Biobased hot-melt adhesive including lignin as a component
US-2019338168-A1 · Nov 7, 2019 · US
US12584019B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12584019-B2 |
| Application number | US-202017995398-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 3, 2020 |
| Priority date | Apr 3, 2020 |
| Publication date | Mar 24, 2026 |
| Grant date | Mar 24, 2026 |
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A sports field can comprise: (i) a lower base layer; (ii) an upper grass and/or artificial grass layer, and (iii) a shock pad layer, positioned between the base layer and the grass or artificial grass layer. The shock pad layer can comprise at least one shock pad comprising a coherent plate having upper and lower major surfaces, and the coherent plate can comprise at least one coherent layer comprising man-made vitreous fibres (MMVF) bonded with a cured aqueous binder composition. The aqueous binder composition prior to curing can comprise a component (i) in form of one or more oxidized lignins; a component (ii) in form of one or more cross-linkers; and a component (iii) in form of one or more plasticizers.
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The invention claimed is: 1 . A sports field comprising: a lower base layer; an upper grass and/or artificial grass layer; a shock pad layer, positioned between the base layer and the grass and/or artificial grass layer; wherein the shock pad layer comprises at least one shock pad comprising a coherent plate having upper and lower major surfaces, wherein the coherent plate comprises at least one coherent layer comprising man-made vitreous fibres (MMVF) bonded with a cured aqueous binder composition; wherein the aqueous binder composition prior to curing comprises: a component (i) in form of one or more oxidized lignins; a component (ii) in form of one or more cross-linkers; a component (iii) in form of one or more plasticizers. 2 . The sports field according to claim 1 , wherein component (i) is in form of one or more ammonia-oxidized lignins (AOLs). 3 . The sports field according to claim 1 , wherein the component (ii) comprises one or more cross-linkers selected from β-hydroxyalkylamide-cross-linkers and/or oxazoline-cross-linkers. 4 . The sports field according to claim 1 , wherein the component (ii) comprises: one or more cross-linkers selected from a group consisting of polyethylene imine, polyvinyl amine, fatty amines; and/or one more cross-linkers in form of fatty amides; and/or one or more cross-linkers selected from a group consisting of dimethoxyethanal, glycolaldehyde, glyoxalic acid; and/or one or more cross-linkers selected from polyester polyols astone; and/or one or more cross-linkers selected from a group consisting of starch, modified starch, CMC; and/or one or more cross-linkers in form of aliphatic multifunctional carbodiimides; and/or one or more cross-linkers selected from melamine based cross-linkers. 5 . The sports field according to claim 1 , comprising component (ii) in an amount of 1 to 40 wt.-%, based on the dry weight of component (i). 6 . The sports field according to claim 1 , wherein component (iii) comprises one or more plasticizers selected from a group consisting of polyethylene glycols, polyethylene glycol ethers, polyethers, hydrogenated sugars, phthalates and/or acids. 7 . The sports field according to claim 1 , wherein component (iii) comprises: one or more plasticizers selected from a group consisting of fatty alcohols, monohydroxy alcohols; and/or one or more plasticizers selected from alkoxylates; and/or one or more plasticizers in form of propylene glycols; and/or one or more plasticizers in form of glycol esters; and/or one or more plasticizers selected from a group consisting of adipates, acetates, benzoates, cyclobenzoates, citrates, stearates, sorbates, sebacates, azelates, butyrates, valerates; and/or one or more plasticizers selected from phenol derivatives; and/or one or more plasticizers selected from a group consisting of silanols, siloxanes; and/or one or more plasticizers selected from a group consisting of sulfates, sulfonates, phosphates; and/or one or more plasticizers in form of hydroxy acids; and/or one or more plasticizers selected from a group consisting of monomeric amides, fatty acid amides; and/or one or more plasticizers selected from quaternary ammonium compounds; and/or one or more plasticizers selected from vegetable oils; and or one or more plasticizers selected from a group consisting of hydrogenated oils, acetylated oils; and/or one or more plasticizers selected from acid methyl esters; and/or one or more plasticizers selected from a group consisting of alkyl polyglucosides, gluconamides, aminoglucoseamides, sucrose esters, sorbitan esters; and/or one or more plasticizers selected from a group consisting of polyethylene glycols, polyethylene glycol ethers. 8 . The sports field according to claim 1 , wherein the component (iii) is present in an amount of 0.5 to 50 s wt.-%, based on the dry weight of component (i). 9 . The sports field according to claim 1 , wherein the aqueous binder composition comprises a further component (iv) in form of one or more coupling agents, such as organofunctional silanes. 10 . The sports field according to claim 1 , wherein the aqueous binder composition comprises a component (v) in form of one or more components selected from a group consisting of ammonia, amines or any salts thereof. 11 . The sports field according to claim 1 , wherein the aqueous binder composition comprises a further component (iv) in form of urea. 12 . The sports field according to claim 1 , wherein the binder composition consists essentially of: the component (i) in form of one or more oxidized lignins; the component (ii) in form of one or more cross-linkers; the component (iii) in form of one or more plasticizers; a component (iv) in form of one or more coupling agents; optionally a component in form of one or more compounds selected from a group consisting of ammonia, amines or any salts thereof; optionally a component in form of urea; optionally a component in form of a more reactive or non-reactive silicones; optionally a hydrocarbon oil; optionally one or more surface active agents; water. 13 . The sports field according to claim 1 , wherein the shock pad further comprises: an upper membrane layer bonded to the upper major surface of the coherent plate; and/or a lower membrane layer bonded to the lower major surface of the coherent plate. 14 . The sports field according to claim 1 , wherein the at least one coherent layer has a thickness in a range of 12 mm to 60 mm. 15 . The sports field according to claim 1 , wherein the at least one coherent layer has a density in a range of 175 kg/m 3 to 300 kg/m 3 . 16 . The sports field according to claim 1 , wherein the at least one coherent layer has a hydraulic conductivity of 5 m/day to 200 m/day and/or a contact angle with water of less than 90°. 17 . The sports field according to claim 1 , wherein the at least one coherent layer comprises MMVF having a geometric fibre diameter of 1.5 to 10 microns. 18 . The sports field according to claim 1 , wherein the at least one coherent layer does not comprise any wetting agent. 19 . The sports field according to claim 1 , further comprising (iv) an infill layer between the shock pad layer and the grass and/or artificial grass layer or in the grass and/or artificial grass layer, wherein the infill layer comprises sand or non-plastic material. 20 . A method of producing a sports field, comprising the steps of: providing a lower base layer; providing a shock pad layer above the base layer; providing an upper grass and/or artificial grass layer above the shock pad layer; wherein the shock pad layer comprises at least one shock pad comprising a coherent plate having upper and lower major surfaces, wherein the coherent plate comprises at least one coherent layer comprising man-made vitreous fibres (MMVF) bonded with a cured aqueous binder composition; wherein the aqueous binder composition prior to curing comprises: a component (i) in form of one or more oxidized lignins; a component (ii) in form of one or more cross-linkers; a component (iii) in form of one or more plasticizers. 21 . The method according to claim 20 , further comprising providing an infill layer between the shock pad layer and the upper grass or artificial grass layer, wherein the infill layer comprises sand or non-plastic material.
Surfaces simulating grass {; Grass-grown sports grounds (grass-like surfaces for skiing E01C13/12)} · CPC title
Plasticisers · CPC title
Characterised by the use of lignin-containing materials · CPC title
with glass fibres · CPC title
obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds · CPC title
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