylphosphate, bis(trifluoromethylsulfonyl)imide, bis-2,4,4-(trimethylpentyl) phosphinate, iodide, chloride, bromide, nitrate, thiocyanate, and mixtures thereof.

20 . The method of claim 10 , wherein the composition further comprises a third electrolyte different from the first and second electrolytes, the third electrolyte comprising one or more electrolytes selected from the group consisting of: potassium hydroxide, sodium hydroxide, ammonium hydroxide, lithium hydroxide, nickel hydroxide, cadmium hydroxide, magnesium hydroxide, sulfuric acid, hydrochloric acid, fluoroboric acid, ammonium chloride, zinc c

Assignees

• Nthdegree Tech Worldwide Inc

Inventors

• Lockett Vera Nicholaevna
• Lowenthal Mark David
• Shotton Neil O
• Ray William Johnstone
• Kamins Theodore I

Classifications

• H01M50/449

  having a layered structure · CPC title

• H01M50/431

  Inorganic material · CPC title

• H01M50/411

  Organic material · CPC title

• H01M50/409

  Separators, membranes or diaphragms characterised by the material · CPC title

• H01G11/62

  characterised by the solute, e.g. salts, anions or cations therein · CPC title