Continuous thermal compression of hydrogen

Patent metadata

Field	Value
Publication number	US-12545575-B2
Application number	US-202118006221-A
Country	US
Kind code	B2
Filing date	May 26, 2021
Priority date	Jul 28, 2020
Publication date	Feb 10, 2026
Grant date	Feb 10, 2026

Abstract

A continuous thermal hydrogen compression system, and methods of thermally compressing hydrogen, are disclosed. A hydrogenation module accepts a hydrogen gas stream to be absorbed or adsorbed to a lean carrier stream through heat removal, thereby producing a heat output and a rich carrier stream containing absorbed or adsorbed hydrogen. A pump, connected to an output of the hydrogenation module, increases the pressure of the rich carrier stream to produce a pressurized rich carrier stream. A dehydrogenation module separates, via an addition of heat, a pressurized hydrogen gas stream from the pressurized rich carrier stream to produce a lean carrier stream. A pressure reducing device reduces the pressure of the lean carrier stream before it is returned to the hydrogenation module. The carrier stream is cycled continuously between the hydrogenation module and the dehydrogenation module.

First claim

What is claimed is:

1 . A method of continuously compressing a hydrogen gas stream, comprising:
in a hydrogenation module, adsorbing or absorbing the hydrogen gas stream at a first pressure level to a lean carrier stream through heat removal, to thereby produce a heat output and a rich carrier stream containing absorbed or adsorbed hydrogen; using a pump, increasing a pressure of the rich carrier stream to produce a pressurized rich carrier stream; in a dehydrogenation module, separating, via an addition of heat, a pressurized hydrogen gas stream from the pressurized rich carrier stream, to thereby produce a lean carrier stream; reducing a pressure of the lean carrier stream before the lean carrier stream is returned to the hydrogenation module; and cycling the carrier stream is continuously between the hydrogenation module and the dehydrogenation module.

2 . The method of claim 1 , wherein the carrier comprises a composition that is substantially incompressible throughout a range of pressures used in the hydrogenation module and the dehydrogenation module.

3 . The method of claim 1 , further comprising:
in a recuperative heat exchanger, exchanging heat between the lean carrier stream exiting the dehydrogenation module and the pressurized rich carrier stream exiting the pump.

4 . The method of claim 1 , further comprising:
accepting at least a portion of a heat output of the hydrogenation module into a heat pump; and with a work input, providing a heat output from the heat pump, wherein the heat output is used, at least partially, in the dehydrogenation module.

5 . The method of claim 4 , further comprising:
cooling the pressurized hydrogen gas stream in an ambient or sub-ambient cooler.

6 . The method of claim 1 , further comprising:
determining a heat rejection temperature of the hydrogenation module; determining a hydrogen loading of the carrier stream using the heat rejection temperature; using the hydrogen loading and a pressure of the pressurized hydrogen gas stream, determining a required temperature of a heat input into the dehydrogenation module and setting a heat input set point for the dehydrogenation module; and controlling an amount of hydrogen processed by the thermal hydrogen compression system by varying a flow rate of the carrier stream while maintaining the required temperature of the heat input into the dehydrogenation module.

7 . The method of claim 6 , further comprising:
controlling a pump speed of the pump to vary the flow rate of the carrier stream.

8 . The method of claim 7 , further comprising:
determining the pump speed based on at least one of a desired flow rate of the pressurized hydrogen gas stream, a pressure of the pressurized hydrogen gas stream, and the heat rejection temperature.

9 . The method of claim 8 , further comprising:
using the pump speed to determine needed changes to the heat rejection temperature.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Staedter Marcel

Classifications

• Y02P90/45

  Hydrogen technologies in production processes · CPC title

• Y02P20/129

  Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines · CPC title

• Y02E60/32

  Hydrogen storage · CPC title

• F17C11/005

  for hydrogen · CPC title

• C01B3/0073 Primary

  Slurries; Suspensions · CPC title