Poly(3-hydroxybutyrate)-based resin tube and method for producing same

Patent metadata

Field	Value
Publication number	US-12570850-B2
Application number	US-202117907518-A
Country	US
Kind code	B2
Filing date	Apr 9, 2021
Priority date	Apr 17, 2020
Publication date	Mar 10, 2026
Grant date	Mar 10, 2026

Abstract

It is an object of an embodiment of the present invention to provide: a poly(3-hydroxybutyrate)-based resin tube which exhibits excellent resistance to repeated bending; and a method for producing the poly(3-hydroxybutyrate)-based resin tube. The object is attained by providing a poly(3-hydroxybutyrate)-based resin tube which contains 95 wt % to 60 wt % of a poly(3-hydroxybutyrate)-based resin and 5 wt % to 40 wt % of an aliphatic-aromatic polyester-based resin and has an elongation at yield point in a tensile test, a tensile elongation of not less than 50% in the tensile test, and a thickness of 0.01 mm to 0.6 mm.

First claim

The invention claimed is:

1 . A method for producing a poly(3-hydroxybutyrate)-based resin tube,
wherein the poly(3-hydroxybutyrate)-based resin tube comprises
from 95 wt % to 60 wt % of a poly(3-hydroxybutyrate)-based resin; and
from 5 wt % to 40 wt % of an aliphatic-aromatic polyester-based resin,
wherein the poly(3-hydroxybutyrate)-based resin tube has an elongation at yield point in a tensile test and a tensile elongation of at least 50% in the tensile test, and the poly(3-hydroxybutyrate)-based resin tube has a thickness of 0.01 mm to 0.6 mm, wherein a crystal melting curve of a mixture of the poly(3-hydroxybutyrate)-based resin and the aliphatic-aromatic polyester-based resin in differential scanning calorimetry is such that a difference between a top temperature (Tma) of the crystal melting curve within a range of 130° C. to 155° C. and an end temperature (Tmb) of the crystal melting curve is at least 10° C., the method comprising: processing the poly(3-hydroxybutyrate)-based resin tube at room temperature to form bellows therein.

2 . The method for producing a poly (3-hydroxybutyrate)-based resin tube of claim 1 , wherein:
the aliphatic-aromatic polyester-based resin comprises a repeating unit derived from an aliphatic dicarboxylic acid, a repeating unit derived from an aromatic dicarboxylic acid, and a repeating unit derived from a diol; the aliphatic dicarboxylic acid is at least one selected from the group consisting of succinic acid, adipic acid, azelaic acid, sebacic acid, brassylic acid, pimelic acid, suberic acid, fumaric acid, and itaconic acid; the aromatic dicarboxylic acid is at least one selected from the group consisting of terephthalic acid, isophthalic acid, and frandicarboxylic acid; and the diol is at least one selected from the group consisting of 1,2-ethanediol, 1,3-propanediol, and 1,4-butanediol.

3 . The method for producing a poly (3-hydroxybutyrate)-based resin tube of claim 1 , wherein the poly(3-hydroxybutyrate)-based resin is poly(3-hydroxybutyrate-co-3-hydroxyhexanoate).

4 . The method for producing a poly (3-hydroxybutyrate)-based resin tube of claim 1 , further comprising:
melting a mixture of the poly(3-hydroxybutyrate)-based resin and the aliphatic-aromatic polyester-based resin in an extruder; and extruding the mixture through an annular die into water, wherein the annular die has a temperature set between a top temperature (Tma) of a crystal melting curve in differential scanning calorimetry of the mixture and an end temperature (Tmb) of the crystal melting curve.

5 . The method for producing a poly (3-hydroxy butyrate)-based resin tube of claim 1 , wherein the top temperature (Tma) of the crystal melting curve is from 140° C. to 145° C., and the end temperature (Tmb) of the crystal melting curve is from 165° C. to 175° C.

Assignees

• Kaneka Corp

Inventors

• Hashiguchi Tomoaki
• Okura Tetsuo

Classifications

• F16L11/04 Primary

  made of rubber or flexible plastics · CPC title

• B29L2023/008

  Drinking straws · CPC title

• B29K2995/0077

  Yield strength; Tensile strength · CPC title

• B29K2995/006

  Bio-degradable, e.g. bioabsorbable, bioresorbable or bioerodible · CPC title

• B29K2105/0088

  Blends of polymers · CPC title