Method for laser treatment of a lithium surface

Patent metadata

Field	Value
Publication number	US-12542276-B2
Application number	US-202117924440-A
Country	US
Kind code	B2
Filing date	Apr 29, 2021
Priority date	May 11, 2020
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

A method for treating a surface of a strip or film, the strip or film being made of lithium or a lithium-based alloy, the method comprising a step of radiating at least one portion of the surface of the strip or film with a laser beam, the radiating step being carried out in a controlled atmosphere, the laser beam radiating the entire area of the at least one portion of the surface of the strip or film.

First claim

The invention claimed is:

1 . A method for treating a surface of a strip or film, said strip or film being made of lithium or a lithium-based alloy, the method comprising a step of laser beam irradiation of at least a portion of a surface of said strip or film, the irradiation step being carried out under controlled atmosphere, the entire surface area of said at least one surface portion of the strip or film being irradiated by the laser beam,
the method comprising a succession of trajectories of the laser beam above said at least one portion of a surface of the strip or film, the spacing between two trajectories being less than the size of the focal spot of the laser, so that the portion of the surface irradiated by the laser beam does not include a geometric pattern, regardless of the angle of observation, and is modified without forming edges.

2 . The method of claim 1 , wherein one or more of the trajectories of the laser beam are non-linear.

3 . The method according to claim 1 , wherein the laser is a pulsed laser.

4 . The method according to claim 1 , wherein the laser emits a wavelength in the infrared (IR) domain.

5 . The method according to claim 1 , wherein the irradiation step is carried out in anhydrous medium, according to one of the following conditions:
in an atmosphere of one or more gases selected from oxygen O 2 , nitrogen N 2 , argon Ar, helium He and mixtures thereof, under vacuum, or in a reactive atmosphere or environment with respect to lithium.

6 . The method according to claim 5 , wherein the reactive atmosphere or environment comprises a compound containing atoms selected from fluorine, sulfur, phosphorus, carbon and a mixture thereof.

7 . The method according to claim 1 , wherein said strip or film is covered before treatment by a protective or passivation layer.

8 . A strip or film made of lithium or a lithium-based alloy comprising a surface, a portion of the surface being treated by the method as defined in claim 1 , in which the entire surface area of said portion does not include any geometric pattern, regardless of the angle of observation, and does not include edges.

9 . An electrode comprising the strip or film as defined in claim 8 .

10 . An electrochemical cell comprising:
at least one negative electrode which is the electrode as defined in claim 9 , at least one positive electrode, and a liquid or solid electrolyte.

11 . The electrochemical cell of claim 10 , which is a primary electrochemical cell comprising a liquid or solid electrolyte.

12 . The electrochemical cell of claim 10 , which is a secondary electrochemical cell comprising a solid electrolyte.

Assignees

• Accumulateurs Fixes

Inventors

• Borel Philippe
• Gazziero Maeva
• Levasseur Delphin
• Breger Julien
• Pavlenko Ekaterina
• Huchet Olivier
• Herreyre Sylvie

Classifications

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/12

  of consumable metal or alloy electrodes (use of alloy compositions as active materials H01M4/38) · CPC title

• H01M4/06

  Electrodes for primary cells · CPC title

• B23K26/38

  by boring or cutting · CPC title