Laminate having microstructured substrate and method for producing the laminate

Patent metadata

Field	Value
Publication number	US-12571940-B2
Application number	US-202117918045-A
Country	US
Kind code	B2
Filing date	Apr 12, 2021
Priority date	Apr 14, 2020
Publication date	Mar 10, 2026
Grant date	Mar 10, 2026

Abstract

A laminate, including a substrate having a microstructure on a surface thereof; and a coating layer formed on the substrate and encapsulating the microstructure of the substrate. A glass transition temperature T 1 of the substrate is higher than a glass transition temperature T 2 of the coating layer. A method of producing an ophthalmic lens, including deforming the laminate into a shape of the ophthalmic lens by applying heat and/or pressure at a temperature of lower than T 1 .

First claim

The invention claimed is:

1 . A laminate, comprising:
a substrate having a microstructure on a surface thereof; and a coating layer formed on the substrate and encapsulating the microstructure of the substrate,
wherein a glass transition temperature T 1 of the substrate is higher than a glass transition temperature T 2 of the coating layer.

2 . The laminate of claim 1 , wherein a refractive index ni of the substrate is different from a refractive index n 2 of the coating layer.

3 . The laminate of claim 1 , wherein each of the substrate and the coating layer comprises a thermoplastic, which is independently selected from a group consisting of polycarbonate, thermoplastic urethane, polyacrylate, polyester, copolyester, polymethacrylate, polystyrene, polyamide, polysulfone, polyphenylsulfone, polyetherimide, polypentene, polyolefin, ionomer, ethylene methacrylic acid, cyclic olefin copolymer, acrylonitrile, styrene maleic anhydride, a copolymer thereof, or a derivative or mixture thereof.

4 . The laminate of claim 1 , wherein a peel strength between the substrate and the coating layer is at least 100 g/25 mm measured under the test method ASTM D1876-01.

5 . The laminate of claim 1 , wherein the substrate and coating layer are transparent.

6 . The laminate of claim 1 , wherein the substrate comprises:
polycarbonate and the coating layer comprises polymethyl methacrylate, or polysulfone and the coating layer comprises polyester, or copolyester and the coating layer comprises polymethyl methacrylate, or polyamide and the coating layer comprises polymethyl methacrylate, or copolyester and the coating layer comprises thermoplastic urethane, or polyamide and the coating layer comprises polyamide.

7 . The laminate of claim 1 , wherein the microstructure is formed by embossing the surface of the substrate.

8 . The laminate of claim 1 , wherein the substrate is a micro lens for myopia control having the microstructure, the microstructure is Fresnel microstructure for increasing optical power of the substrate, or the microstructure is a moth eye microstructure for providing an anti-reflection property to the substrate.

9 . The laminate of claim 1 , wherein the substrate has a thickness from 50 μm to 2 mm.

10 . A method of producing an ophthalmic lens comprising the laminate of claim 1 , the method comprising:
deforming the laminate into a shape of the ophthalmic lens by applying heat, pressure, or both; wherein a glass transition temperature T1 of the substrate is higher than a glass transition temperature T2 of the coating layer.

11 . A method of processing a substrate having a microstructure on a surface thereof, the method comprising:
forming a coating layer on the substrate such that the coating layer encapsulates the microstructure of the substrate; and
deforming a laminate of the substrate and the coating layer by applying heat, pressure, or both,

wherein a glass transition temperature T 1 of the substrate is higher than a glass transition temperature T 2 of the coating layer.

12 . The method of claim 11 , wherein the laminate is deformed by thermoforming, and/or injection molding a hot melt polymer over the laminate at a temperature of lower than T 1 .

13 . The method of claim 11 , wherein the substrate comprises:
polycarbonate and the coating layer comprises polymethyl methacrylate, or polysulfone and the coating layer comprises polyester, or copolyester and the coating layer comprises polymethyl methacrylate, or polyamide and the coating layer comprises polymethyl methacrylate, or copolyester and the coating layer comprises thermoplastic urethane, or polyamide and the coating layer comprises polyamide.

14 . The method of claim 10 , comprising:
extruding a first polymer having a glass transition temperature T 1 to form a substrate; embossing a surface of the substrate to form the microstructure on the surface of the substrate; extruding a second polymer having a glass transition temperature T 2 to form the coating layer on the substrate such that the coating layer encapsulates the microstructure of the substrate to form the laminate; and deforming the laminate according to the method of claim 10 the laminate is deformed by thermoforming and/or injection molding a hot melt polymer over the laminate at a temperature lower than T 1 .

15 . The method of claim 14 , wherein the substrate comprises:
polycarbonate and the coating layer comprises polymethyl methacrylate, or polysulfone and the coating layer comprises polyester, or copolyester and the coating layer comprises polymethyl methacrylate, or polyamide and the coating layer comprises polymethyl methacrylate, or copolyester and the coating layer comprises thermoplastic urethane, or polyamide and the coating layer comprises polyamide.

Assignees

• Essilor Int

Inventors

• Shan Haifeng

Classifications

• G02F2202/08

  glass transition temperature · CPC title

• G02F2202/025

  thermocurable · CPC title

• G02B25/002

  Magnifying glasses · CPC title

• G02B3/08

  with discontinuous faces, e.g. Fresnel lens {(diffractive Fresnel lenses G02B5/1876)} · CPC title

• C08J2375/04

  Polyurethanes · CPC title