Formation process for a potassium-ion hybrid super-capacitor

Patent metadata

Field	Value
Publication number	US-12567751-B2
Application number	US-202217940179-A
Country	US
Kind code	B2
Filing date	Sep 8, 2022
Priority date	Sep 13, 2021
Publication date	Mar 3, 2026
Grant date	Mar 3, 2026

Abstract

A process may form a potassium-ion hybrid super-capacitor. Such a process may include: charging a potassium-ion hybrid supercapacitor including (i) a negative electrode comprising graphite, (ii) a positive electrode comprising activated carbon, and (ii) an electrolyte comprising a potassium salt, at constant current in a protocol of between Cx/50 and Cx/2, to a charge cutoff voltage of between 3.0 V and 3.3 V; holding the supercapacitor at the charge cutoff voltage until the leakage current is between Cx/2000 and Cx/500; and discharging the supercapacitor at constant current in a protocol of between Cx/50 and Cx, to a discharge cutoff voltage of between 0 V and 2 V, wherein the process further includes degassing the supercapacitor after the charging, the holding, or the discharging.

First claim

The invention claimed is:

1 . Formation-A process for forming a potassium-ion hybrid super-capacitor, the process comprising:
charging the potassium-ion hybrid supercapacitor comprising (i) a negative electrode comprising graphite, (ii) a positive electrode comprising activated carbon, and (iii) an electrolyte comprising a potassium salt, at constant current in a protocol-range of from Cy/10 to 5C y /2, to a charge cutoff voltage in a range of from 3.0 to 3.3 V, C, being a formation capacity of an intercalation compound KC 8 , holding the potassium-ion hybrid supercapacitor at the charge cutoff voltage until a leakage current is in a range of from C y /400 to C y /100, discharging the potassium-ion hybrid supercapacitor at constant current in a range of from C y /10 to 5C y , to a discharge cutoff voltage in a range of from 0 to 2 V; and, degassing the supercapacitor after the charging, the holding, or the discharging.

2 . The process of claim 1 , wherein the charging the holding, and/or the discharging is implemented at a temperature in a range of from 15° C. to 30° C.

3 . The process of to claim 2 , wherein each of the charging, the holding, and the discharging are implemented at a temperature in a range of from 15° C. to 30° C.

4 . The process of claim 1 , wherein the charging and the discharging are carried out in a protocol range of from C y /3 to C y .

5 . The process of claim 4 , wherein the charging and the discharging are carried out at C y /2.

6 . The process of claim 1 , wherein the hold time the holding is in a range of from 20 to 28 hours.

7 . The process of claim 6 , wherein the hold time in the holding is 24 hours.

8 . The process of claim 1 , wherein the leakage current at the end of the discharging is C y /200.

9 . The process of claim 1 , wherein the degassing of the supercapacitor is carried out after the discharging.

10 . The process of claim 1 , wherein the electrolyte is non-aqueous.

11 . The process of claim 1 , wherein the potassium salt present in the electrolyte is in solution comprising an organic solvent.

12 . The process of claim 1 , wherein the potassium salt present in the electrolyte comprises KClO 4 , KBF 4 , KPF 6 , potassium bis(trifluoromethanesulfonyl)imide, potassium bis(fluorosulfonyl)imide, potassium bis(oxalato) borate, KSCN, KSbF 6 , KAsF 6 , KAICl 4 , KSiF 6 , and/or KSO 3 CF 3 .

13 . The process of claim 12 , wherein the potassium salt present in the electrolyte comprises KClO 4 , KBF 4 , and/or KPF 6 .

14 . The process of claim 12 , wherein the potassium salt is in solution comprising a carbonate, linear ether, nitrile, lactone, and/or amide solvents.

15 . The process of claim 14 , wherein the solvent comprises propylene carbonate, ethylene carbonate, diethyl carbonate, dimethyl carbonate, dimethoxyethane, acetonitrile, γ-butyrolactone, and/or dimethylformamide.

16 . The process of claim 1 , wherein the charging, the holding, and/or the discharging is implemented at a temperature in a range of from 15 to 30° C., and
wherein the charging and the discharging are carried out in a range of from C y /3 to C y .

17 . The process of claim 1 , wherein each of the charging, the holding, and the discharging are implemented at a temperature in a range of from 15 to 30° C., and
wherein the charging and the discharging are carried out in a range of from C y /3 to C y .

18 . The process of claim 1 , wherein the potassium salt present in the electrolyte comprises KClO 4 .

19 . The process of claim 1 , wherein the potassium salt present in the electrolyte comprises KBF 4 .

20 . The process of claim 1 , wherein the potassium salt present in the electrolyte comprises KPF 6 .

Assignees

• Commissariat Energie Atomique

Inventors

• Yvenat Marie-Eve
• Azais Philippe
• Chavillon Benoît
• Mayousse Eric
• Perdu Fabien

Classifications

• H01G11/62

  characterised by the solute, e.g. salts, anions or cations therein · CPC title

• H01G11/60

  characterised by the solvent · CPC title

• Y02E60/13

  Energy storage using capacitors · CPC title

• H01G11/32

  Carbon-based · CPC title

• H01G11/02

  using combined reduction-oxidation reactions, e.g. redox arrangement or solion · CPC title