Acriflavine fusing agents for three-dimensional printing

Patent metadata

Field	Value
Publication number	US-12594717-B2
Application number	US-202118572714-A
Country	US
Kind code	B2
Filing date	Jun 28, 2021
Priority date	Jun 28, 2021
Publication date	Apr 7, 2026
Grant date	Apr 7, 2026

Abstract

A fusing agent for three-dimensional printing can include an aqueous liquid vehicle and an acriflavine dye dissolved in the aqueous liquid vehicle. The aqueous liquid vehicle can include water, organic co-solvent, and surfactant.

First claim

What is claimed is:

1 . A fusing agent for three-dimensional printing, the fusing agent consisting of:
an aqueous liquid vehicle consisting of water, an organic co-solvent, and a surfactant, wherein the water is present in an amount of from about 10 wt % to about 98 wt % with respect to a total weight of the fusing agent; and an acriflavine dye dissolved in the aqueous liquid vehicle, wherein the acriflavine dye absorbs energy at a wavelength ranging from 350 nm to 500 nm.

2 . The fusing agent of claim 1 , wherein the acriflavine dye is included in an amount of from about 0.5 wt % to about 18 wt % with respect to the total weight of the fusing agent.

3 . The fusing agent of claim 2 , wherein the organic co-solvent is included in an amount of from about 1 wt % to about 40 wt % and the surfactant is included in an amount of from about 0.1 wt % to about 5 wt %, with respect to the total weight of the fusing agent.

4 . The fusing agent of claim 1 , wherein the acriflavine dye is included in an amount of from about 8 wt % to about 18 wt % with respect to the total weight of the fusing agent.

5 . The fusing agent of claim 1 , wherein the organic co-solvent is selected from the group consisting of 1,2 butanediol; 1,2-propanediol; 2,3-butanediol; 1,2-pentanediol; 2-methyl-2,4-pentanediol; 2-methyl-1,3-propanediol; tetrahydrofuran; ethylene glycol dimethyl ether; ethylene glycol; diethylene glycol;
triethylene glycol; propylene glycol; tripropylene glycol butyl ether; 2-pyrrolidone; 1-(2-hydroxyethyl)-2-pyrrolidone; and a combination thereof.

6 . A three-dimensional printing kit, comprising:
a polymer build material including from about 80 wt % to 100 wt % of polymeric particles; and a fusing agent consisting of an aqueous liquid vehicle and an acriflavine dye dissolved in the aqueous liquid vehicle, wherein the aqueous liquid vehicle consists of water, an organic co-solvent, and a surfactant, and wherein the water is present in an amount ranging from about 10 wt % to about 98 wt % with respect to a total weight of the fusing agent, wherein the acriflavine dye absorbs energy at a wavelength ranging from 350 nm to 500 nm.

7 . The three-dimensional printing kit of claim 6 , wherein the polymeric particles comprise polyacetals, polyacrylates, polybutylene terephthalates, polycarbonates, polyesters, polyether ketones, polyethylene terephthalates, polyethylenes, polypropylenes, polystyrenes, polyurethanes, thermoplastic polyurethanes, polyamides, thermoplastic polyamides, a copolymer thereof, or a mixture thereof.

8 . The three-dimensional printing kit of claim 6 , wherein the polymeric particles have a D50 particle size of from about 10 μm to about 150 μm.

9 . The three-dimensional printing kit of claim 6 , wherein the organic co-solvent is present in an amount of from about 1 wt % to about 40 wt % with respect to the total weight of the fusing agent.

10 . The three-dimensional printing kit of claim 6 , further comprising a second fluid agent, wherein the second fluid agent is a coloring agent including a liquid vehicle and a colorant, or a detailing agent including a detailing compound that reduces a temperature of the build material onto which the detailing agent is applied.

11 . A method for three-dimensional printing, the method comprising:
iteratively applying individual build material layers of a polymer build material including from about 80 wt % to 100 wt % of polymeric particles to a powder bed; based on a three-dimensional object model, iteratively and selectively dispensing a fusing agent onto the individual build material layers, wherein the fusing agent consists of an aqueous liquid vehicle and an acriflavine dye dissolved in the aqueous liquid vehicle, wherein the aqueous liquid vehicle consists of water, an organic co-solvent, and a surfactant, wherein the water is present in an amount ranging from about 10 wt % to about 98 wt % with respect to a total weight of the fusing agent, and wherein the acriflavine dye absorbs energy at a wavelength ranging from 350 nm to 500 nm; and iteratively exposing the powder bed to light energy having a peak wavelength of from about 365 nm to about 475 nm to selectively fuse the polymeric particles in contact with the acriflavine dye at the individual build material layers resulting in a fused three-dimensional object.

12 . The method of claim 11 , wherein the light energy is provided by a light emitting diode having peak emission wavelength of about 435 nm or about 445 nm or about 450 nm or about 455 nm or about 460 nm.

13 . The method of claim 11 , further comprising pre-heating the polymer build material to a pre-heat temperature that is from about 5° C. to about 85° C. below a melting point of the polymeric particles.

14 . The method of claim 11 , wherein based on the three-dimensional object model, the method further comprises iteratively applying a second fluid agent to individual build material layers, wherein the second fluid agent is a coloring agent including a liquid vehicle and a colorant, or a detailing agent including a detailing compound that reduces a temperature of the build material onto which the detailing agent is applied.

Assignees

• Peridot Print Llc

Inventors

• Levin Emily
• Discekici Emre Hiro

Classifications

• B29K2995/0094

  Geometrical properties · CPC title

• B29K2995/002

  Coloured · CPC title

• B29K2105/251

  Particles, powder or granules (expandable particles B29K2105/046) · CPC title

• B29K2105/0032

  Pigments, colouring agents or opacifiyng agents · CPC title

• B29K2077/00

  Use of {PA, i.e.} polyamides, e.g. polyesteramides {or derivatives thereof}, as moulding material · CPC title