Corrosion inhibitor compositions for reducing corrosion, and related methods of operating a wellbore

Patent metadata

Field	Value
Publication number	US-12553316-B2
Application number	US-202418782974-A
Country	US
Kind code	B2
Filing date	Jul 24, 2024
Priority date	Aug 30, 2023
Publication date	Feb 17, 2026
Grant date	Feb 17, 2026

Abstract

A method of reducing corrosion within a wellbore includes placing a wireline including a perforating gun in a wellbore, the wellbore extending through an earth formation and including a casing extending through the earth formation, the wireline including zinc, discharging the perforating gun to form perforations through the casing and in the earth formation surrounding the casing proximate the at least one perforating gun, flowing a fracturing fluid including one or more proppants through the perforations and into the earth formation to open fractures in the earth formation with the one or more proppants, introducing a flushing fluid into the wellbore to displace the fracturing fluid, and flowing a corrosion inhibitor composition into the wellbore and through the perforations with at least one of the fracturing fluid and the flushing fluid. The corrosion inhibitor includes an alkenylphenone, and a substituted 1-azanapthalene.

First claim

What is claimed is:

1 . A method for operating a wellbore, the method comprising:
placing a wireline including a perforating gun in a wellbore, the wellbore extending through an earth formation and including a casing extending through the earth formation, the wireline including zinc in a galvanized coating on an outer surface of the wireline; discharging the perforating gun to form perforations through the casing and in the earth formation surrounding the casing proximate the perforating gun; flowing a fracturing fluid including one or more proppants through the perforations and into the earth formation to open fractures in the earth formation with the one or more proppants; introducing a flushing fluid into the wellbore to displace the fracturing fluid; flowing a corrosion inhibitor composition into the wellbore and through the perforations before the fracturing fluid, the corrosion inhibitor composition comprising:
an alkenylphenone; and
a substituted 1-azanapthalene; and
performing a fracturing operation on an additional wellbore neighboring the wellbore while the corrosion inhibitor composition is in the wellbore, the fracturing operation including:
placing a wireline including a perforating gun in an additional wellbore neighboring the wellbore, the additional wellbore extending through the earth formation and including an additional casing extending through the earth formation, the wireline including zinc;
discharging the perforating gun to form additional perforations through the additional casing and in the earth formation surrounding the additional casing proximate the perforating gun;
flowing the fracturing fluid through the additional perforations and into the earth formation to open additional fractures in the earth formation with the one or more proppants;
introducing the flushing fluid into the additional wellbore to displace the fracturing fluid; and
flowing the corrosion inhibitor composition into the additional wellbore and through the additional perforations therein before the flowing the fracturing fluid through the additional perforations.

2 . The method of claim 1 , wherein discharging the perforating gun to form the perforations includes forming the perforations through cement surrounding the casing.

3 . The method of claim 1 , further comprising flowing an acid into the wellbore after forming the perforations through the casing and in the earth formation, the acid including the corrosion inhibitor composition.

4 . The method of claim 1 , wherein flowing the corrosion inhibitor composition into the wellbore includes flowing the corrosion inhibitor composition into the wellbore while the wireline is in the wellbore.

5 . The method of claim 1 , wherein flowing the corrosion inhibitor composition into the wellbore includes contacting surface equipment with the corrosion inhibitor composition.

6 . The method of claim 5 , further comprising removing the perforating gun from the wellbore prior to flowing the fracturing fluid through the perforations.

7 . The method of claim 1 , wherein:
the alkenylphenone includes the following structure:

wherein R 1 is an unsubstituted or an inertly substituted aryl having 6 carbon atoms to 10 carbon atoms, and R 2 and R 3 individually include hydrogen, a halogen, an inertly substituted aliphatic of 3 carbon atoms to 12 carbon atoms, or an unsubstituted or an inertly substituted aryl having 6 carbon atoms to 10 carbon atoms; and
the substituted 1-azanaphthalene has the following structure:

wherein R 4 is a substituted alkyl having 4 carbon atoms to 16 carbon atoms, or an unsubstituted or inertly substituted alkylaryl having 7 carbon atoms to 20 carbon atoms, and X is a halide.

8 . The method of claim 1 , wherein the corrosion inhibitor composition comprises at least about 3.0 parts by weight of the substituted 1-azanaphthalene for every about 1.0 part by weight of the alkenylphenone.

9 . The method of claim 1 , wherein the corrosion inhibitor composition comprises a cetyl trimethyl ammonium bromide.

10 . The method of claim 1 , wherein the corrosion inhibitor composition includes from about 2.0 parts by weight to about 5.0 parts by weight of the substituted 1-azanaphthalene for every about 1.0 part by weight of the alkenylphenone.

Assignees

• Schlumberger Technology Corp

Inventors

• Rabie Ahmed
• Prabhu Rasika
• Daeffler Christopher
• Estrada Benavides Juan David
• Brown Robert

Classifications

• E21B43/267 Primary

  reinforcing fractures by propping · CPC title

• C09K8/80

  Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open · CPC title

• C09K2208/32

  Anticorrosion additives · CPC title

• C09K8/54

  Compositions for in situ inhibition of corrosion in boreholes or wells · CPC title

• E21B43/27

  by use of eroding chemicals, e.g. acids · CPC title