Electrochemical apparatus and electronic apparatus

Patent metadata

Field	Value
Publication number	US-12555794-B2
Application number	US-202218147914-A
Country	US
Kind code	B2
Filing date	Dec 29, 2022
Priority date	Dec 29, 2021
Publication date	Feb 17, 2026
Grant date	Feb 17, 2026

Abstract

An electrochemical apparatus includes a positive electrode plate. The positive electrode plate includes a positive electrode material layer. The positive electrode material layer includes a fluorine-containing polymer and a cyano-containing polymer. A ratio b/a of a mole number b of nitrogen to a mole number a of fluorine in the positive electrode material layer satisfies 0.1≤b/a≤0.5. Adding the fluorine-containing polymer and the cyano-containing polymer in the positive electrode material layer and controlling the ratio b/a satisfies the above relationship enable a good bonding effect between particles in the positive electrode material layer. In addition, after cyano functional groups interact with transition metal ions of the positive electrode active material at full charge, oxidizing ability of transition metal ions is weakened, reducing side reactions between the positive electrode material layer and electrolyte, thereby improving high-temperature performance of the electrochemical apparatus.

First claim

What is claimed is:

1 . An electrochemical apparatus, comprising: a positive electrode plate, wherein the positive electrode plate comprises a positive electrode material layer, and the positive electrode material layer comprises a fluorine-containing polymer and a cyano-containing polymer, wherein a ratio b/a of a mole number b of nitrogen to a mole number a of fluorine in the positive electrode material layer satisfies 0.1≤b/a≤0.5;
wherein a weight average molecular weight of the cyano-containing polymer is 250 to 8000.

2 . The electrochemical apparatus according to claim 1 , wherein 0.3≤gb/a≤0.5.

3 . The electrochemical apparatus according to claim 1 , wherein the fluorine-containing polymer comprises at least one of polyvinylidene fluoride, polytetrafluoroethylene, polyhexafluoropropylene, vinylidene fluoride-tetrafluoroethylene copolymer, vinylidene fluoride-hexafluoropropylene copolymer, tetrafluoroethylene-hexafluoropropylene copolymer, or vinylidene fluoride-tetrafluoroethylene-hexafluoropropylene terpolymer.

4 . The electrochemical apparatus according to claim 1 , wherein the cyano-containing polymer comprises at least one of polyacrylonitrile, poly(2-butenenitrile), poly(3-butenenitrile), acrylonitrile-(2-butenenitrile) copolymer, acrylonitrile-(3-butenenitrile) copolymer, (2-butenenitrile)-(3-butenenitrile) copolymer, acrylonitrile-(2-butenenitrile)-(3-butenenitrile) terpolymer, or melamine.

5 . The electrochemical apparatus according to claim 1 , wherein a molar ratio of carbon (C) to nitrogen (N) in the cyano-containing polymer is m, and 2<m≤6.

6 . The electrochemical apparatus according to claim 1 , further comprising an electrolyte, wherein the electrolyte comprising a nitrile additive, and based on a total mass of the positive electrode material layer, a percentage sum of the cyano-containing polymer and the nitrile additive is more than 0 wt % and less than or equal to 5 wt %.

7 . The electrochemical apparatus according to claim 6 , wherein the nitrile additive comprises at least one of succinonitrile, adiponitrile, ethylene glycol bis(2-cyanoethyl) ether, or 1,2,3-tris(2-cyanoethoxy) propane.

8 . The electrochemical apparatus according to claim 1 , wherein based on a total mass of the positive electrode material layer, a percentage sum of the cyano-containing polymer and the fluorine-containing polymer is 2 wt % to 5 wt %.

9 . The electrochemical apparatus according to claim 1 , wherein the positive electrode material layer comprises a positive electrode active material, and the positive electrode active material comprises at least one of lithium cobaltate, lithium manganate, lithium nickelate, lithium nickel manganate, lithium nickel cobalt oxide, lithium nickel cobalt manganate, lithium nickel cobalt aluminate, lithium iron phosphate, lithium iron manganese phosphate, or a lithium-rich material.

10 . An electronic apparatus comprises an electrochemical apparatus, the electrochemical apparatus comprises a positive electrode plate, wherein the positive electrode plate comprises a positive electrode material layer, and the positive electrode material layer comprises a fluorine-containing polymer and a cyano-containing polymer, wherein a ratio b/a of a mole number b of nitrogen to a mole number a of fluorine in the positive electrode material layer satisfies 0.1≤b/a≤0.5;
wherein a weight average molecular weight of the cyano-containing polymer is 250 to 8000.

11 . The electronic apparatus according to claim 10 , wherein 0.3 gb/a≤0.5.

12 . The electronic apparatus according to claim 10 , wherein the fluorine-containing polymer comprises at least one of polyvinylidene fluoride, polytetrafluoroethylene, polyhexafluoropropylene, vinylidene fluoride-tetrafluoroethylene copolymer, vinylidene fluoride-hexafluoropropylene copolymer, tetrafluoroethylene-hexafluoropropylene copolymer, or vinylidene fluoride-tetrafluoroethylene-hexafluoropropylene terpolymer.

13 . The electronic apparatus according to claim 10 , wherein the cyano-containing polymer comprises at least one of polyacrylonitrile, poly(2-butenenitrile), poly(3-butenenitrile), acrylonitrile-(2-butenenitrile) copolymer, acrylonitrile-(3-butenenitrile) copolymer, (2-butenenitrile)-(3-butenenitrile) copolymer, acrylonitrile-(2-butenenitrile)-(3-butenenitrile) terpolymer, or melamine.

14 . The electronic apparatus according to claim 10 , wherein a molar ratio of carbon (C) to nitrogen (N) in the cyano-containing polymer is m, and 2<m≤6.

15 . The electronic apparatus according to claim 10 , further comprising an electrolyte, wherein the electrolyte comprising a nitrile additive, and based on a total mass of the positive electrode material layer, a percentage sum of the cyano-containing polymer and the nitrile additive is more than 0 wt % and less than or equal to 5 wt %.

16 . The electronic apparatus according to claim 15 , wherein the nitrile additive comprises at least one of succinonitrile, adiponitrile, ethylene glycol bis(2-cyanoethyl) ether, or 1,2,3-tris(2-cyanoethoxy) propane.

17 . The electronic apparatus according to claim 10 , wherein based on a total mass of the positive electrode material layer, a percentage sum of the cyano-containing polymer and the fluorine-containing polymer is 2 wt % to 5 wt %.

18 . The electronic apparatus according to claim 10 , wherein the positive electrode material layer comprises a positive electrode active material, and the positive electrode active material comprises at least one of lithium cobaltate, lithium manganate, lithium nickelate, lithium nickel manganate, lithium nickel cobalt oxide, lithium nickel cobalt manganate, lithium nickel cobalt aluminate, lithium iron phosphate, lithium iron manganese phosphate, or a lithium-rich material.

Assignees

• Dongguan Amperex Tech Ltd

Inventors

• Sun Zhenhe

Classifications

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0567

  characterised by the additives · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title