Controlled method for depositing a chromium or chromium alloy layer on at least one substrate
US-2020017986-A1 · Jan 16, 2020 · US
US12553143B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12553143-B2 |
| Application number | US-202118022730-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 20, 2021 |
| Priority date | Aug 27, 2020 |
| Publication date | Feb 17, 2026 |
| Grant date | Feb 17, 2026 |
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Provided is a shock absorber in which trivalent chromium is used to achieve both high hardness and low frictional force at a high level without using hexavalent chromium which is suspected of causing damage to the human body and the environment, and a method for manufacturing the shock absorber. A shock absorber ( 100 ) of the present invention includes: a cylinder ( 1 ) which is filled with hydraulic oil ( 3 ); a piston rod ( 2 ) which is movable in the cylinder ( 1 ); and an oil seal ( 8 ) which is fixed to the cylinder ( 1 ) and slides on the piston rod ( 2 ), in which a hard layer mainly containing chromium obtained from a trivalent chromium plating bath is provided on a surface of the piston rod ( 2 ), and the hard layer contains both a crystalline material and an amorphous material, and also contains an additive other than chromium.
Opening claim text (preview).
The invention claimed is: 1 . A shock absorber comprising: a cylinder which is filled with hydraulic oil; a piston rod which is movable in the cylinder; and an oil seal which is fixed to the cylinder and slides on the piston rod, wherein a hard layer mainly containing chromium obtained from a trivalent chromium plating bath is provided on a surface of the piston rod, the hard layer contains both a crystalline material and an amorphous material, and also contains an additive other than the chromium, and the hard layer has a crystallization rate of 5 to 99%, as calculated from a peak integral intensity ratio of a value measured by X-ray diffraction and the following (Equation 1): Crystallization rate(peak integral intensity ratio %)=(crystalline/(crystalline+amorphous))×100 (Equation 1). 2 . The shock absorber according to claim 1 , wherein the additive contains at least one element of hydrogen, carbon, nitrogen, or oxygen, and a content of the additive is 0.5 mass % or greater and 4.3 mass % or less. 3 . The shock absorber according to claim 1 , wherein the hard layer has a Vickers hardness HV of 800 HV or greater and a frictional force of less than 47.3 N. 4 . The shock absorber according to claim 1 , wherein the hard layer has a surface roughness Rz of 0.6 μm or less. 5 . A method for manufacturing a shock absorber the shock absorber including: a cylinder which is filled with hydraulic oil; a piston rod which is movable in the cylinder; and an oil seal which is fixed to the cylinder and slides on the piston rod, the method comprising a plating step of forming a plating film including a hard layer mainly containing trivalent chromium on a surface of the piston rod, wherein the plating step is performed at a cathode current density of 100 A/dm2 or greater in a plating bath containing a trivalent chromium salt, a carboxylic acid, a pH buffering agent, and a conductive salt and having a pH of ≤0.1. 6 . The shock absorber according to claim 2 , wherein the hard layer has a Vickers hardness HV of 800 HV or greater and a frictional force of less than 47.3 N. 7 . The shock absorber according to claim 2 , wherein the hard layer has a surface roughness Rz of 0.6 μm or less. 8 . The shock absorber according to claim 6 , wherein the hard layer has a surface roughness Rz of 0.6 μm or less.
Surface features, e.g. notches or protuberances · CPC title
of solids, e.g. hardness · CPC title
Surface treatments · CPC title
Alloys · CPC title
Fluid damping · CPC title
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