Plasticizer and method for manufacturing the same

Patent metadata

Field	Value
Publication number	US-12577348-B2
Application number	US-202217985597-A
Country	US
Kind code	B2
Filing date	Nov 11, 2022
Priority date	May 23, 2022
Publication date	Mar 17, 2026
Grant date	Mar 17, 2026

Abstract

A plasticizer and a method for manufacturing the plasticizer are provided. The method includes steps as follow. A dicarboxylic acid, a diol, and a catalyst are mixed to form a reactant mixture. The reactant mixture is reacted at a temperature ranging from 130° C. to 220° C. to form a semi-product. An endcapping alcohol into the semi-product at a temperature ranging from 205° C. to 220° C. to form a coarse plasticizer. The coarse plasticizer is purified under a pressure ranging from 760 Torr to 5 Torr to obtain the plasticizer. The dicarboxylic acid includes a first dicarboxylic acid and a second dicarboxylic acid, and the second dicarboxylic acid is adipic acid. The diol includes diethylene glycol and 2-methyl-1, 3-propanediol. The endcapping alcohol includes isooctyl alcohol, isodecyl alcohol, or 2-propylheptanol. A molar ratio of dicarboxylic acid:diol:the endcapping alcohol ranges from 1:0.6 to 0.9:0.3 to 0.6.

First claim

What is claimed is:

1 . A method for manufacturing a plasticizer, comprising:
mixing a dicarboxylic acid component, a diol, and a catalyst to form a reactant mixture, the dicarboxylic acid component including a first dicarboxylic acid and a second dicarboxylic acid, the second dicarboxylic acid being adipic acid, and the diol including diethylene glycol and 2-methyl-1, 3-propanediol; reacting the reactant mixture under a plurality of fixed temperature stages of a temperature-raising process, so as to form a semi-product; adding an endcapping alcohol into the semi-product at a temperature ranging from 205° C. to 220° C. so as to form a coarse plasticizer, the endcapping alcohol including isooctyl alcohol, isodecyl alcohol, or 2-propylheptanol, wherein the dicarboxylic acid component, the diol, and the endcapping alcohol have a molar ratio ranging from 1:0.6 to 0.9:0.3 to 0.6; and purifying the coarse plasticizer under a pressure ranging from 760 Torr to 5 Torr so as to obtain the plasticizer; wherein the plurality of fixed temperature stages includes a first fixed temperature stage, a second fixed temperature stage, a third fixed temperature stage, a fourth fixed temperature stage, and a fifth fixed temperature stage, a temperature range of the first fixed temperature stage ranges from 130° C. to 150° C., a temperature range of the second fixed temperature stage ranges from 150° C. to 170° C. a temperature range of the third fixed temperature stage ranges from 170° C. to 190° C., a temperature range of the fourth fixed temperature stage ranges from 190° C. to 205° C., and a temperature range of the fifth fixed temperature stage ranges from 205° C. to 220° C.

2 . The method according to claim 1 , wherein the first dicarboxylic acid is selected from the group consisting of: oxalic acid, malonic acid, methylmalonic acid, succinic acid, glutaric acid, maleic acid, and citraconic acid.

3 . The method according to claim 1 , wherein a molar amount of the first dicarboxylic acid is less than or equal to a molar amount of the second dicarboxylic acid, and a molar ratio of the first dicarboxylic acid to the dicarboxylic acid component is higher than or equal to 0.2.

4 . The method according to claim 3 , wherein a molar ratio of the first dicarboxylic acid to the second dicarboxylic acid ranges from 1:1 to 1:4.

5 . The method according to claim 1 , wherein a molar amount of diethylene glycol is less than or equal to a molar amount of 2-methyl-1, 3-propanediol.

6 . The method according to claim 5 , wherein a molar ratio of diethylene glycol to 2-methyl-1, 3-propanediol ranges from 1:1 to 1:3.

7 . The method according to claim 1 , wherein the coarse plasticizer is purified under a plurality of vacuum stages of a pressure-decreasing process so as to obtain the plasticizer, and a pressure range of the pressure-decreasing process ranges from 760 Torr to 5 Torr.

8 . The method according to claim 7 , wherein, when an acid value of the semi-product ranges from 70 mg KOH/g to 90 mg KOH/g, the temperature-raising process is completed.

9 . The method according to claim 7 , wherein, when an acid value of the coarse plasticizer ranges from 10 mg KOH/g to 30 mg KOH/g, the pressure-decreasing process is started.

10 . The method according to claim 7 , wherein the pressure-decreasing process includes a first vacuum stage, a second vacuum stage, a third vacuum stage, a fourth vacuum stage, and a fifth vacuum stage, a pressure range of the first vacuum stage ranges from 750 Torr to 400 Torr, a pressure range of the second vacuum stage ranges from 400 Torr to 300 Torr, a pressure range of the third vacuum stage ranges from 300 Torr to 150 Torr, a pressure range of the fourth vacuum stage ranges from 150 Torr to 20 Torr, and a pressure range of the fifth vacuum stage ranges from 20 Torr to 10 Torr.

Assignees

• Nan Ya Plastics Corp

Inventors

• Liao Te-Chao
• Chuang Jung-Jen
• Chen Chung-Yu
• Wu Jung-Tsu

Classifications

• C08G63/85

  Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof {(C08G63/823 takes precedence)} · CPC title

• C08G63/52

  Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation · CPC title

• C08G63/20

  Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups · CPC title

• C08G63/50

  by monohydric alcohols · CPC title

• C08G63/672 Primary

  Dicarboxylic acids and dihydroxy compounds · CPC title