Ammonium nitrate reactor with static mixer

Patent metadata

Field	Value
Publication number	US-12539501-B2
Application number	US-202418868096-A
Country	US
Kind code	B2
Filing date	Sep 9, 2024
Priority date	Sep 8, 2023
Publication date	Feb 3, 2026
Grant date	Feb 3, 2026

Abstract

The disclosure pertains to an ammonium nitrate reactor with a first type static mixer in the mixing zone upstream of the tube bundle and/or a second type static mixer downstream of the tube bundle.

First claim

The invention claimed is:

1 . A reaction unit for the production of ammonium nitrate by neutralization of aqueous nitric acid with gaseous NH 3 , the reaction unit comprising:
an inlet zone comprising a first inlet for a stream of recirculated ammonium nitrate solution and a second inlet for the aqueous nitric acid; a mixing zone located downstream of said inlet zone, said mixing zone comprising a first type static mixer adapted to mix the recirculated ammonium nitrate solution with the aqueous nitric acid to form a liquid mixture; a shell-and-tube chamber comprising tube bundle and a shell space wherein the shell space comprises an inlet for gaseous NH 3 , wherein a tube of the tube bundle has a tube wall, an inlet tube end and an outlet tube end and is configured for receiving the liquid mixture from the mixing zone through the inlet tube end, and comprises perforations in the tube wall to allow gaseous NH 3 from the shell space to enter the tube; and a reaction zone downstream of the outlet end of the tube, wherein said first type static mixer in the mixing zone upstream of the tube bundle comprises: a flow-diverting plate which extends in a transversal direction perpendicular to the general liquid flow direction in the mixing zone and wherein in operation liquid impinges on the flow-diverting plate; a first aperture in the flow-diverting plate, a circumferential flange around the first aperture, wherein said flange extends perpendicular to the plate and has a first end that is joined to the plate and an opposite second end; and a transversal element, extending substantially parallel to the plate and joined to said second end of the circumferential flange; such that the transversal element and the flange together provide a cup-like structure around the first aperture;
wherein the circumferential flange comprises a plurality of second apertures, wherein each second aperture provides a smaller flow area than said first aperture.

2 . A reactor comprising the reaction unit according to claim 1 , and
a gas/liquid separation zone receiving an effluent from the reaction unit, a liquid flow line from said separation zone to an inlet of the reaction unit for recirculation of ammonium nitrate solution to said first inlet of the inlet zone; a gas outlet for gas from the separation zone; and a liquid outlet for product AN solution from the separation zone.

3 . The reactor according to claim 2 , wherein the reactor comprises a pressure reduction means, between the reaction zone and the gas/liquid separation zone; and a pump in the liquid flow line for recirculated AN solution.

4 . The reactor according to claim 3 , wherein pressure reduction means is a restriction orifice or valve between the reaction zone and the gas/liquid separation zone.

5 . The reaction unit according to claim 1 , wherein the transversal element comprises a third aperture, wherein the third aperture provides a smaller flow area than said first aperture.

6 . The reaction unit according to claim 5 , wherein the transversal element comprises a plurality of third apertures.

7 . The reaction unit according to claim 1 , wherein the total flow area of the apertures in the flange and in the transversal element is at least 80% of the flow area of the first aperture.

8 . The reaction unit according to claim 7 , wherein the total flow area of the apertures in the flange and in the transversal element is at least 100% of the flow area of the first aperture.

9 . The reaction unit according to claim 1 , wherein the transversal element and the flange together provide a perforated mixing cup.

10 . The reaction unit according to claim 1 , wherein the second apertures in the flange are configured to provide for a swirling motion of the liquid mixture in the transversal plane parallel to the plate, which swirling motion is diverging or converging.

11 . The reaction unit according to claim 1 , wherein the second aperture is a skewed hole in the flange, wherein the second aperture is an aperture that is at a non-zero angle relative to a local normal of the flange at the position of the second aperture.

12 . The reaction unit according to claim 1 , wherein the reaction zone comprises a second type static mixer.

13 . A process for the production of ammonium nitrate by neutralization of aqueous nitric acid with gaseous NH 3 carried out in a reaction unit according to claim 2 .

14 . A reaction unit for the production of ammonium nitrate by neutralization of aqueous nitric acid with gaseous NH 3 , the reaction unit comprising:
an inlet zone comprising a first inlet for a stream of recirculated ammonium nitrate solution and a second inlet for the aqueous nitric acid; a mixing zone located downstream of said inlet zone; a shell-and-tube chamber comprising tube bundle and a shell space wherein the shell space comprises an inlet for gaseous NH 3 , wherein a tube of the tube bundle has a tube wall, an inlet tube end and an outlet tube end and is configured for receiving the liquid mixture from the mixing zone through the inlet tube end, and wherein said tube comprises perforations in the tube wall to allow gaseous NH 3 from the shell space to enter the tube; and a reaction zone downstream of the outlet end of the tube, wherein the reaction zone comprises a static mixer, wherein the static mixer is provided downstream of the outlet tube ends, wherein the reaction zone has a generally vertically upward flow direction, and wherein the static mixer comprises: a horizontal gas redistribution plate provided with a liquid passageway and a gas vent hole, wherein the liquid passageway is provided with a flange extending downward from a perimeter of the liquid passageway, wherein the plate and flange together provide an interstice configured for collecting gas from the outlet tube ends in a gas layer or cushion below the gas redistribution plate.

15 . A reactor comprising the reaction unit according to claim 14 , and
a gas/liquid separation zone receiving an effluent from the reaction unit, a liquid flow line from said separation zone to an inlet of the reaction unit for recirculation of ammonium nitrate solution to said first inlet of the inlet zone; a gas outlet for gas from the separation zone; and a liquid outlet for product AN solution from the separation zone.

16 . The reactor according to claim 15 , wherein the reactor comprises a pressure reduction means, between the reaction zone and the gas/liquid separation zone; and a pump in the liquid flow line for recirculated AN solution.

17 . The reactor according to claim 16 , wherein the pressure reduction means is a restriction orifice or valve between the reaction zone and the gas/liquid separation zone.

18 . The reaction unit according to claim 14 , wherein the horizontal gas redistribution plate comprises a plurality of said liquid passageways and a plurality of said gas vent holes, wherein the total flow area of the gas vent holes is less than 5% of the total flow area of the liquid passageways, and wherein each of said liquid passageways of the horizontal gas redistribution plate is provided with one of said flanges.

19 . The reaction unit according to claim 18 , wherein the flanges each extend at least 5 cm down from the gas redistribution plate.

20 . The reaction unit according to claim 18 , wherein the total flow area of the gas vent holes is less than 1% of the total flow area of the liquid passageways.

21 . The reaction unit according to cl

Assignees

• Stamicarbon

Inventors

• Patil Rahul
• Gevers Lambertus Wilhelmus
• Wassie Solomon Assefa
• Tsopozidis Michail

Classifications

• B01J2219/00162

  controlling the pressure · CPC title

• B01J2204/002

  the feeding side being of particular interest · CPC title

• C01C1/185

  Preparation · CPC title

• B01J19/002

  Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions · CPC title

• B01J10/00

  Chemical processes in general for reacting liquid with gaseous media other than in the presence of solid particles, or apparatus specially adapted therefor (B01J19/08 takes precedence; separation, e.g. distillation, also combined with chemical reactions B01D, {e.g. B01D3/009}) · CPC title