Glasses with improved ion exchangeability

Patent metadata

Field	Value
Publication number	US-12570570-B2
Application number	US-201916460084-A
Country	US
Kind code	B2
Filing date	Jul 2, 2019
Priority date	Jul 6, 2018
Publication date	Mar 10, 2026
Grant date	Mar 10, 2026

Abstract

The present invention relates to glasses, such as e.g. thin or thinnest glasses, but also to glasses for the production of tubular glass, carpules and syringes as well as other pharmaceutical vessels. The glasses are characterized by a high chemical prestressability (tem-perability) with very well alkali, hydrolytic and/or acid resistance as well as an advantageous coefficient of thermal expansion. The glass has a composition characterized by the following constituent phases: 0-60 mol % reedmergnerite; 20-60 mol % albite; 0-30 mol % orthoclase; 0-20 mol % natrosilite; 0-20 mol % sodium metasilicate; 0-20 mol % parakeldyshite; 0-20 mol % narsarsukite; 0-20 mol % disodium zinc silicate; 0-21 mol % cordierite; and 0-20 mol % danburite. A quotient of a coefficient of thermal expansion of the glass multiplied by 1000 (in ppm/K) and the product of a pH value and a removal rate in alkaline environment (in mg/(dm 2 3 h)) according to ISO 695 is at least 9.0.

First claim

What is claimed is:

1 . A glass, comprising:
a composition characterized by the following constituent phases:
0-60 mol % reedmergnerite;
20-60 mol % albite;
0-30 mol % orthoclase;
0-20 mol % natrosilite;
0-20 mol % sodium metasilicate;
0-20 mol % parakeldyshite;
0-20 mol % narsarsukite;
0-20 mol % disodium zinc silicate;
0-21 mol % cordierite; and
0-20 mol % danburite, wherein at least one of the proportions of narsarsukite and disodium zinc silicate is less than 1000 ppm (molar), and wherein a quotient of a coefficient of thermal expansion of the glass multiplied by 1000 (in ppm/K) and the product of a pH value and a removal rate in alkaline environment (in mg/(dm 2 3 h)) according to ISO 695 is at least 9.0.

2 . The glass of claim 1 , wherein the proportion of disodium zinc silicate is at most 19 mol %.

3 . The glass of claim 1 , wherein the proportion of cordierite is at least one of at most 20 mol % or at least 3 mol %.

4 . The glass of claim 1 , wherein the proportion of albite is at least one of at least 30 mol % or at most 55 mol %.

5 . The glass of claim 1 , wherein the proportion of orthoclase is at least one of at least 5 mol % or at most 25 mol %.

6 . The glass of claim 1 , wherein the proportion of parakeldyshite is at most 5 mol %.

7 . The glass of claim 1 , wherein a ratio of cordierite to sodium metasilicate in mole percentages at least one of is at least 1.2 or does not exceed a value of 3.5.

8 . The glass of claim 1 , wherein the proportion of cordierite is higher than the proportion of orthoclase.

9 . The glass of claim 1 , wherein a sum of the proportion of albite, the proportion of orthoclase, and the proportion of cordierite is at least 60 mol %.

10 . The glass of claim 1 , wherein the proportion of disodium zinc silicate is at least 1.4 mol %.

11 . The glass of claim 1 , wherein the glass is free of at least one of narsarsukite, parakeldyshite, or danburite.

12 . The glass of claim 1 , wherein the proportion of further components in the composition is at most 3 mol %.

13 . The glass of claim 1 , wherein the glass has at least one of:
a characteristic acid number k of less than 208; the removal rate in alkaline environment (in mg/(dm 2 3 h)) according to ISO 695 of at most 112 mg/(dm 2 3 h); or a CTE of 6.5 to 10.5 ppm/K.

14 . A glass article, comprising:
a glass having a composition characterized by the following constituent phases:
0-60 mol % reedmergnerite;
20-60 mol % albite;
0-30 mol % orthoclase;
0-20 mol % natrosilite;
0-20 mol % sodium metasilicate;
0-20 mol % parakeldyshite;
0-20 mol % narsarsukite;
0-20 mol % disodium zinc silicate;
0-21 mol % cordierite; and
0-20 mol % danburite, wherein at least one of the proportions of narsarsukite and disodium zinc silicate is less than 1000 ppm (molar), and wherein a quotient of a coefficient of thermal expansion of the glass multiplied by 1000 (in ppm/K) and the product of a pH value and a removal rate in alkaline environment (in mg/(dm 2 3 h)) according to ISO 695 is at least 9.0.

15 . The glass article of claim 14 , wherein the glass has a cooling state which corresponds to a continuous cooling from a temperature T1 to a temperature T2 with a cooling rate K of at least 400K/min*600 μm/thickness of the glass article, wherein the temperature T1 is at least higher than a glass transition temperature TG of the glass and the temperature T2 is at least 150° C. lower than T1.

16 . The glass article of claim 14 , wherein the glass article is a pharmaceutical vessel or a thin glass having a thickness of less than 2 mm.

17 . A method for the production of a glass, the method comprising:
melting glass raw materials; and cooling the melted glass raw materials to form the glass, the formed glass having a composition characterized by the following constituent phases:
0-60 mol % reedmergnerite;
20-60 mol % albite;
0-30 mol % orthoclase;
0-20 mol % natrosilite;
0-20 mol % sodium metasilicate;
0-20 mol % parakeldyshite;
0-20 mol % narsarsukite;
0-20 mol % disodium zinc silicate;
0-21 mol % cordierite; and
0-20 mol % danburite, wherein at least one of the proportions of narsarsukite and disodium zinc silicate is less than 1000 ppm (molar), wherein a quotient of a coefficient of thermal expansion of the glass multiplied by 1000 (in ppm/K) and the product of a pH value and a removal rate in alkaline environment (in mg/(dm 2 3 h)) according to ISO 695 is at least 9.0.

18 . The method of claim 17 , further comprising producing a shaped glass article by down draw, overflow fusion, redrawing, floating or tube drawing.

Assignees

• Schott Ag

Inventors

• Fotheringham Ulrich
• Wegener Holger
• Hochrein Oliver
• Ritter Simone Monika
• Mannstadt Wolfgang
• Berndhäuser Christoph
• Gross Christoph

Classifications

• C03C4/20

  for chemical resistant glass · CPC title

• C03C3/066

  containing zinc · CPC title

• C03C2204/00

  Glasses, glazes or enamels with special properties · CPC title

• C03C4/18

  for ion-sensitive glass · CPC title

• C03C21/002

  to perform ion-exchange between alkali ions (C03C21/005 takes precedence) · CPC title