Polyimide and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-12565564-B2
Application number	US-201917610999-A
Country	US
Kind code	B2
Filing date	Nov 28, 2019
Priority date	May 13, 2019
Publication date	Mar 3, 2026
Grant date	Mar 3, 2026

Abstract

The present application relates to a polyimide and a manufacturing method therefor, thereby providing a polyimide capable of implementing excellent adhesion force while maintaining the inherent characteristics of the polyimide, and a manufacturing method therefor.

First claim

The invention claimed is:

1 . A polyimide comprising a polymer in which a diamine monomer and a dianhydride monomer are polymerized, wherein the average light transmittance in a wavelength region of 380 nm to 780 nm is in a range of 49 to 61%, and the light transmittance at a wavelength of 550 nm is in a range of 40 to 64%,
wherein the light transmittance was measured for the polyimide in the form of a film having an average thickness of about 15 to 17 μm, wherein the polymer comprises first chains and second chains shorter than the first chains, and the second chains are in an oxidized state, and wherein the polyimide is formed by heat-treatment in an imidization atmosphere comprising nitrogen and oxygen, the heat treatment starting at 110° C. and increasing to 460° C.; wherein the nitrogen and oxygen have a volume ratio of 80 to 90 and 10 respectively; and wherein the polyimide exhibits an adhesion force, according to ASTM D 3359, while attached to a glass substrate having a width of 10 mm and peeling at a rate of 20 mm/min and a peel angle of 180°, of 0.3 N/cm or more.

2 . The polyimide according to claim 1 , wherein the oxidized second chains are included in a range of 5 wt % or less in the total polymer.

3 . The polyimide according to claim 1 , wherein the diamine monomer comprises 3,5-diamino benzoic acid, 3,3-dihydroxy-4,4-diamino-biphenyl, 2,5-dihydroxy-p-phenylenediamine, 4,6-diaminoresorcinol, 1,4-diaminobenzene (PPD), 1,3-diaminobenzene (MPD), 2,4-diaminotoluene, 2,6-diaminotoluene or 4,4′-methylenediamine (MDA).

4 . The polyimide according to claim 1 , wherein the dianhydride monomer comprises pyromellitic dianhydride (PMDA), 3,3′,4,4′-biphenyltetracarboxylic dianhydride (s-BPDA) or 2,3,3′,4′-biphenyltetracarboxylic dianhydride (a-BPDA).

5 . The polyimide according to claim 1 , wherein the diamine monomer comprises at least one or more hydroxyl groups in the molecular structure.

6 . The polyimide according to claim 1 , wherein the thermal decomposition temperature is 560° C. or more.

7 . The polyimide according to claim 1 , wherein the glass transition temperature is 360° C. or more.

8 . The polyimide according to claim 1 , wherein the coefficient of thermal expansion (CTE) is 15 ppm/° C. or less.

9 . A method for manufacturing the polyimide according to claim 1 , comprising imidizing a polyimide precursor composition by heat treatment under a nitrogen and oxygen atmosphere, the heat treatment starting from 110° C. and increasing to 460° C.;
wherein the nitrogen and oxygen have a volume ratio of 80 to 90 and 10 to 20 respectively.

10 . The method for manufacturing a polyimide according to claim 9 , wherein the polyimide having the form of a film with a thickness of 5 to 50 μm is manufactured.

11 . The method for manufacturing a polyimide according to claim 9 , wherein the polyimide precursor composition has solid contents in a range of 5 to 30 wt %.

12 . The method for manufacturing a polyimide according to claim 9 , wherein the polyimide precursor composition has a viscosity of 10,000 cP or less as measured by a Brookfield viscometer in the RV-7 spindle under conditions of a temperature of 23° C. and a rotation speed of 0.5 rpm.

Assignees

• Pi Advanced Mat Co Ltd

Inventors

• Ro Gyeong Hyeon
• Hwang In Hwan
• Lee Ik Sang

Classifications

• C08L2203/16

  used for films · CPC title

• C08L2201/10

  Transparent films; Clear coatings; Transparent materials · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title

• C08L79/08

  Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors · CPC title

• C08G73/1007

  from tetracarboxylic acids or derivatives and diamines · CPC title