Reactor and method for making calcium hydroxide

Patent metadata

Field	Value
Publication number	US-12590009-B2
Application number	US-202017626024-A
Country	US
Kind code	B2
Filing date	Jul 8, 2020
Priority date	Jul 11, 2019
Publication date	Mar 31, 2026
Grant date	Mar 31, 2026

Abstract

A method for making a calcium hydroxide solution includes adding water and calcium oxide into a slaking reactor equipped with a stirring means at an upper end and two or more outlets positioned at different heights. The materials are stirred so that a vertical concentration gradient of calcium ions develops within the reactor, producing a clear liquid layer at an upper region and a milk of lime suspension at a lower region. A desired calcium hydroxide solution is obtained by selecting an outlet corresponding to the required concentration of calcium ions.

First claim

The invention claimed is:

1 . A method for making a calcium hydroxide solution comprising the steps of:
adding water and calcium oxide to a slaking reactor comprising a stirring means at an upper end thereof, and two or more outlets provided at different vertical positions of the slaking reactor; stirring the water and the calcium oxide such that a concentration gradient of calcium ions is formed within the slaking reactor; and selecting an outlet from the two or more outlets to collect the calcium hydroxide solution depending on a concentration of calcium ions required.

2 . The method according to claim 1 wherein the speed of the stirring means is selectively controlled from 100 rpm to 1000 rpm.

3 . The method according to claim 1 further comprising spraying the calcium hydroxide solution into a carbonation reactor containing supercritical carbon dioxide to form a slurry of calcium carbonate.

4 . The method according to claim 3 wherein the water and the calcium oxide are stirred slowly to provide a ‘clear top’ solution at an upper outlet of the slaking reactor, such that when the ‘clear top’ solution is collected as the calcium hydroxide solution and sprayed into the carbonation reactor:
a. without dilution, calcium carbonate is formed with a particle size of around 2-10 μm; or
b. with dilution by 10-30% by volume of the calcium hydroxide solution with water, calcium carbonate is formed with a particle size of around 300-600 nm.

5 . The method according to claim 3 wherein the water and the calcium oxide are stirred slowly to provide a ‘milk of lime’ solution at a lower outlet, such that when sprayed into the carbonation reactor, calcium carbonate is formed with a particle size of around 10-30 μm.

6 . The method according to claim 3 wherein the calcium hydroxide solution is provided to the carbonation reactor continuously at a flow rate of 0.5-1.5 L/min.

7 . The method according to claim 3 wherein the calcium hydroxide solution is sprayed using an injector nozzle provided at a top section of the carbonation reactor, having a working pressure of around 80-400 bar.

8 . The method according to claim 7 wherein the injector nozzle extends around 30-40% into the carbonation reactor.

Assignees

• Petroliam Nasional Berhad Petronas

Inventors

• M Noh Mohammad Ghaddaffi B
• Onn M Syazwan B
• Sanom Ruzilah Binti

Classifications

• C01P2004/62

  Submicrometer sized, i.e. from 0.1-1 micrometer · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title

• C01F11/02

  Oxides or hydroxides (production of lime C04B2/00) · CPC title

• B01J2219/00182

  controlling the level of reactants in the reactor vessel · CPC title

• B01J2219/00164

  controlling the flow · CPC title