Processes and systems for making particulate masterbatches, and compositions obtained therefrom

Patent metadata

Field	Value
Publication number	US-12559598-B2
Application number	US-202318103454-A
Country	US
Kind code	B2
Filing date	Jan 30, 2023
Priority date	Feb 1, 2022
Publication date	Feb 24, 2026
Grant date	Feb 24, 2026

Abstract

Improved processes and systems are disclosed for making masterbatches of particulates to be incorporated into polymers. In some variations, a process for making a particulate masterbatch comprises the sequential steps of: providing particulates; conveying an aqueous polymer latex and the particulates to a mixing unit, thereby generating a particulate-latex mixture comprising water; conveying the particulate-latex mixture to a homogenizer; conveying the homogenized particulate-latex mixture to a centrifuge to remove a first portion of water; and then conveying the dewatered and homogenized particulate-latex mixture to a screw mixer configured to remove a second portion of water, thereby generating a particulate masterbatch. Other variations employ polymer solids rather than a polymer latex. The processes and systems enable higher energy efficiency, more robust operability that minimizes process fouling, and exceptional particulate dispersion within the masterbatch. Also, these processes do not require the use of a latex coagulant.

First claim

What is claimed is:

1 . A process for making a particulate masterbatch, said process comprising:
(a) providing a plurality of particulates; (b) introducing said plurality of particulates and a pH-adjusting agent to a first mixing unit; (c) conveying an aqueous polymer latex and said plurality of particulates from step (a) or from step (b) to a second mixing unit, thereby generating a particulate-latex mixture comprising water; (d) conveying said particulate-latex mixture and a first process additive to a third mixing unit; (e) conveying said particulate-latex mixture to a homogenizer, thereby generating a homogenized particulate-latex mixture; (f) optionally conveying said homogenized particulate-latex mixture to a centrifuge to remove a first portion of said water, thereby generating a dewatered and homogenized particulate-latex mixture; and (g) conveying said dewatered and homogenized particulate-latex mixture or, if step (f) is not conducted, conveying said homogenized particulate-latex mixture from step (e) to a screw mixer, wherein said screw mixer is configured to remove a second portion of said water, thereby generating a particulate masterbatch, wherein steps (a)-(g) are substantially conducted sequentially.

2 . The process of claim 1 , wherein said second mixing unit is a second static inline mixer.

3 . The process of claim 1 , wherein said plurality of particulates is first introduced to a pre-mixing unit (i) prior to step (b), or (ii) prior to step (c).

4 . The process of claim 1 , wherein said plurality of particulates is first slurried prior to step (b).

5 . The process of claim 1 , wherein step (f) utilizes heating to enhance water removal.

6 . The process of claim 1 , wherein said screw mixer is a twin-screw extruder.

7 . The process of claim 6 , wherein said twin-screw extruder is configured with a plurality of extruder zones with independently controlled temperatures, and a plurality of vacuum vents, for enhanced removal of said second portion of water.

8 . The process of claim 1 , wherein said screw mixer is a twin-rotor mixer.

9 . The process of claim 1 , wherein said process is continuous or semi-continuous.

10 . The process of claim 1 , wherein said particulate masterbatch is characterized by a dispersion index of at least 50.

11 . The process of claim 1 , wherein said process does not employ a polymer latex coagulating agent.

12 . The process of claim 1 , wherein said plurality of particulates includes biomass-derived particulates selected from the group consisting of cellulose, nanocellulose, hemicellulose, nanohemicellulose, lignin, nanolignin, nanolignocellulose, and combinations thereof.

13 . The process of claim 1 , wherein said plurality of particulates includes particulates selected from the group consisting of silica, alumina, clay, nano-clay, zeolites, ceramics, metals, glass, polymers, and combinations thereof.

14 . The process of claim 1 , wherein said plurality of particulates includes carbonaceous particulates selected from the group consisting of graphite, graphene, activated carbon, carbon nanotubes, carbon fibers, biochar, coke, nanodiamonds, and combinations thereof.

15 . A process for making a particulate masterbatch, said process comprising:
(a) providing a plurality of particulates; (b) optionally introducing said plurality of particulates and a pH-adjusting agent to a first mixing unit; (c) conveying an aqueous polymer latex and said plurality of particulates from step (a) or from step (b), if conducted, to a second mixing unit, thereby generating a particulate-latex mixture comprising water, wherein said second mixing unit is a second static inline mixer; (d) optionally conveying said particulate-latex mixture and a first process additive to a third mixing unit; (e) conveying said particulate-latex mixture to a homogenizer, thereby generating a homogenized particulate-latex mixture; (f) optionally conveying said homogenized particulate-latex mixture to a centrifuge to remove a first portion of said water, thereby generating a dewatered and homogenized particulate-latex mixture; and (g) conveying said dewatered and homogenized particulate-latex mixture or, if step (f) is not conducted, conveying said homogenized particulate-latex mixture from step (e) to a screw mixer, wherein said screw mixer is configured to remove a second portion of said water, thereby generating a particulate masterbatch, wherein steps (a), (c), (e), (f), and (g) are substantially conducted sequentially.

16 . A process for making a particulate masterbatch, said process comprising:
(a) providing a plurality of particulates; (b) optionally introducing said plurality of particulates and a pH-adjusting agent to a first mixing unit; (c) conveying an aqueous polymer latex and said plurality of particulates from step (a) or from step (b), if conducted, to a second mixing unit, thereby generating a particulate-latex mixture comprising water; (d) optionally conveying said particulate-latex mixture and a first process additive to a third mixing unit; (e) conveying said particulate-latex mixture to a homogenizer, thereby generating a homogenized particulate-latex mixture; (f) conveying said homogenized particulate-latex mixture to a centrifuge to remove a first portion of said water, thereby generating a dewatered and homogenized particulate-latex mixture, wherein step (f) utilizes heating to enhance water removal; and (g) conveying said dewatered and homogenized particulate-latex mixture to a screw mixer, wherein said screw mixer is configured to remove a second portion of said water, thereby generating a particulate masterbatch, wherein steps (a), (c), (e), (f), and (g) are substantially conducted sequentially.

Assignees

• Granbio Intellectual Property Holdings Llc

Inventors

• Nelson Kimberly

Classifications

• C08J5/02

  Direct processing of dispersions, e.g. latex, to articles · CPC title

• C08J2321/02

  Latex · CPC title

• B29B7/72

  Measuring, controlling or regulating · CPC title

• B29B7/82

  Heating or cooling · CPC title

• B29B7/48

  with intermeshing devices, e.g. screws · CPC title