Integrated pyrolysis and gasification of biomass

Patent metadata

Field	Value
Publication number	US-12540281-B2
Application number	US-202217931577-A
Country	US
Kind code	B2
Filing date	Sep 13, 2022
Priority date	Oct 6, 2021
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

Systems and methods are provided for integrated pyrolysis and gasification of a biomass feed, either as a separate feed or under co-processing conditions. The integrated pyrolysis and gasification can be performed using any convenient reactor configuration, such as fluidized coking reactor configuration or a fluid catalytic cracking reactor configuration. The biomass feed can initially by pyrolyzed to form liquid products, gas phase products, and char. The char can then be used as the input feed to gasification. In aspects where the biomass feed is co-processed, the biomass can be co-processed with a co-feed that is suitable for processing under fluidized coking conditions or other pyrolysis conditions, such as a conventional fluidized coking feedstock.

First claim

What is claimed is:

1 . A method for converting biomass, comprising:
exposing a feed comprising biomass to a fluidized bed comprising solid particles in a reactor under pyrolysis conditions to form i) a liquid pyrolysis product comprising pyrolysis oil, ii) char, coke, or a combination thereof, and iii) a gas phase pyrolysis product, at least a portion of the char, coke, or combination thereof being deposited on the solid particles; passing at least a portion of solid particles comprising deposited char, coke, or a combination thereof from the reactor into a gasifier; introducing an oxygen-containing stream and steam into the gasifier; exposing the at least a portion of the solid particles comprising deposited char, coke, or a combination thereof to partial oxidation conditions in the gasifier to form a gas phase gasifier product comprising CO and CO 2 , and partially gasified particles; and passing at least a portion of the partially gasified particles from the gasifier to the reactor.

2 . The method of claim 1 , wherein the feed comprises 50 wt % or more biomass.

3 . The method of claim 2 , wherein a ratio of a weight of the char, coke, or a combination thereof to a weight of the gas phase gasifier product is 1.6 or more.

4 . The method of claim 1 , wherein the gas phase gasifier product further comprises H 2 .

5 . The method of claim 1 , wherein the feed further comprises a mineral feedstock.

6 . The method of claim 1 , wherein the oxygen-containing stream comprises 45% to 75% of a stoichiometric amount of oxygen to combust the char, coke, or a combination thereof.

7 . The method of claim 1 , wherein the solid particles comprise particles of sand, or wherein the solid particles comprise particles of spent fluid catalytic cracking catalyst, or a combination thereof.

8 . The method of claim 1 , further comprising separating CO 2 from the gas phase gasifier product to form a synthesis gas stream and a CO 2 -containing product.

9 . The method of claim 8 , wherein a portion of the CO 2 -containing product is recycled to the gasifier as a diluent.

10 . The method of claim 1 , wherein the oxygen-containing stream comprises 21 vol % or more of O 2 , or wherein the oxygen-containing stream comprises 50 vol % or less of N 2 , or a combination thereof.

11 . The method of claim 1 , wherein at least a portion of the gas phase pyrolysis product is passed into the reactor as a fluidizing gas for the fluidized bed.

12 . The method of claim 1 , wherein the reactor comprises a fluidized coking reactor.

13 . The method of claim 12 , wherein passing at least a portion of the solid particles comprising deposited char, coke, or a combination thereof from the reactor to the gasifier comprises passing the at least a portion of the solid particles comprising deposited char, coke, or a combination thereof to a heater, and passing the at least a portion of the solid particles comprising deposited char, coke, or a combination thereof from the heater to the gasifier.

14 . The method of claim 12 , wherein passing at least a portion of the partially gasified coke particles from the gasifier to the reactor comprises passing the at least a portion of partially gasified coke particles to a heater, and passing the at least a portion of the partially gasified coke particles from the heater to the reactor.

15 . The method of claim 1 , wherein the partial oxidation conditions comprise a temperature of 650° C. to 1000° C.

16 . The method of claim 1 , wherein the reactor comprises a riser reactor.

17 . The method of claim 16 , wherein the fluidized bed comprises a moving bed, the solid particles in the moving bed comprising a superficial velocity of 10 to 25 m/s.

18 . The method of claim 16 , wherein the partial oxidation conditions comprise a temperature of 650° C. to 760° C.

19 . The method of claim 1 , wherein the feed comprising biomass is exposed to the pyrolysis conditions in the presence of 0.1 vol % or less of added oxygen.

20 . The method of claim 1 , wherein the pyrolysis conditions comprise a temperature of 450° C. to 750° C.

Assignees

• Exxonmobil Technology & Engineering Company
• Exxonmobile Tech And Engineering Company

Inventors

• Bielenberg James R
• Billimoria Rustom M
• Xu Xiaochun
• Sharma Arun K

Classifications

• C10J2300/1815

  for carbon dioxide · CPC title

• C10J2300/1612

  CO2-separation and sequestration, i.e. long time storage · CPC title

• C10J2300/0916

  Biomass · CPC title

• C10G2300/4081

  Recycling aspects · CPC title

• C10G2300/1011

  Biomass · CPC title