Method for liquefying a stream rich in CO2

Patent metadata

Field	Value
Publication number	US-12540771-B2
Application number	US-202218280060-A
Country	US
Kind code	B2
Filing date	Mar 2, 2022
Priority date	Mar 3, 2021
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

In a method for liquefying a gas rich in carbon dioxide, the gas is compressed to a first pressure greater than its critical pressure in a compressor to form a compressed gas, the compressed gas is cooled through heat exchange with a refrigerant to a variable temperature to form a cooled compressed gas with a density between 370 and 900 kg/m 3 , the cooled compressed gas is cooled at supercritical pressure in a first heat exchanger to a temperature below the critical temperature, the gas cooled below the critical temperature is expanded to a second pressure between 45 and 60 bara to form a diphasic fluid which is separated in a phase separator to form a liquid and a gas, and a liquid portion originating from the phase separator provides cold to the first heat exchanger.

First claim

The invention claimed is:

1 . A process for the liquefaction of a gas rich in carbon dioxide, the process comprising the steps of:
i. compressing the gas to a first pressure greater than its critical pressure in a compressor to form a compressed gas; ii. cooling the compressed gas by heat exchange with a refrigerant having a variable temperature to form a cooled compressed gas with a density between 370 and 900 kg/m 3 ; iii. cooling the cooled compressed gas at the supercritical pressure in a first heat exchanger down to a temperature below the critical temperature; iv. expanding the gas cooled below the critical temperature to a second pressure between 45 and 60 bara to form a liquid or a two-phase fluid; wherein a part of the liquid or of the two-phase fluid from step iv) supplies cold to the first heat exchanger; and where in the part of the liquid or of the two-phase fluid from step iv) is subcooled to form a subcooled liquid: wherein, if the temperature of the refrigerant of step ii) lessens, the first pressure is reduced and/or, if the temperature of the refrigerant of step ii) increases, the first pressure is increased, and/or if the temperature of the refrigerant of step ii) lessens, the flow of liquid or of two-phase fluid sent to the first heat exchanger is reduced and/or, if the temperature of the refrigerant of step ii) increases, the flow of liquid or of two-phase fluid sent to the first heat exchanger is increased, wherein the first pressure is regulated in order to have one of N pressures, N being an integer between 2 and 5, whatever the temperature of the refrigerant.

2 . The process as claimed in claim 1 , wherein the part of the liquid or of the two-phase fluid which provides cold in the first heat exchanger heats up in the first heat exchanger.

3 . The process as claimed in claim 1 , wherein the part of the liquid or of the two-phase fluid which supplies cold to the first heat exchanger is vaporized in the first heat exchanger and then mixed with the gas to be compressed.

4 . The process as claimed in claim 1 , wherein the part of the liquid or of the two-phase fluid from step iv) is subcooled in a second heat exchanger and sent to be separated in a distillation column and a liquid enriched in carbon dioxide is withdrawn from the distillation column as product.

5 . The process as claimed in claim 4 , wherein a part of the bottom liquid from the distillation column vaporizes in the second heat exchanger and is sent to the compressor in order to be compressed therein with the gas to be separated.

6 . The process as claimed in claim 5 , wherein the part of the liquid or of the two-phase fluid which supplies cold to the first heat exchanger is vaporized in the first heat exchanger, wherein the compressor comprises at least two stages and the vaporized bottom liquid is sent to the compressor at a lower pressure than that at which the liquid vaporized in the first heat exchanger is sent thereto.

7 . The process as claimed in claim 1 , wherein the two-phase fluid from step iv) is separated in a phase separator to form a liquid and a gas wherein at least a part of the gas formed in the phase separator is discharged to the atmosphere.

8 . The process as claimed in claim 7 , wherein, if the gas to be liquefied becomes less rich in carbon dioxide, the flow of gas formed in the phase separator discharged to the atmosphere is increased.

9 . The process as claimed in claim 1 , wherein the two-phase fluid from step iv) is separated in a phase separator to form a liquid and a gas, wherein at least a part of the gas formed in the phase separator is cooled in a second heat exchanger before being sent to a distillation column.

10 . The process as claimed in claim 1 , wherein the two-phase fluid from step iv) is separated in a phase separator to form a liquid and a gas, wherein at least a part of the gas formed in the phase separator is sent to the compressor in order to be compressed therein with the gas to be separated.

11 . The process as claimed in claim 1 , wherein the two-phase fluid from step iv) is separated in a phase separator to form a liquid and a gas, wherein the gas from the phase separator is compressed in the at least two stages of the compressor.

12 . The process as claimed in claim 1 , wherein h the density of the liquid from step iv) or of the two-phase fluid is between 750 and 950 kg/m 3 .

13 . A process for the liquefaction of a gas rich in carbon dioxide, the process comprising the steps of:
i. compressing the gas to a first pressure greater than its critical pressure in a compressor to form a compressed gas; ii. cooling the compressed gas by heat exchange with a refrigerant having a variable temperature to form a cooled compressed gas with a density between 370 and 900 kg/m 3 ; iii. cooling the cooled compressed gas at the supercritical pressure in a first heat exchanger down to a temperature below the critical temperature; iv. expanding the gas cooled below the critical temperature to a second pressure between 45 and 60 bara to form a liquid or a two-phase fluid; wherein a part of the liquid or of the two-phase fluid from step iv) supplies cold to the first heat exchanger; and wherein a part of the liquid or of the two-phase fluid from step iv) is subcooled to form a subcooled liquid: wherein, if the temperature of the refrigerant of step ii) lessens, the first pressure is reduced and/or, if the temperature of the refrigerant of step ii) increases, the first pressure is increased, and/or if the temperature of the refrigerant of step ii) lessens, the flow of liquid or of two-phase fluid sent to the first heat exchanger is reduced and/or, if the temperature of the of refrigerant of step ii) increases, the flow of liquid or of two-phase fluid sent to the first heat exchanger is increased,
wherein, during a first period, the refrigerant is at an average temperature of T° C. and, during a second period, the refrigerant is at an average temperature of T+20° C., such that the density of the liquid from step iv) or of the liquid fraction of the two-phase fluid during the first period differs from that during the second period only by at most 100 kg/m 3 .

Assignees

• Air Liquide

Inventors

• Tran Michael
• Leclerc Mathieu

Classifications

• F25J2270/80

  Quasi-closed internal or closed external carbon dioxide refrigeration cycle · CPC title

• F25J2240/40

  Expansion without extracting work, i.e. isenthalpic throttling, e.g. JT valve, regulating valve or venturi, or isentropic nozzle, e.g. Laval · CPC title

• F25J2230/80

  the fluid being carbon dioxide · CPC title

• F25J2210/80

  Carbon dioxide · CPC title

• F25J2205/04

  in the feed line, i.e. upstream of the fractionation step · CPC title