Dielectric slurry composition and multilayer electronic component using same

Patent metadata

Field	Value
Publication number	US-12580127-B2
Application number	US-202318131022-A
Country	US
Kind code	B2
Filing date	Apr 5, 2023
Priority date	Nov 29, 2022
Publication date	Mar 17, 2026
Grant date	Mar 17, 2026

Abstract

A dielectric slurry composition according to an embodiment of the present disclosure includes: a first solution including a hydrophobic solvent and dielectric particles; and a second solution containing a hydrophilic solvent, a hydrophilic dispersant, and a hydrophilic binder, wherein at least a portion of the first solution has an emulsion structure in the second solution.

First claim

What is claimed is:

1 . A dielectric slurry composition comprising:
a first solution including a hydrophobic solvent and dielectric particles; and a second solution including a hydrophilic solvent, a hydrophilic dispersant, and a hydrophilic binder, wherein at least a portion of the first solution has an emulsion structure in the second solution, wherein the second solution includes: 0.1 vol % or more and 10.0 vol % or less of the hydrophilic dispersant, 5.0 vol % or more and 50.0 vol % or less of the hydrophilic binder, and 40.0 vol % or more and 94.9 vol % or less of the hydrophilic solvent, and wherein the hydrophilic solvent includes at least one of water or dimethyl sulfoxide wherein the emulsion structure includes a droplet structure dispersed in the second solution.

2 . The dielectric slurry composition of claim 1 , wherein the dielectric particles are disposed on an inner surface of the emulsion structure.

3 . The dielectric slurry composition of claim 2 , wherein the dielectric particles are disposed in the emulsion structure.

4 . The dielectric slurry composition of claim 1 , wherein a volume ratio of the first solution is 1.0 vol % or more and 50.0 vol % or less, and a volume ratio of the second solution is 50.0 vol % or more and 99.0 vol % or less.

5 . The dielectric slurry composition of claim 1 , wherein the hydrophilic solvent of the second solution is a single solvent.

6 . The dielectric slurry composition of claim 1 , wherein the first solution includes:
1.0 vol % or more and 80.0 vol % or less of the dielectric particles and 20.0 vol % or more and 99.0 vol % or less of the hydrophobic solvent.

7 . The dielectric slurry composition of claim 1 , wherein the hydrophilic solvent includes water.

8 . The dielectric slurry composition of claim 7 , wherein the hydrophobic solvent includes at least one of dihydro terpinyl acetate (DHTA), toluene, benzene, chloroform, hexyl acetate, or an allyl hexanoate-based solvent.

9 . The dielectric slurry composition of claim 8 , wherein the dielectric particles include a barium titanate-based material, a lead composite perovskite-based material, or a strontium titanate-based material.

10 . The dielectric slurry composition of claim 1 , wherein the emulsion structure includes a droplet structure dispersed in the second solution.

11 . A method of producing a multilayer electronic component, the method comprising:
forming an internal electrode pattern; and inkjet-printing a dielectric slurry composition on the internal electrode pattern, wherein the dielectric slurry composition includes:
a first solution including a hydrophobic solvent and dielectric particles, and
a second solution including a hydrophilic solvent, a hydrophilic dispersant and a hydrophilic binder,
wherein at least a portion of the first solution has an emulsion structure in the second solution,
wherein the second solution includes: 0.1 vol % or more and 10.0 vol % or less of the hydrophilic dispersant, 5.0 vol % or more and 50.0 vol % or less of the hydrophilic binder, and 40.0 vol % or more and 94.9 vol % or less of the hydrophilic solvent, and wherein the hydrophilic solvent includes at least one of water or dimethyl sulfoxide.

12 . The method of producing a multilayer electronic component of claim 11 , wherein the emulsion structure includes a droplet structure dispersed in the second solution.

13 . The method of producing a multilayer electronic component of claim 11 , wherein the dielectric particles are disposed on an inner surface of the emulsion structure.

14 . The method of producing a multilayer electronic component of claim 13 , wherein the dielectric particles are disposed in the emulsion structure.

15 . The method of producing a multilayer electronic component of claim 11 , wherein a volume ratio of the first solution is 1.0 vol % or more and 50.0 vol % or less, and a volume ratio of the second solution is 50.0 vol % or more and 99.0 vol % or less.

16 . The method of producing a multilayer electronic component of claim 11 , wherein the hydrophilic solvent of the second solution is a single solvent.

17 . The method of producing a multilayer electronic component of claim 11 , wherein the first solution includes:
1.0 vol % or more and 80.0 vol % or less of the dielectric particles and 20.0 vol % or more and 99.0 vol % or less of the hydrophobic solvent.

18 . The method of producing a multilayer electronic component of claim 11 , further comprising, before the inkjet-printing: mixing the first solution and the second solution, sonicating the resultant mixture, and preparing the emulsion structure including converting the at least the portion of the first solution into the emulsion structure.

19 . The method of producing a multilayer electronic component of claim 11 , further comprising, after the inkjet-printing: drying the dielectric slurry composition,
wherein at least one of the hydrophilic dispersant or the hydrophilic binder of the second solution is disposed on at least a portion of outer surfaces of the emulsion structure in the dried dielectric slurry composition.

Assignees

• Samsung Electro Mech

Inventors

• Kwon Tae Gyun
• Hong So Hyeon
• Lee Eung Seok

Classifications

• H01G4/1209 Primary

  characterised by the ceramic dielectric material (H01G4/1272, H01G4/1281 take precedence) · CPC title

• H01G4/12

  Ceramic dielectrics {(H01G4/085 takes precedence)} · CPC title

• C09D11/322

  Pigment inks · CPC title

• C09D11/033

  characterised by the solvent · CPC title

• C09D11/037

  characterised by the pigment · CPC title