Bipolar membrane

Patent metadata

Field	Value
Publication number	US-12540202-B2
Application number	US-202117904995-A
Country	US
Kind code	B2
Filing date	Apr 1, 2021
Priority date	Apr 2, 2020
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

Bipolar membranes (BPMs) comprising a cation exchange layer (CEL) and an anion exchange layer (AEL) wherein the colour properties of the CEL are visibly different to the colour properties of the AEL. The CEL and the AEL are easily distinguishable so that a stack of membranes comprising the BPMs can be built fast and without mistakes in layer order.

First claim

The invention claimed is:

1 . A bipolar membrane (BPM) comprising a cation exchange layer (CEL) and an anion exchange layer (AEL) wherein at least one of the CEL and AEL contains a dye which is a photoinitiator and the colour properties of the CEL are visibly different to the colour properties of the AEL, wherein the dye is free from transition metal ions.

2 . The BPM according to claim 1 wherein the dye which is a photoinitiator is a Norrish Type II photoinitiator having an absorption maximum at a wavelength longer than 400 nm, when measured at a temperature of 23° C. in one or more of the following solvents: water, ethanol and toluene.

3 . The BPM according to claim 1 wherein the AEL and CEL are free from dyes which form ions when irradiated with light.

4 . The BPM according to claim 1 wherein the AEL and CEL each contain a dye and the dye present in the AEL is different to or is the same as the dye present in the CEL.

5 . The BPM according to claim 1 wherein the visible difference in colour properties comprises a difference in ΔE 00 , as expressed according to CIEDE2000, of at least 4.

6 . The BPM according to claim 1 wherein at least one of the AEL and CEL has a lightness, as expressed by L′ according to CIEDE2000, of less than 90 and at least 10.

7 . The BPM according to claim 1 wherein at least one of the AEL and CEL has a saturation, as expressed by chroma C′ according to CIEDE2000, of at least 5.

8 . The BPM according to claim 1 wherein the colour properties of the AEL and/or the CEL are substantially homogeneous.

9 . The BPM according to claim 1 which is free from perfluorinated polymers.

10 . The BPM according to claim 1 wherein the CEL and/or the AEL is obtained by curing a curable composition comprising a dye which functions as a photoinitiator, and a co-initiator which can generate a free radical in reaction with the dye when the dye is in an electronic excited state.

11 . The BPM according to claim 1 wherein said dye is not covalently bound to the AEL or CEL.

12 . The BPM according to claim 1 wherein:
the visible difference in color properties between the AEL and CEL make the layers distinguishable by human eye and by automatic sensors;
the dye has a molar attenuation coefficient at the absorption maximum of at least 7,500 M −1 cm −1 ; and
the dye comprises a conjugated system having at least 10 delocalized electrons.

13 . The BPM according to claim 1 wherein the visible difference in color properties between the AEL and CEL make the layers distinguishable by human eye and by automatic sensors.

14 . The BPM according to claim 1 wherein the dye has a molar attenuation coefficient at the absorption maximum of at least 7,500 M −1 cm −1 .

15 . The BPM according to claim 1 wherein the dye comprises a conjugated system having at least 10 delocalized electrons.

16 . An electrochemical device comprising the BPM according to claim 1 .

17 . A process for manufacturing a bipolar membrane comprising a cation exchange layer (CEL) and an anion exchange layer (AEL) wherein the colour properties of the CEL are visibly different to the colour properties of the AEL, the process comprising curing, in either order or simultaneously, a first curable composition to form the AEL and curing a second curable composition to form the CEL, wherein at least one of the first curable composition and the second curable composition contains a dye which is a photoinitiator.

18 . The process according to claim 17 wherein the dye has an absorption maximum at a wavelength longer than 400 nm, when measured at a temperature of 23° C. in one or more of the following solvents: water, ethanol and toluene.

19 . The process according to claim 17 wherein one or both of the first curable composition and the second curable composition comprises:
a. one or more curable monomers comprising at least one anionic or cationic group;
b. a dye which is a photoinitiator;
c. optionally a co-initiator;
d. optionally a curable monomer which is free from anionic and cationic groups; and
e. optionally a solvent.

20 . The process according to claim 17 wherein both the first curable composition and the second curable composition comprise a dye which is a photoinitiator and the dye present in the first curable composition has a different chemical formula to the dye present in the second curable composition.

Assignees

• Fujifilm Mfg Europe Bv
• Fujifilm Corp

Inventors

• Van Rijen Adrianus Jacobus
• Martinez Elisa Huerta

Classifications

• C08J5/2206

  based on organic and/or inorganic macromolecular compounds · CPC title

• B01D61/445

  with bipolar membranes; Water splitting · CPC title

• C08F2/50 Primary

  with sensitising agents · CPC title

• Y02E60/50

  Fuel cells · CPC title

• C08F220/38

  Esters containing sulfur · CPC title