Melt spinning resin composition, manufacturing method for same, and fiber manufacturing method

Patent metadata

Field	Value
Publication number	US-12577703-B2
Application number	US-202318535350-A
Country	US
Kind code	B2
Filing date	Dec 11, 2023
Priority date	Dec 2, 2019
Publication date	Mar 17, 2026
Grant date	Mar 17, 2026

Abstract

The resin composition for melt spinning of the present invention is a filament having a melt viscosity of 250 Pa·s or less at 200° C. and a shear rate of 0.1 s −1 and a tensile strength of 10 MPa or more. The filament can be produced by forming a molten liquid of a resin composition having a melt viscosity of 250 Pa·s or less at 200° C. and a shear rate of 0.1 s −1 into a filament shape to provide a formed material, and conveying and concurrently cooling the formed material. The present invention also provides a resin composition for melt spinning being a filament, and a method for producing fiber using a melt spinning apparatus.

First claim

The invention claimed is:

1 . A method for producing a fiber using a melt spinning apparatus, the method comprising
feeding a filament comprising a thermoplastic resin composition to a heating device in a feed direction; heating the filament using the heating device to produce a molten filament comprising the thermoplastic resin composition in a molten state; and providing a force in a spinning direction to the molten filament to produce the fiber; and collecting the fiber, wherein the thermoplastic resin composition has a melt viscosity of 250 Pa·s or less at 200° C., a shear rate of 0.1 s −1 or more, and a tensile strength of 10 MPa or more, the method produces a continuous fiber while the feeding is performed, the fiber has a mean fiber diameter of 0.1 to 10 μm, and the force is provided by at least one selected from the group consisting of blowing gas and electric repulsion of the molten filament, the electric repulsion generated by applying a voltage to an electrode.

2 . The method of claim 1 , wherein the feeding is performed from a filament roll comprising the filament in a wound state.

3 . The method of claim 1 , wherein the heating is performed without applying a kneading force to the filament.

4 . The method of claim 1 , wherein the filament has a cross-sectional average diameter in a direction perpendicular to a length direction thereof of 1 mm or more and 30 mm or less.

5 . The method of claim 1 , wherein the thermoplastic resin composition includes a thermoplastic resin at an amount of 95 parts by mass or more based on 100 parts by mass of the resin composition.

6 . The method of claim 1 , wherein the thermoplastic resin composition comprises a polylactic acid-based resin.

7 . The method of claim 1 , wherein
the thermoplastic resin composition comprises at least one selected from the group consisting of a polypropylene resin having a weight-average molecular weight of 1,000 g/mol to 150,000 g/mol and a polylactic acid-based resin having a weight-average molecular weight of 150,000 g/mol or less.

8 . The method of claim 1 , wherein the resin comprises a thermoplastic resin, and the thermoplastic resin comprises a polylactic acid-based resin having a weight-average molecular weight of 100,000 g/mol or less.

9 . The method of claim 1 , further comprising forming the filament by
extruding a molten liquid of the resin composition into a formed material; conveying the formed material to a cooler; and cooling the formed material to produce the filament.

10 . The method of claim 9 , wherein the cooling is performed using at least one of air cooling, a cooling roller, a gas tank, and a liquid tank.

11 . The method of claim 9 , wherein a ratio of a speed of the formed material conveyed (V2) to a speed of the molten liquid extruded (V1), V2/V1, is 1 or more and 50 or less.

12 . The method of claim 11 , wherein the speed of the formed material conveyed, V2, is 0.2 m/min or more and 200 m/min or less.

13 . A melt spinning system, comprising
a supply port to which a filament is supplied in a feed direction; a heating section connected to the supply port and configured to receive the filament from the supply port and melt the filament without application of any kneading force; a nozzle connected to the heating section and configured to receive a molten filament from the heating section and provide a force in a spinning direction to the molten filament to produce a fiber; and at least one selected from the group consisting of
a gas flow spraying section configured to provide a gas flow in a spinning direction, the gas flow configured to provide the force to form the molten filament into the fiber, and
an electric charging device including an electrode configured to create an electric field between the electrode and the nozzle and to electrically charge the molten filament such that an electric force is supplied to the molten filament to form the molten filament into the fiber, wherein the filament is supplied from the supply port, and concurrently the molten filament is discharged from the nozzle into an electrical field to be spun, in a state where the electrical field is formed by the electrical charging device,
wherein the filament comprises a thermoplastic resin composition having a melt viscosity of 250 Pa·s or less at 200° C., a shear rate of 0.1 s −1 or more, and a tensile strength of 10 MPa or more, the heating section is configured such that and the filament is supplied such that the filament is substantially molten only when the filament passes from the heating section to the nozzle, the force is supplied such that the molten filament is formed into the fiber, and the fiber has a mean fiber diameter of 0.1 to 10 μm.

14 . The system of claim 13 , further comprising
a filament producing apparatus; comprising
an extruding section which extrudes a molten thermoplastic resin composition as a formed material;
a conveying section which conveys the formed material; and
a cooling section configured to cool the formed material to produce the filament, wherein
a distance between the extruding section and the conveying section is 1 mm or more and 50 mm or less, and the cooling is performed using at least one of air cooling, a cooling roller, a gas tank, and a liquid tank.

15 . The method of claim 1 , wherein the thermoplastic resin has a tensile strength of 10 to 150 MPa.

16 . The method of claim 5 , wherein the thermoplastic resin composition further comprises at least one additive selected from the group consisting of an elastomer, a plasticizer, a modifier, a decomposition inhibitor, and a charge control agent.

17 . The method of claim 1 , wherein the force is provided by electric repulsion of the molten filament, and the voltage applied to the electrode is 5 kV to 100 kV between the electrode and the heating device.

18 . The method of claim 1 , wherein the force is provided by blowing gas, the gas having a temperature of 100 to 500° C.

19 . The system of claim 13 , comprising the gas flow spraying section configured to provide a gas flow in a spinning direction, and
further comprising a gas heater configured to heat the gas to a temperature of 100 to 500° C.

20 . The system of claim 13 , comprising the electric charging device including an electrode configured to create an electric field between the electrode and the nozzle and to electrically charge the molten filament such that an electric force is supplied to the molten filament to form the molten filament into the fiber, wherein the electric field is created by applying a voltage of 5 kV to 100 kV between the nozzle and the electrode.

Assignees

• Kao Corp

Inventors

• Hirano Takahiro
• Kobayashi Hideo
• Uematsu Takehiko
• Natsui Shohei

Classifications

• B29K2067/046

  PLA, i.e. polylactic acid or polylactide · CPC title

• Y10T428/298

  Physical dimension · CPC title

• D01F6/625

  derived from hydroxy-carboxylic acids, e.g. lactones · CPC title

• D01F6/06 Primary

  from polypropylene · CPC title

• D01D1/06

  Feeding liquid to the spinning head (constructions of pumps F04) · CPC title