Porous polyurethane particle composition and methods thereof

Patent metadata

Field	Value
Publication number	US-12584014-B2
Application number	US-202217649505-A
Country	US
Kind code	B2
Filing date	Jan 31, 2022
Priority date	Jan 31, 2022
Publication date	Mar 24, 2026
Grant date	Mar 24, 2026

Abstract

A composition that includes porous polyurethane particles is provided. The porous particles are formed by curing an isocyanate component with water in the presence of a polyester filler and a hydrocarbon phase. A method for the preparation of porous polyurethane particles is also provided. The method includes providing a dispersed medium that contains a hydrocarbon phase, water, and a polyester filler. Then, an isocyanate component that is immiscible with the hydrocarbon phase may be added to the dispersed medium to form polyurethane prepolymer droplets, that may be cured by the water in the medium. An additional method for porous polymer particle preparation that includes providing a dispersed medium comprising a hydrocarbon phase, an isocyanate component that is immiscible in the hydrocarbon phase, and a polyester filler is provided. The dispersed medium may be agitated to form polyurethane prepolymer droplets, that may be cured by adding water.

First claim

What is claimed:

1 . A composition comprising:
a mixture comprising a catalyst, a polylactic acid filler, a hydrocarbon phase, and an isocyanate component dispersed as droplets into the hydrocarbon phase, wherein the isocyanate component is an isocyanate-terminated polyurethane prepolymer, and wherein the mixture is configured to be cured by water to form porous polyurethane particles, wherein the isocyanate component is present in an amount ranging from 1 to 50 wt % of the mixture.

2 . The composition of claim 1 , wherein the porous polyurethane particles have a size ranging from 10 micrometers to 50 millimeters.

3 . The composition of claim 1 , wherein the catalyst is an organometallic compound or a tertiary amine.

4 . The composition of claim 1 , wherein the hydrocarbon phase is selected from the group consisting of crude oil, base oil, aliphatic hydrocarbons, aromatic hydrocarbons, mineral oil, kerosene, naphtha, diesel, and combinations thereof.

5 . The composition of claim 1 , wherein the polylactic acid filler is present in an amount of 0.5 to 30 wt % based on the amount of the isocyanate component.

6 . A method comprising:
providing a dispersed medium, wherein the dispersed medium comprises a hydrocarbon phase, water, and a polylactic acid filler; adding an isocyanate component to the dispersed medium such that polyurethane prepolymer droplets are formed, wherein the isocyanate component is immiscible with the hydrocarbon phase, wherein the isocyanate component is present in an amount ranging from 1 to 50 wt %, based on the total combined weight of the dispersed medium and the isocyanate component; and curing the polyurethane prepolymer droplets.

7 . The method of claim 6 , wherein the isocyanate component is an isocyanate-terminated polyurethane prepolymer containing 1 wt % to 8 wt % of isocyanate groups.

8 . The method of claim 7 , wherein the isocyanate groups are present in an amount of 2 wt % to 6 wt % in the isocyanate-terminated polyurethane prepolymer.

9 . The method of claim 6 , wherein the dispersed medium further comprises a catalyst.

10 . The method of claim 9 , wherein the catalyst is present in an amount of 0.05 wt % to 0.5 wt %, based on the total combined weight of the dispersed medium and the isocyanate component.

11 . The method of claim 6 , wherein the polylactic acid filler is present in an amount of 3 wt % to 20 wt % based on the amount of the isocyanate component.

12 . The method of claim 6 , wherein the hydrocarbon phase is present in an amount of 75 wt % to 90 wt %, based on the total combined weight of the dispersed medium and the isocyanate component.

13 . The method of claim 6 , wherein the dispersed medium further comprises a stabilizing component selected from the group consisting of an anionic surfactant, a cationic surfactant, a non-ionic surfactant, and combinations thereof.

14 . A method comprising:
providing a dispersed medium, wherein the dispersed medium comprises a hydrocarbon phase, an isocyanate component and a polylactic acid filler, wherein the hydrocarbon phase and the isocyanate component are immiscible, wherein the isocyanate component is present in an amount ranging from 1 to 50 wt %, based on the total combined weight of the dispersed medium and isocyanate component; agitating the dispersed medium to form polyurethane prepolymer droplets; adding water to the dispersed medium under agitation; and curing the polyurethane prepolymer droplets.

15 . The method of claim 14 , wherein the isocyanate component is an isocyanate-terminated polyurethane prepolymer containing 1 wt % to 8 wt % of isocyanate groups.

16 . The method of claim 14 , wherein the dispersed medium further comprises a catalyst.

17 . The method of claim 14 , wherein the dispersed medium further comprises a stabilizing component selected from the group consisting of an anionic surfactant, a cationic surfactant, a non-ionic surfactant, and combinations thereof.

Assignees

• Aramco Services Co
• Saudi Arabian Oil Co

Inventors

• Li Wenwen
• Chang Fakuen Frank
• Liang Feng

Classifications

• C08J9/26

  by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out · CPC title

• C08G18/22

  containing metal compounds · CPC title

• C08G18/0866

  the dispersing or dispersed phase being an aqueous medium · CPC title

• C08G18/14

  Manufacture of cellular products · CPC title

• C08G2101/00

  Manufacture of cellular products · CPC title