Rotomolding composition

Patent metadata

Field	Value
Publication number	US-12540235-B2
Application number	US-202117798510-A
Country	US
Kind code	B2
Filing date	Feb 12, 2021
Priority date	Feb 17, 2020
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

A polyethylene composition suitable for rotomolding and comprising a blend of a stabilized polyethylene, and optionally substantially non-stabilized polyethylene, with a recycled polymer (PCR), is described. By using a PCR with a higher density and lower melt flow as compared to the stabilized polyethylene, a higher portion of the recycled polymer is present on the interior surface the rotomolded part. Oxidation of the recycled polymer results in formation of oxidized species, such as carbonyl groups, on the interior surface of the part, which along with higher surface roughness enhances adhesion between the interior surface and coatings or fillings, such as polyurethane, used to provide a layer of insulation or improve structural strength or buoyancy.

First claim

The invention claimed is:

1 . A polyethylene composition comprising:
a) from 85 to 99 wt % of a stabilized polyethylene having a melt index, I 2 , as measured by ASTM D 1238 at 190° C. using a 2.16 kg load, of from 0.5 to 10 g/10 min; a density as measured by ASTM D792 of from 0.920 to 0.950 g/cc; and b) from 15 to 1 wt % of a recycled polymer having a recycled polymer density greater than the density of the stabilized polyethylene, and a recycled polymer melt index, I 2 , of less than 1 g/10 min.

2 . The polyethylene composition of claim 1 wherein the recycled polymer is chosen from recycled polyethylene or recycled polyolefins.

3 . The polyethylene composition of claim 1 wherein the recycled polymer density is at least 0.01 g/cc higher than the density of the stabilized polyethylene.

4 . The polyethylene composition of claim 1 wherein the recycled polymer melt index is at least 3.0 g/10 min lower than the melt index, I 2 , of the stabilized polyethylene.

5 . The polyethylene composition of claim 1 wherein the recycled polymer has a recycled polymer high load melt index, I 21 , that is at least 40 g/10 min lower than a high load melt index, I 21 , of the stabilized polyethylene.

6 . The polyethylene composition of claim 1 wherein the stabilized polyethylene contains a stabilizer package comprising one or both of:
a) a primary antioxidant in an amount of from 250 to 1500 parts per million by weight, and
b) a secondary antioxidant in an amount of from 250 to 1500 parts per million by weight.

7 . A process to prepare a rotomolded part comprising
a) preparing a polymer composition according to claim 1 ; and b) subjecting the polymer composition to rotational molding, wherein the rotomolded part has an interior surface and an exterior surface.

8 . The process of claim 7 wherein the interior surface has a higher surface roughness than the exterior surface.

9 . The process of claim 7 wherein the rotational molding is undertaken at a temperature of from 250° C. to 400° C.

10 . The process of claim 7 wherein the interior surface is characterized by having carbonyl functional groups that are detectable by a Fourier Transform Infrared instrument.

11 . A polyethylene composition comprising:
a) a stabilized polyethylene having a melt index, I 2 , as measured by ASTM D123 8 at 190° C. using a 2.16 kg load, of from 0.5 to 10 grams/10 minutes; a density as measured by ASTM D792 of from 0.920 to 0.950 g/cc; b) a substantially non-stabilized polyethylene having i) a high load melt index, I 21 , as measured by ASTM D1238 at 190° C. using a 21.6 kg load, of from 2 to 20 grams/10 minutes; ii) a density of from 0.950 to 0.965 g/cc as measured by ASTM D792; and iii) an average particle size of from 500 to 3000 microns; and c) a recycled polymer having a recycled polymer density greater than the density of the stabilized polyethylene, and a recycled polymer melt index, I 2 , of less than 1 g/10 min.

12 . The polyethylene composition of claim 11 wherein the stabilized polyethylene is at least 70 wt % and the recycled polymer does not exceed 15 wt %.

13 . The polyethylene composition of claim 11 wherein the average particle size of the stabilized polyethylene is smaller than the average particle size of the substantially non-stabilized polyethylene.

14 . The polyethylene composition of claim 11 wherein the substantially non-stabilized polyethylene has a high load melt index, I 21 , as measured by ASTM D1238 at 190° C. using a 21.6 kg load, of from 3 to 6 grams per 10 minutes.

15 . The polyethylene composition of claim 11 wherein the stabilized polyethylene contains a stabilizer package comprising one or both of:
a) a primary antioxidant in an amount of from 250 to 1500 parts per million by weight, and
b) a secondary antioxidant in an amount of from 250 to 1500 parts per million by weight.

16 . A process to prepare a rotomolded part comprising:
a) preparing a polymer composition according to claim 11 ; and b) subjecting the polymer composition to rotational molding, wherein the rotomolded part has an interior surface and an exterior surface.

17 . The process of claim 16 wherein the rotational molding is undertaken at a temperature of from 250° C. to 400° C.

18 . The process of claim 16 wherein the interior surface has a surface roughness of from 10 microns to 30 microns.

19 . The process of claim 18 wherein the surface roughness is from 12 to 20 microns.

20 . The process of claim 16 wherein the interior surface is further characterized by having carbonyl functional groups that are detectable by a Fourier Transform Infrared instrument.

Assignees

• Nova Chemicals International Sa

Inventors

• D'Agostino Carmine
• Arnould Gilbert

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L23/06 Primary

  Polyethylene · CPC title

• B29K2105/26

  Scrap {or recycled material} · CPC title

• B29C41/04

  Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould · CPC title

• C08L2207/20

  Recycled plastic · CPC title