Production of metals from metal oxides

Patent metadata

Field	Value
Publication number	US-12595578-B1
Application number	US-202217808219-A
Country	US
Kind code	B1
Filing date	Jun 22, 2022
Priority date	Jun 22, 2022
Publication date	Apr 7, 2026
Grant date	Apr 7, 2026

Abstract

A process and apparatus for producing a metal (RE) from a metal oxide (REOx). The method includes introducing the REOx and a reductant into a molten alkali and/or alkaline earth metal chloride salt phase in an oxide reductant compartment (ORC) of a partitioned process vessel. A tray containing the REOx in the ORC is reciprocated in contact with the salt phase and a molten metal collection pool phase below the salt phase. Metal formed by the reductant is induced to move through the molten metal collection pool phase from the ORC to a recovery and purification compartment (RPC) on an opposite side of a partition of the process vessel. A mixture of alkali and/or alkaline earth chloride salt containing from about 1 to about 10 wt. % chloride salt of the metal (RE) being produced is electrolyzed in the RPC. Metal produced on a cathode in the RPC is recovered.

First claim

What is claimed is:

1. A process for producing a metal from a metal oxide comprising:
introducing a metal oxide selected from rare earth metal oxides and actinide oxides, and a reductant into a molten alkali and/or alkaline earth metal chloride salt phase in an oxide reductant compartment (ORC) of a partitioned process vessel;
reciprocating a tray containing the metal oxide in the ORC in contact with the salt phase and a molten metal collection pool phase below the salt phase, wherein the molten metal collection pool comprises a metal selected from the group consisting of iron, zinc, aluminum, and other non-rare earth metals;
inducing metal selected from rare earth metals and actinides formed by the reductant to move through the molten metal collection pool phase in the ORC to a recovery and purification compartment (RPC) on an opposite side of a partition of the partitioned process vessel;
electrolyzing in the RPC a mixture of an alkali and/or alkaline earth chloride salt containing from 1 to about 10 wt. % chloride salt of the metal being produced in an electrolytic phase in the RPC; and
recovering the metal being produced on a cathode inserted into the mixture in the RPC, wherein the entire process for producing the metal from the metal oxide is conducted at a temperature ranging from about 700° C. to about 750° C.

2. The process of claim 1 , wherein the reductant comprises calcium.

3. The process of claim 1 , further comprising purging the partitioned vessel with an inert gas.

4. The process of claim 1 , further comprising removing the recovered metal from the cathode and consolidating the metal into a metal ingot.

5. The process of claim 1 , wherein the metal is a rare earth metal selected from the group consisting of lanthanum, cerium, praseodymium, and neodymium.

6. A process for producing a metal from a metal oxide comprising:
providing a partitioned vessel having an oxide reductant compartment (ORC), a recovery and purification compartment (RPC), and a molten metal collection pool phase spanning the ORC and RPC, wherein the partitioned vessel comprises a partition wall that isolates the ORC from the RPC and extends into the molten metal collection pool phase;
introducing the metal oxide selected from rare earth metal oxides and actinide oxides into a perforated tantalum or molybdenum tray disposed in a molten alkali and/or alkaline earth metal chloride salt phase in the ORC;
dissolving an amount of metal reductant selected from the group consisting of calcium, sodium and potassium in the molten alkali and alkaline earth metal chloride salt phase in the ORC above the molten metal collection pool phase, wherein the molten metal collection pool comprises a metal selected from the group consisting of iron, zinc, aluminum, and other non-rare earth metals, wherein the amount metal reductant is an amount sufficient to reduce all of the metal oxide to metal selected from rare earth metals and actinides that is dissolved in the molten metal collection pool phase in the ORC;
reciprocating the tantalum or molybdenum tray in the salt phase and the metal collection pool phase;
transporting the metal by forced convection through the molten metal collection pool phase from the ORC to the RPC;
electrolyzing in the RPC a mixture of an alkali and/or alkaline earth chloride salt containing from 1 to about 10 wt. % chloride salt of the metal being produced in an electrolytic phase in contact with the molten metal collection pool; and
recovering the metal being produced on a cathode inserted in the mixture in the RPC, wherein the entire process for producing the metal from the metal oxide is conducted at a temperature ranging from about 700° C. to about 750° C.

7. The process of claim 6 , wherein the partitioned process vessel is contained within an insulated and heated containment vessel, further comprising purging the containment vessel with an inert gas during the dissolving and electrolyzing steps.

8. The process of claim 6 , further comprising forming dendrites of the metal on the cathode.

9. The process of claim 8 , wherein the metal is a rare earth metal selected from the group consisting of lanthanum, cerium, praseodymium, and neodymium.

Assignees

• Cons Nuclear Security Llc

Inventors

• Holland Justin M

Classifications

• C25C7/025

  used in cells for the electrolysis of melts · CPC title

• C25C3/34

  of metals not provided for in groups C25C3/02 - C25C3/32 · CPC title

• C25C7/06 Primary

  Operating or servicing · CPC title