Low-odor soft PVC material

Patent metadata

Field	Value
Publication number	US-12590191-B2
Application number	US-202017788744-A
Country	US
Kind code	B2
Filing date	Oct 30, 2020
Priority date	Dec 26, 2019
Publication date	Mar 31, 2026
Grant date	Mar 31, 2026

Abstract

Disclosed is a low-odor soft PVC material. The material comprises the following components in parts by weight: 100 parts of a PVC resin, 60-125 parts of a plasticizer, 2-10 parts of a heat stabilizer, 10-50 parts of a filler, 0-2 parts of an antioxidant, 0.02-0.06 parts of a lubricant and 0.5-1 parts of a deodorant. The PVC resin has a degree of polymerization of lower than 1300; and the deodorant comprises nano calcium carbonate and zinc ricinoleate. By selecting a PVC resin with a low degree of polymerization and a deodorant with a high deodorizing efficiency, the low-odor soft PVC material of the present invention reduces odors from the source, has a small overall impact on the appearance and performance of automotive interior parts, and is low in cost and suitable for large-scale production.

First claim

What is claimed is:

1 . A low-odor soft polyvinyl chloride (PVC) material, comprising the following components in parts by weight: 100 parts of a PVC resin, 60-125 parts of a plasticizer, 2-10 parts of a heat stabilizer, 10-50 parts of a filler, 0.2-2 parts of an antioxidant, 0.02-0.06 part of a lubricant and 0.5-1 part of a deodorant; a degree of polymerization of the PVC resin is less than or equal to 1,300; the deodorant contains nano calcium carbonate and zinc ricinoleate,
wherein a weight ratio of the nano calcium carbonate to the zinc ricinoleate is 3-6.5:3-6.5, wherein the antioxidant is a hindered phenolic antioxidant and a hindered amine antioxidant, and a weight ratio of the hindered phenolic antioxidant to the hindered amine antioxidant is 1-3:1-3; wherein the hindered phenolic antioxidant is at least one of pentaerythritol tetrakis(β-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate), 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)benzene and tris(2,4-di-tert-butylphenyl)phosphite, and the hindered amine antioxidant is 4,4′-bis(α,α-dimethylbenzyl)diphenylamine.

2 . The low-odor soft PVC material according to claim 1 , wherein a particle size D50 of the nano calcium carbonate is 15-40 nm.

3 . The low-odor soft PVC material according to claim 1 , wherein the antioxidant is 0.2 to 1 part.

4 . The low-odor soft PVC material according to claim 1 , wherein the heat stabilizer is a calcium-zinc heat stabilizer.

5 . The low-odor soft PVC material according to claim 1 , wherein the plasticizer is at least one of benzoates, polyol esters, epoxidized soybean oil, citric acid esters and polyesters.

6 . The low-odor soft PVC material according to claim 1 , wherein the filler is at least one of calcium carbonate, barium sulfate, talc and kaolin.

7 . The low-odor soft PVC material of claim 1 , wherein the PVC material further comprises at least one of a light stabilizer, a reinforcing agent, a toughening agent, an antistatic agent and a coloring agent.

8 . The low-odor soft PVC material according to claim 5 , wherein the plasticizer is at least one of dioctyl terephthalate, di(2-propylheptyl) phthalate and trioctyl trimellitate.

Assignees

• Kingfa Science & Technology Co

Inventors

• Zhu Xiumei
• Huang Xianbo
• Ye Nanbiao
• Wang Yusen
• Yin Guojie
• Xie Mingxing
• Yang Xiaoyun

Classifications

• C08K5/103

  with polyalcohols · CPC title

• C08K5/10

  Esters; Ether-esters · CPC title

• C08K2003/265

  Calcium, strontium or barium carbonate · CPC title

• C08K5/098

  Metal salts of carboxylic acids · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title