Cross-flow interconnect and fuel cell system including same

Patent metadata

Field	Value
Publication number	US-12580205-B2
Application number	US-202418415054-A
Country	US
Kind code	B2
Filing date	Jan 17, 2024
Priority date	May 31, 2018
Publication date	Mar 17, 2026
Grant date	Mar 17, 2026

Abstract

A cross-flow interconnect and a fuel cell stack including the same, the interconnect including fuel inlets and outlets that extend through the interconnect adjacent to opposing first and second peripheral edges of the interconnect; an air side; and an opposing fuel side. The air side includes an air flow field including air channels that extend in a first direction, from a third peripheral edge of the interconnect to an opposing fourth peripheral edge of the interconnect; and riser seal surfaces disposed on two opposing sides of the air flow field and in which the fuel inlets and outlets are formed. The fuel side includes a fuel flow field including fuel channels that extend in a second direction substantially perpendicular to the first direction, between the fuel inlets and outlets; and a perimeter seal surface surrounding the fuel flow field and the fuel inlets and outlets.

First claim

What is claimed is:

1 . A fuel cell stack, comprising:
interconnects stacked over one another; fuel cells disposed between the interconnects, facing fuel and air flow fields of adjacent interconnects; a fuel inlet riser at least partially defined by fuel inlets in the interconnects and configured to provide fuel to the fuel flow fields; a fuel outlet riser at least partially defined by fuel outlets in the interconnects and configured to receive anode exhaust from the fuel flow fields; riser seals disposed on a riser seal region of each interconnect and configured to prevent fuel in the fuel inlet and outlet risers from entering the air flow fields; and perimeter seals disposed on a perimeter seal region of each interconnect and configured to prevent air from entering the fuel flow fields, wherein the riser and perimeter seals are formed of a seal material comprising, by weight: SiO 2 in an amount ranging from about 40% to about 60%; BaO in an amount ranging from about 10% to about 35%; CaO in an amount ranging from 5% to about 20%; Al 2 O 3 in an amount ranging from 13% to about 20%; and B 2 O 3 in an amount ranging from about 0.25% to about 7%.

2 . The fuel cell stack of claim 1 , wherein each fuel cell comprises:
an electrolyte disposed between adjacent first and second interconnects; a cathode covering a first surface of the electrolyte and facing the air flow field of the first interconnect; and an anode covering an opposing second surface of the electrolyte and facing the fuel flow field of the second interconnect, wherein, adjacent manifold seals contact portions of the first surface of the electrolyte that are not covered by the cathode, and each fuel cell further comprises an electrolyte reinforcement layer that extends from the anode and overlaps with the manifold seals in a stacking direction of the interconnects.

3 . The fuel cell stack of claim 2 , wherein:
the fuel cells comprise solid oxide fuel cells; the electrolyte reinforcement layer comprises a ceramic material; and a coefficient of thermal expansion of the interconnects is within +/−10% of a coefficient of thermal expansion of the fuel cells.

4 . The fuel cell stack of claim 1 , wherein the fuel cells are free of through holes.

5 . The fuel cell stack of claim 1 , further comprising conductive layers disposed between the fuel cells and adjacent fuel flow fields,
wherein portions of each conductive layer extending beyond the adjacent flow field and overlaps with an adjacent manifold seal in a stacking direction of the interconnects.

6 . The fuel cell stack of claim 5 , wherein the conductive layers comprise a nickel mesh.

7 . The fuel cell stack of claim 1 , wherein the seal material further comprises, by weight, K 2 O in an amount ranging from about 0.5% to about 1.5%.

8 . The fuel cell stack of claim 1 , wherein the fuel cell stack comprises at least 40 fuel cells and does not comprise an anode splitter plate.

9 . The fuel cell stack of claim 1 , further comprising curved ceramic baffle plates disposed on opposing sides of the fuel cell stack that curve around edges of the fuel cell stack.

10 . The fuel cell stack of claim 1 , wherein the seal material comprises, by weight CaO in an amount ranging from 7% to about 16%.

11 . The fuel cell stack of claim 1 , wherein the seal material comprises, by weight Al 2 O 3 in an amount ranging from 13% to about 15%.

12 . The fuel cell stack of claim 11 , wherein the seal material comprises, by weight CaO in an amount ranging from 7% to about 16%.

13 . The fuel cell stack of claim 10 , wherein the seal material further comprises, by weight, K 2 O in an amount ranging from about 0.5% to 1.5%.

14 . The fuel cell stack of claim 11 , wherein the seal material further comprises, by weight, K 2 O in an amount ranging from about 0.5% to 1.5%.

15 . The fuel cell stack of claim 12 , wherein the seal material further comprises, by weight, K 2 O in an amount ranging from about 0.5% to 1.5%.

16 . The fuel cell stack of claim 1 , wherein the seal material consists essentially of, by weight:
SiO 2 in an amount ranging from about 40% to about 60%; BaO in an amount ranging from about 10% to about 35%; CaO in an amount ranging from 5% to about 20%; Al 2 O 3 in an amount ranging from 13% to about 20%; B 2 O 3 in an amount ranging from about 0.25% to about 7%; and K 2 O in an amount ranging from about 0 to 1.5%.

17 . The fuel cell stack of claim 1 , wherein the seal material consists essentially of, by weight:
SiO 2 in an amount ranging from about 40% to about 60%; BaO in an amount ranging from about 10% to about 35%; CaO in an amount ranging from 7% to about 16%; Al 2 O 3 in an amount ranging from 13% to about 20%; B 2 O 3 in an amount ranging from about 0.25% to about 7%; and K 2 O in an amount ranging from about 0 to 1.5%.

18 . The fuel cell stack of claim 1 , wherein the seal material consists essentially of, by weight:
SiO 2 in an amount ranging from about 40% to about 60%; BaO in an amount ranging from about 10% to about 35%; CaO in an amount ranging from 5% to about 20%; Al 2 O 3 in an amount ranging from 13% to about 15%; B 2 O 3 in an amount ranging from about 0.25% to about 7%; and K 2 O in an amount ranging from about 0 to 1.5%.

19 . The fuel cell stack of claim 1 , wherein the seal material consists essentially of, by weight:
SiO 2 in an amount ranging from about 40% to about 60%; BaO in an amount ranging from about 10% to about 35%; CaO in an amount ranging from 7% to about 16%; Al 2 O 3 in an amount ranging from 13% to about 15%; B 2 O 3 in an amount ranging from about 0.25% to about 7%; and K 2 O in an amount ranging from about 0 to 1.5%.

20 . The fuel cell stack of claim 1 , wherein the seal material consists essentially of, by weight:
SiO 2 in an amount ranging from about 40% to about 60%; BaO in an amount ranging from about 10% to about 35%; CaO in an amount ranging from 7% to about 16%; Al 2 O 3 in an amount ranging from 13% to about 15%; B 2 O 3 in an amount ranging from about 0.25% to about 7%; and K 2 O in an amount ranging from about 0.5 to 1.5%.

Assignees

• Bloom Energy Corp

Inventors

• Gasda Michael
• Srivatsan Vijay
• Hintz Robert M
• Venkataraman Swaminathan
• Anantha Padiadpu Shankara
• El Batawi Emad
• Lin Cheng-Yu
• Mainkar Sagar
• Richards Gilbert
• Scholl Jonathan

Classifications

• H01M8/0258 Primary

  characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant · CPC title

• H01M8/2425

  High-temperature cells with solid electrolytes · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• Y02E60/50

  Fuel cells · CPC title

• C23C4/134

  Plasma spraying · CPC title