Fabric care compositions comprising polyurethane, polyurea and/or polyurethaneurea polymers

Patent metadata

Field	Value
Publication number	US-2015307816-A1
Application number	US-201514698879-A
Country	US
Kind code	A1
Filing date	Apr 29, 2015
Priority date	Apr 29, 2014
Publication date	Oct 29, 2015
Grant date	—

Abstract

The present disclosure relates to compositions and systems comprising fit retention polymers and methods of making and using the same. Methods of using such compositions including contacting a fabric with the fabric care composition are also disclosed.

First claim

What is claimed is:

1 . A fabric care composition comprising
a) from about 0.01% to about 30% based on total fabric care composition weight, of an organosiloxane polymer comprising having Formula I, Formula II or Formula III below:

said Formula I comprising a total of from 1 to about 200 Qs and said Formula II comprising from 2 to about 200 Qs, each Q for Formula I and II being independently selected from Formula IV, Formula V and Formula VI below:

wherein for each Formula I through VI;
(i) each X is independently selected from the group consisting of

and combinations thereof;
(ii) each L is a linking bivalent alkylene radical, (iii) at least one, R moiety is —OR 2 , and all other R moieties are independently selected from the group consisting of H, C 1 -C 20 alkyl radical, C 1 -C 20 substituted alkyl radical, C 6 -C 20 aryl radical, C 6 -C 20 substituted aryl radical, C 7 -C 20 alkylaryl radical and combinations thereof; (iv) each R 1 is independently selected from the group consisting of, H, a C 1 -C 20 alkyl radical, a C 6 -C 10 aryl radical, a C 1 -C 4 substituted alkyl radical, and a C 6 -C 10 cycloalkyl radical; (v) each R 2 is independently selected from the group consisting of H, a C 1 -C 4 alkyl radical, —C(O)R 6 wherein each R 6 is independently selected from the group consisting of C 1 -C 20 alkyl radical, C 1 -C 20 substituted alkyl radical, C 6 -C 20 aryl radical, C 6 -C 20 substituted aryl radical, and C 7 -C 20 alkylaryl radical; (vi) each R 3 is independently selected from the group consisting of an aromatic radical comprising from 6 to 30 carbon atoms, an aliphatic radical comprising from 2 to 30 carbon atoms, and a cycloaliphatic radical comprising from 6 to 30 carbon atoms; (vii) each R 4 is independently selected from the group consisting of H, a C 1 -C 20 alkyl radical, a C 6 -C 10 aryl radical, a C 1 -C 4 substituted alkyl radical, and a C 6 -C 10 cycloalkyl radical; (viii) each R 5 is independently selected from the group consisting of H, a C 1 -C 4 alkyl radical, a C 1 -C 4 substituted alkyl radical, a C 6 -C 10 aryl radical, and a C 6 -C 10 substituted aryl radical; (ix) each W is independently selected from the group consisting of a C 1 -C 200 alkylene radical that optionally comprises at least one hetero atom that interrupts said C 1 -C 200 chain, or a substituted C 1 -C 200 alkylene radical that optionally comprises at least one hetero atom that interrupts said C 1 -C 200 chain and/or optionally at least one hetero atom that interrupts said substituent; (x) p is an integer of from about 2 to about 2000; (xi) s is an integer of from about 2 to about 83; (xii) y is an integer of from about 1 to about 50; (xiii) n is an integer of from about 0 to about 50; (xiv) k is an integer selected from 0 to about 100; and
f. optionally, a material having the formula Si(R 7 ) m (OR 8 ) j wherein the index j is 1 to 4 and the index m=4−j and each R 7 is independently selected from the group consisting of C 1 -C 20 alkyl radical, C 1 -C 20 substituted alkyl radical, C 6 -C 20 aryl radical, C 6 -C 20 substituted aryl radical, and C 7 -C 20 alkylaryl radical, and each R 8 is independently selected from the group consisting of H, C 1 -C 20 alkyl radical, C 1 -C 20 substituted alkyl radical, C 6 -C 20 aryl radical, C 6 -C 20 substituted aryl radical, C 7 -C 20 alkylaryl radical, and —C(O)R 9 , wherein each R 9 is independently selected from the group consisting of C 1 -C 20 alkyl radical, C 1 -C 20 substituted alkyl radical, C 6 -C 20 aryl radical, C 6 -C 20 substituted aryl radical, and C 7 -C 20 alkylaryl radical;
g. optionally a solvent system
h. optionally a carrier; and
i. optionally, based on total fabric care composition weight, from about 0.1% to about 95%, of a surfactant.

2 . A fabric care composition according to claim 1 wherein said organosiloxane polymer comprises, based on total organosiloxane polymer weight, from about 5% to about 100%, of said repeat units having Formula (I).

3 . A fabric care composition according to claim 1 wherein 1 to 20 R moieties of Formula I are —OR 2 .

4 . A fabric care composition according to claim 1 wherein the solvent system is selected from the group consisting of a solvent having a C log P from about −0.180 to about 3.764.

5 . A fabric care composition according to claim 3 wherein said solvent is selected from the group consisting of ethanol, acetic acid, 1-propanol, 1-butanol, 2-propanol, acetonitrile, t-butyl alcohol, dimethylformamide, acetone, 1,2-dichloroethane, methylene chloride, chloroform, ethylacetate, tetrahydrofuran, dioxane, methyl t-butyl ether, diethyl ether, benzene, toluene, butyl cellosolve, butyl carbitol, hexylene glycol, water, glycerine, polyglycerine, ethylene glycol, diethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, butylene glycol, mono, di and triethanolamine, methyldiethanolamine, diethylene glycol monomethyl ether, mono and diacetin, methanol and mixtures thereof.

6 . A fabric care composition according to claim 1 wherein said carrier is selected from the group consisting of polymers, waxes, salts and mixtures thereof, preferably said polymer is selected from a polysaccharide, a polyethylene glycol and mixtures thereof and, said salt is selected from a detergent builder.

7 . A fabric care composition according to claim 1 wherein surfactant is selected from:
a) an anionic surfactant;
b) a cationic surfactant;
c) an amphoteric surfactant;
d) a nonionic surfactant; and
e) mixtures thereof.

8 . A fabric care composition according to claim 1 wherein said material having the formula Si(R 7 ) m O(R 8 ) j is selected from a monoalkoxysilane, a monoacetoxysilane, a dialkoxysilane, a diacetoxysilane, a trialkoxysilane, a triacetoxysilane, a tetraalkoxysilane, a tetraacetoxysilane and mixtures thereof.

9 . A fabric care composition according to claim 7 wherein:
a) said monoalkoxysilane is selected from the group consisting of Methoxytrimethylsilane, Ethoxytrimethylsilane, (3-Aminopropyl) ethoxydimethylsilane, (3-Aminopropyl)methoxydimethylsilane, 2-(Trimethylsiloxy)-1-aminoethane, and mixtures thereof;
b) said monoacetoxysilane is acetoxytrimethylsilane;
c) said dialkoxysilane is selected from the group consisting of Dimethoxydimethylsilane, 2-Aminoethyl-3-aminopropylmethyldimethoxysilane, Dimethyldiethoxysilane, (3-Aminopropyl)methyldiethoxysilane, 3-Aminopropylmethyldimethoxysilane and mixtures thereof;
d) said diacetoxysilane is Diacetoxydimethylsilane;
e) said trialkoxysilane is selected from the group consisting of (3-Aminopropyl)triethoxylsilane, (3-Aminopropyl)trimethoxysilane, 3-(N-Aminoethyl)aminopropyltrimethoxysilane, Methyltrimethoxysilane, Methyltriethoxysilane, (Aminomethyl)trimethoxysilane and (Diethylamino)methyltriethoxysilane, and mixtures thereof;
f) said triacetoxysilane is selected from the group consisting of Triacetoxymethylsilane, Triacetoxyethylsilane and mixtures thereof; and
g) said tetraalkoxysilane is selected from the group consisting of tetramethoxysilane, tetraethoxysilane, and mixtures thereof.

10 . A fabric care composition according to claim 1 , said fabric care composition, based on total fabric care composition weight, comprising less than 2% of a material that comprises an aldehyde and/or ketone group.

Assignees

• Procter & Gamble

Inventors

• Panandiker Rajan Keshav
• Kluesener Bernard William
• Menkhaus Julie Ann

Classifications

• C11D11/0017

  Chemistry & Metallurgy · mapped topic

• C08G77/388

  containing nitrogen · CPC title

• C11D3/3742 Primary

  Nitrogen containing silicones · CPC title

• D06M23/06

  Processes in which the treating agent is dispersed in a gas, e.g. aerosols (aerosol compositions C09K3/30) · CPC title

• D06M13/513

  with at least one carbon-silicon bond · CPC title