Conductive diamond/amorphous carbon composite material having high strength and process for preparing the same

Patent metadata

Field	Value
Publication number	US-12590004-B2
Application number	US-202217847440-A
Country	US
Kind code	B2
Filing date	Jun 23, 2022
Priority date	Nov 23, 2021
Publication date	Mar 31, 2026
Grant date	Mar 31, 2026

Abstract

The present application discloses a conductive high-strength diamond/amorphous carbon composite material and a preparation process thereof. The diamond/amorphous carbon composite material is composed of an amorphous carbon continuous phase and multiple separate diamond phases embedded in the amorphous carbon continuous phase, wherein the diamond phases exhibit an ordered sp3 hybrid state, and the amorphous carbon continuous phase exhibits a disordered sp2 hybrid state. The present application further discloses a process for preparing the above diamond/amorphous carbon composite material. The process comprises using sp3 carbon powder or glassy carbon as a raw material to obtain the above-mentioned material by sintering. The diamond/amorphous carbon composite material shows good electrical conductivity, good electrical discharge machining ability, good chemical stability and light weight, and has broad application prospects in aerospace, automobile industry and biomedical equipment.

First claim

What is claimed is:

1 . A process for preparing the carbon composite material, comprising the steps of:
(1) providing a block preform of glassy carbon; (2) loading the block preform of glassy carbon into a sintering mold, and then carrying out a first high temperature and high pressure sintering treatment; (3) after the first high temperature and high pressure sintering, cooling cavity of sintering equipment slowly to room temperature following by pressure relieve, taking out the sintered body, and then loading it into a sintering mold for a second high temperature and high pressure sintering, wherein cooling cavity of sintering equipment slowly to room temperature is a controlled stepwise cooling; (4) after the second high temperature and high pressure sintering, subjecting the sintered body to rapid cooling so as to cool the sintered body and cavity of sintering equipment quickly to room temperature, releasing pressure and taking out the sintered body for optional processing and post-processing, wherein the carbon composite material is composed of an amorphous carbon continuous phase and multiple separate diamond phases embedded in the amorphous carbon continuous phase, and wherein the diamond phases exhibit an ordered sp3 hybrid state, and the amorphous carbon continuous phase exhibits a disordered sp2 hybrid state.

2 . The process for preparing the carbon composite material as claimed in claim 1 , wherein:
the first high temperature and high pressure sintering in step (2) is carried out at a sintering pressure of 0.5 GPa to 15 GPa and a sintering temperature of 800° C. to 1500° C.; and/or the second high temperature and high pressure sintering in step (4) is carried out at a sintering pressure of 0.5 GPa to 25 GPa and a sintering temperature of 800° C. to 2500° C.

3 . The process for preparing the carbon composite material as claimed in claim 1 , wherein the controlled stepwise cooling is to first hold the temperature at 1500° C. for 10 minutes, lower it at a rate of 50° C./min to 1000° C., then hold the temperature of 1000° C. for 5 minutes, then lower it to 500° C. at a rate of 50° C./min, and hold it for 2 minutes, and finally, lower the temperature to room temperature at a rate of 50° C./min.

4 . The process for preparing the carbon composite material as claimed in claim 1 , wherein the amorphous carbon continuous phase is present in a volume content of at least 5%, or at least 10%, or at least 20%.

5 . The process for preparing the carbon composite material as claimed in claim 1 , wherein the carbon composite material has a compressive strength of greater than 1.5 GPa, and a room temperature electrical conductivity of greater than 10 S/m.

6 . The process for preparing the carbon composite material as claimed in claim 5 , wherein the compressive strength and/or the electrical conductivity is not more than 25% deviated from its average value, respectively.

7 . The process for preparing the carbon composite material as claimed in claim 1 , wherein the carbon composite material is in the form of a bulk material.

8 . The process for preparing the carbon composite material as claimed in claim 4 , wherein the carbon composite material is in the form of a bulk material.

Assignees

• Univ Yanshan

Inventors

• Zhao Zhisheng
• Liu Bing
• Li Zihe
• Wu Yingju
• Luo Kun
• Sun Lei
• Li Baozhong
• He Julong
• Yu Dongli
• Liu Zhongyuan
• Hu Wentao
• Xu Bo
• Tian Yongjun

Classifications

• C01P2006/40

  Electric properties · CPC title

• C01P2002/02

  Amorphous compounds · CPC title

• C01B32/05

  Preparation or purification of carbon not covered by groups C01B32/15, C01B32/20, C01B32/25, C01B32/30 · CPC title

• C04B2235/425

  Graphite · CPC title

• C04B2235/422

  Carbon · CPC title