Methods for decreasing calcium sulfate precipitation in produced water

Patent metadata

Field	Value
Publication number	US-12565433-B2
Application number	US-202218062171-A
Country	US
Kind code	B2
Filing date	Dec 6, 2022
Priority date	Dec 6, 2022
Publication date	Mar 3, 2026
Grant date	Mar 3, 2026

Abstract

Precipitation or scaling may occur when combining produced water from multiple sources, such as when one produced water contains dissolved calcium ions and another produced water contains dissolved sulfate anions. The tendency toward precipitation or scaling may be decreased by treating the produced water containing dissolved sulfate anions. Such methods may comprise: providing a first produced water comprising dissolved sulfate anions; treating the first produced water with a metal salt capable of forming an insoluble metal sulfate, thereby forming a metal sulfate precipitate and a treated produced water; separating the metal sulfate precipitate from the treated produced water; and after separating the metal sulfate precipitate, mixing the treated produced water with at least one second produced water to obtain a mixed produced water, the at least one second produced water containing dissolved calcium ions, and the mixed produced water having a saturation ratio for calcium sulfate of less than 1.

First claim

The invention claimed is:

1 . A method comprising:
providing a first produced water comprising dissolved sulfate anions and having a pH of about 5 to about 8; treating the first produced water with a metal salt capable of forming an insoluble metal sulfate, thereby forming a metal sulfate precipitate and a treated produced water; separating the metal sulfate precipitate from the treated produced water; and after separating the metal sulfate precipitate, mixing the treated produced water with at least one second produced water to obtain a mixed produced water, the at least one second produced water containing dissolved calcium ions, and the mixed produced water having a saturation ratio for calcium sulfate of less than 1.

2 . The method of claim 1 , wherein the first produced water is treated with a solid metal salt.

3 . The method of claim 1 , wherein the metal salt is dissolved in an aqueous solution.

4 . The method of claim 1 , wherein the metal salt is an alkaline earth metal salt.

5 . The method of claim 4 , wherein the alkaline earth metal salt comprises at least one of barium chloride, calcium chloride, strontium chloride, or any combination thereof.

6 . The method of claim 4 , wherein the metal sulfate precipitate comprises barium sulfate, calcium sulfate, strontium sulfate, or any combination thereof.

7 . The method of claim 1 , wherein the treated produced water has a sulfate concentration of about 200 ppm or less.

8 . The method of claim 1 , wherein the metal sulfate precipitate is separated using a centrifugal separator, a cyclone separator, a gravitational sedimentation unit, a settling pond, a bag filter, a medium filter, or any combination thereof.

9 . The method of claim 1 , further comprising:
using the metal sulfate precipitate as a weighting agent for a subterranean operation.

10 . A method comprising:
providing a first produced water comprising dissolved sulfate anions; treating the first produced water with a metal salt capable of forming an insoluble metal sulfate, thereby forming a metal sulfate precipitate and a treated produced water; separating the metal sulfate precipitate from the treated produced water; and after separating the metal sulfate precipitate, mixing the treated produced water with at least one second produced water to obtain a mixed produced water, the at least one second produced water containing dissolved calcium ions, and the mixed produced water having a saturation ratio for calcium sulfate of less than 1;
wherein the first produced water and the at least one second produced water are obtained from separate subterranean reservoirs.

11 . The method of claim 10 , wherein the separate subterranean reservoirs are in fluid communication with a common pipeline.

12 . The method of claim 11 , wherein the first produced water is treated with the metal salt before the treated produced water is mixed with the at least one second produced water in the common pipeline.

13 . A method comprising:
providing a first produced water comprising dissolved sulfate anions and having a pH of about 5 to about 8; treating the first produced water with a metal salt dissolved in an aqueous solution, thereby forming a metal sulfate precipitate and a treated produced water; separating the metal sulfate precipitate from the treated produced water; and after separating the metal sulfate precipitate, mixing the treated produced water with at least one second produced water in a common pipeline to obtain a mixed produced water, the at least one second produced water containing dissolved calcium ions, and the mixed produced water having a saturation ratio for calcium sulfate of less than 1 in the common pipeline.

14 . The method of claim 13 , wherein the metal salt is an alkaline earth metal salt.

15 . The method of claim 14 , wherein the alkaline earth metal salt comprises at least one of barium chloride, calcium chloride, strontium chloride, or any combination thereof.

16 . The method of claim 14 , wherein the metal sulfate precipitate comprises barium sulfate, calcium sulfate, strontium sulfate, or any combination thereof.

17 . The method of claim 13 , wherein the treated produced water has a sulfate concentration of about 200 ppm or less.

18 . The method of claim 13 , wherein the metal sulfate precipitate is separated using a centrifugal separator, a cyclone separator, a gravitational sedimentation unit, a settling pond, a bag filter, a medium filter, or any combination thereof.

19 . The method of claim 13 , further comprising:
using the metal sulfate precipitate as a weighting agent for a subterranean operation.

20 . The method of claim 10 , wherein the metal salt is dissolved in an aqueous solution, the treated produced water and the at least one second produced water are mixed in a common pipeline, and the mixed produced water has a saturation ratio for calcium sulfate of less than 1 in the common pipeline.

21 . The method of claim 20 , wherein the separate subterranean reservoirs are each in fluid communication with the common pipeline.

22 . The method of claim 21 , wherein the first produced water is treated with the metal salt before the treated produced water is mixed with the at least one second produced water in the common pipeline.

Assignees

• Saudi Arabian Oil Co

Inventors

• Chen Tao
• Wang Qiwei

Classifications

• C02F2101/101

  Sulfur compounds · CPC title

• C02F2209/19

  SO4-S · CPC title

• C02F2103/06

  Contaminated groundwater or leachate · CPC title

• C02F2303/22

  Eliminating or preventing deposits, scale removal, scale prevention (C02F1/042, C02F1/4602, C02F5/00 take precedence) · CPC title

• C02F1/58

  by removing specified dissolved compounds (using ion-exchange C02F1/42; softening water C02F5/00) · CPC title