Battery cells comprising elastic compressible functional layers and manufacturing process

Patent metadata

Field	Value
Publication number	US-12537202-B2
Application number	US-201917294957-A
Country	US
Kind code	B2
Filing date	Dec 5, 2019
Priority date	Dec 6, 2018
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

The present disclosure concerns a rechargeable battery cell comprising a compressible elastic composite material to form one or more of: a compressible and elastic first current collector; and a compressible and elastic positive electrode; and a compressible and elastic solid state electrolyte; and a compressible and elastic negative electrode; and a compressible and elastic second current collector, wherein the compressible elastic composite material comprises a plurality of compressible pores.

First claim

The invention claimed is:

1 . A rechargeable battery cell comprising a functional layer made of a compressible elastic composite material comprising compressible pores, wherein the functional layer is taken from the group consisting of:
a compressible and elastic first current collector; and a compressible and elastic second current collector; wherein the compressible elastic composite material is configured to, at least in part, counteract compressive and/or tensile forces within the rechargeable battery cell resulting from volume changes in a negative electrode and/or a positive electrode during charging and/or discharging the rechargeable battery cell, wherein the compressible pores are at least in part provided by hollow latex beads having a volumetric core to shell ratio in a range from 5 to 0.05, and having a diameter in a range between 50 nanometers and 5 micrometers, and wherein the compressible pores have a diameter that is:
less than 20% of a thickness of the functional layer made of a compressible elastic composite material comprising compressible pores, and
in a range between 1 micrometer and 50 nanometers; and
wherein the compressible pores are homogeneously dispersed throughout the compressible elastic composite material, and wherein the compressible elastic composite material is electrically conductive.

2 . The rechargeable battery cell according to claim 1 , wherein one or more of the first compressible and elastic current collector and the second compressible and elastic current collector comprises the compressible elastic composite material and an electronic electronically conductive material, thereby providing a compressible characteristic.

3 . The rechargeable battery cell according to claim 2 , wherein the one or more of the first compressible and elastic current collector and the second compressible and elastic current collector comprises an electrically conductive capping.

4 . The rechargeable battery cell according to claim 2 , wherein the one or more of the first compressible and elastic current collector and the second compressible and elastic current comprises, at least in part, a conductive metal film providing homogeneous conductivity along an electrode material interface.

5 . The rechargeable battery cell according to claim 1 , wherein:
a stack of functional layers forms a planar structure, or the rechargeable battery cell is formed of a base current collecting structure comprising an array of conductive elements spaced at a distance from one another and extending in a direction away from said base, and wherein at least one of the electrode and solid state electrolyte is provided between said elements.

6 . The rechargeable battery cell according to claim 1 , comprising at least one rigid external current collector.

Assignees

• TNO

Inventors

• Tulodziecki Michal
• Unnikrishnan Sandeep
• Vercauteren Franky Flory
• Haverkate Lucas Augustinus

Classifications

• H01M2300/0065

  Solid electrolytes · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• H01M4/64

  Carriers or collectors · CPC title

• H01M4/139

  Processes of manufacture · CPC title