Slag component analysis method, slag basicity analysis method, and molten iron refining method

Patent metadata

Field	Value
Publication number	US-12578277-B2
Application number	US-202218560104-A
Country	US
Kind code	B2
Filing date	Mar 10, 2022
Priority date	May 17, 2021
Publication date	Mar 17, 2026
Grant date	Mar 17, 2026

Abstract

Provided is a slag component analysis method capable of quickly and accurately measuring slag components generated during refining of molten iron. The method comprises: irradiating a surface of slag to be analyzed with a pulse laser a plurality of times to turn part of the slag into plasma; dispersing excitation light obtained from the slag turned into plasma and acquiring an emission spectrum of an element contained in the slag per one pulse laser irradiation or per a plurality of pulse laser irradiations; and deriving a target component concentration or component amount ratio from the acquired emission spectrum, wherein the slag to be analyzed is slag generated in a converter-type refining furnace, and in the process of turning part of the slag into plasma, the pulse laser is applied from a side of the converter-type refining furnace tilted to remove the slag generated in the converter-type refining furnace.

First claim

The invention claimed is:

1 . A slag component analysis method comprising:
irradiating a surface of slag to be analyzed with a pulse laser a plurality of times to turn part of the slag into plasma; dispersing excitation light obtained from the slag turned into plasma and acquiring an emission spectrum of elements contained in the slag once for every pulse laser irradiation or once for every a plurality of pulse laser irradiations; and deriving a concentration or component amount ratio of a target component among the elements from acquired emission spectra, wherein the slag to be analyzed is slag generated in a converter-type refining furnace, and the irradiating the surface of slag to be analyzed is done from a side direction of the converter-type refining furnace tilted to remove the slag generated in the converter-type refining furnace, the side direction being a direction in which an angle between a straight line parallel to a rotation axis of the converter-type refining furnace and an optical path of the pulse laser is 45° or less with respect to the rotation axis of the converter-type refining furnace.

2 . The slag component analysis method according to claim 1 , wherein the irradiating the surface of slag to be analyzed is done from a position that is closer to a throat of the converter-type refining furnace than a rotation axis of the converter-type refining furnace when the converter-type refining furnace is tilted.

3 . The slag component analysis method according to claim 1 , wherein the deriving the concentration or component amount ratio of the target component is done using only an emission spectrum in which an emission intensity of at least one element out of Ca, Si, Mg, and Al is greater than or equal to three times a standard deviation σ of noise of the emission spectrum.

4 . The slag component analysis method according to claim 1 , wherein deriving the concentration or component amount ratio of the target component comprises:
using regression analysis to create a component amount ratio estimation model, wherein an emission intensity of an emission line of the target component obtained from the emission spectrum is used as an explanatory variable within the model, substituting the explanatory variable with a different explanatory variable corresponding to an emission spectra acquired beforehand from slag whose concentration or component amount ratio of the target component is known, wherein the different explanatory variable includes at least one emission spectrum of at least part of a wavelength range of the acquired emission spectrum, and then using the component amount ratio estimation model to calculate the concentration or component amount ratio of the target component.

5 . The slag component analysis method according to claim 4 , wherein the model is created through single regression or multivariate regression.

6 . The slag component analysis method according to claim 5 , wherein an analysis method of the multivariate regression is partial least squares.

7 . A slag basicity analysis method comprising
obtaining basicity which is defined as a ratio of CaO mass % to SiO 2 mass % of the slag using the slag component analysis method according to claim 4 .

8 . A molten iron refining method comprising
determining an amount of a slag-forming agent to be added for refining in a next process continuously performed in the converter-type refining furnace after deslagging, based on the basicity which is defined as a ratio of CaO mass % to SiO 2 mass % of the slag obtained using the slag basicity analysis method according to claim 7 .

9 . The molten iron refining method according to claim 8 , wherein the slag-forming agent contains one or more components selected from CaO, MgO, and FeO.

10 . The slag component analysis method according to claim 2 ,
wherein the deriving the concentration or component amount ratio of the target component is done using only an emission spectrum in which an emission intensity of at least one element out of Ca, Si, Mg, and Al is greater than or equal to three times a standard deviation σ of noise of the emission spectrum.

11 . The slag component analysis method according to claim 2 , wherein deriving the concentration or component amount ratio of the target component comprises:
using regression analysis to create a component amount ratio estimation model, wherein an emission intensity of an emission line of the target component obtained from the emission spectrum is used as an explanatory variable within the model, substituting the explanatory variable with a different explanatory variable corresponding to an emission spectra acquired beforehand from slag whose concentration or component amount ratio of the target component is known, wherein the different explanatory variable includes at least one emission spectrum of at least part of a wavelength range of the acquired emission spectrum, and then using the component amount ratio estimation model to calculate the concentration or component amount ratio of the target component.

12 . The slag component analysis method according to claim 3 , wherein deriving the concentration or component amount ratio of the target component comprises:
using regression analysis to create a component amount ratio estimation model, wherein an emission intensity of an emission line of the target component obtained from the emission spectrum is used as an explanatory variable within the model, substituting the explanatory variable with a different explanatory variable corresponding to an emission spectra acquired beforehand from slag whose concentration or component amount ratio of the target component is known, wherein the different explanatory variable includes at least one emission spectrum of at least part of a wavelength range of the acquired emission spectrum, and then using the component amount ratio estimation model to calculate the concentration or component amount ratio of the target component.

13 . The slag component analysis method according to claim 10 , wherein deriving the concentration or component amount ratio of the target component comprises:
using regression analysis to create a component amount ratio estimation model, wherein an emission intensity of an emission line of the target component obtained from the emission spectrum is used as an explanatory variable within the model, substituting the explanatory variable with a different explanatory variable corresponding to an emission spectra acquired beforehand from slag whose concentration or component amount ratio of the target component is known, wherein the different explanatory variable includes at least one emission spectrum of at least part of a wavelength range of the acquired emission spectrum, and then using the component amount ratio estimation model to calculate the concentration or component amount ratio of the target component.

14 . A slag basicity analysis method comprising
obtaining basicity which is defined as a CaO mass % with respect to a SiO 2 mass % of the slag using the slag component analysis method according to claim 5 .

15 . A slag basicity analysis method comprising
obtaining basicity which is defined as a ratio of CaO mass % to SiO 2 mass % of the slag using the slag component analysis method according to claim 6 .

16 . A slag basicity analysis method comprising
obtaining basicity which is defined as a ratio of CaO mass % to SiO 2 mass % of the slag using the slag component analysis method according to claim 11 .

17 . A slag basicity analysis method compris

Assignees

• Jfe Steel Corp

Inventors

• Inose Masao
• Sugawara Seiya

Classifications

• G01N2201/129

  Using chemometrical methods · CPC title

• G01N2201/0697

  Pulsed lasers · CPC title

• C21C5/4673

  Measuring and sampling devices · CPC title

• Y02P10/20

  Recycling · CPC title

• C21C5/28

  Manufacture of steel in the converter {(C21C5/005 takes precedence)} · CPC title