Annealing for damage free laser processing for high efficiency solar cells
US-9214585-B2 · Dec 15, 2015 · US
US2015171257A1 · US · A1
| Field | Value |
|---|---|
| Publication number | US-2015171257-A1 |
| Application number | US-201314404415-A |
| Country | US |
| Kind code | A1 |
| Filing date | Apr 11, 2013 |
| Priority date | Jun 29, 2012 |
| Publication date | Jun 18, 2015 |
| Grant date | — |
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An object of the present invention is to provide a method for manufacturing a semiconductor film capable of manufacturing a ZnMgO film in which the adding amount of Mg to Zn is more than 20 mol %, by means of a liquid phase deposition method. The present invention is a method for manufacturing a semiconductor film including a first step of preparing a mixture liquid including zinc hydroxide, magnesium hydroxide, and a liquid, a second step of applying a member to be film-deposited to the mixed liquid, and a third step of heating the member to be film-deposited to which the mixed liquid is applied, having a temperature range from 300° C. to 400° C. for 100/30 minutes or less.
Opening claim text (preview).
1 . A method for manufacturing a semiconductor film, the method comprising: a first step of preparing a mixed liquid including zinc hydroxide, magnesium hydroxide, and a liquid; a second step of applying the mixed liquid to a member to be film-deposited; and a third step of heating the member to be film-deposited to which the mixed liquid is applied, having a temperature range from 300° C. to 400° C. for 100/30 minutes or less. 2 . The method according to claim 1 , wherein in the third step, the member to be film-deposited to which the mixed liquid is applied is heated with a temperature range from 300° C. to 400° C. for 100/36 minutes or less. 3 . A method for manufacturing a semiconductor film, the method comprising: a first step of preparing a mixed liquid including zinc hydroxide, magnesium hydroxide, and a liquid; a second step of applying the mixed liquid to a member to be film-deposited; and a third step of heating the member to be film-deposited to which the mixed liquid is applied so that an average temperature rising rate from 300° C. to 400° C. is 30° C./min or more. 4 . The method according to claim 3 , wherein in the third step, the member to be film-deposited to which the mixed liquid is applied is heated so that the average temperature rising rate from 300° C. to 400° C. is 36° C./min or more. 5 . The method according to claim 1 , wherein a boiling temperature of the liquid is less than 300° C. 6 . The method according to claim 1 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 7 . The method according to claim 2 , wherein a boiling temperature of the liquid is less than 300° C. 8 . The method according to claim 2 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 9 . The method according to claim 3 , wherein a boiling temperature of the liquid is less than 300° C. 10 . The method according to claim 3 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 11 . The method according to claim 4 , wherein a boiling temperature of the liquid is less than 300° C. 12 . The method according to claim 4 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 13 . The method according to claim 5 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 14 . The method according to claim 7 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 15 . The method according to claim 9 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4. 16 . The method according to claim 11 , wherein determining the amount of Zn included in raw material as X [mol] and the amount of Mg included in the raw material as Y [mol], in the first step, the mixed liquid is produced with the raw material satisfying Y/(X+Y)>0.4.
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