Cyclization and fluid catalytic cracking systems and methods for upgrading naphtha

Patent metadata

Field	Value
Publication number	US-12534674-B2
Application number	US-202418611326-A
Country	US
Kind code	B2
Filing date	Mar 20, 2024
Priority date	Jan 15, 2021
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

A process for upgrading a naphtha feed includes separating the naphtha feed into at least a light naphtha fraction, contacting the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst, and contacting the cyclization effluent with at least one cracking catalyst. Contacting the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst may produce a cyclization effluent comprising a greater concentration of naphthenes compared to the light naphtha fraction. Contacting the cyclization effluent with at least one cracking catalyst under conditions sufficient crack at least a portion of the cyclization effluent may produce a fluid catalytic cracking effluent comprising light olefins, gasoline blending components, or both. A system for upgrading a naphtha feed includes a naphtha separation unit, a cyclization unit disposed downstream of the naphtha separation unit, and a fluid catalytic cracking unit disposed downstream of the cyclization unit.

First claim

What is claimed is:

1 . A system for upgrading a naphtha feed, the system comprising:
a naphtha separation unit operable to separate a naphtha feed into at least a light naphtha fraction and a heavy naphtha fraction; a cyclization unit comprising at least one cyclization catalyst, wherein the at least one cyclization catalyst comprises Y-type (USY) zeolite, and wherein the cyclization unit is disposed downstream of the naphtha separation unit and operable to contact the light naphtha fraction with hydrogen in the presence of at least one cyclization catalyst to produce a cyclization effluent; a fluid catalytic cracking unit disposed downstream of the cyclization unit and operable to crack the cyclization effluent to produce a fluid catalytic cracking effluent; and a naphtha reforming unit comprising at least one reforming catalyst, wherein the at least one reforming catalyst consists of:
a precious metal selected from the group consisting of platinum, palladium, and combinations thereof; and
a catalyst support selected from the group consisting of alumina, silica, titania. and combinations thereof,
wherein the naphtha reforming unit is disposed downstream of the naphtha separation unit, and the naphtha reforming unit operable to contact at least a portion of the heavy naphtha fraction with the at least one reforming catalyst to produce a naphtha reformate.

2 . The system of claim 1 , further comprising a desulfurization unit disposed upstream of the naphtha separation unit operable to contact the naphtha feed at least one desulfurization catalyst to produce a desulfurized naphtha feed.

3 . The system of claim 1 , further comprising an aromatic recovery complex disposed downstream of the fluid catalytic cracking unit and the naphtha reforming unit and operable to separate at least a portion of the fluid catalytic cracking effluent, at least a portion of the naphtha reformate, or both into benzene, toluene, xylene, or combinations of these.

4 . The system of claim 3 , wherein the aromatic recovery complex comprises:
a reformate splitter operable to separate at least the naphtha reformate into a light reformate stream and a heavy reformate stream; a benzene extraction unit operable to extract benzene from the light reformate stream, wherein the benzene extraction unit is disposed downstream of the reformate splitter.

5 . The system of claim 4 , further comprising:
a para-xylene recovery unit operable to separate the heavy reformate stream into at least para-xylenes and mixed xylenes; and a xylene isomerization unit operable to isomerize at least a portion of the mixed xylenes to produce an isomerization effluent.

6 . The system of claim 5 , wherein the mixed xylenes comprise at least ortho-xylene, meta-xylene, or both.

7 . The system of claim 5 , wherein the para-xylene recovery unit is operable to further separate the heavy reformate stream into a C 7 cut mogas stream.

8 . The system of claim 1 , wherein the cyclization unit is in direct fluid communication with the naphtha separation unit and the fluid catalytic cracking unit.

9 . The system of claim 1 , wherein the fluid catalytic cracking unit comprises:
a reactor operable to crack the cyclization effluent to produce the fluid catalytic cracking effluent and spent catalyst; and a catalyst regeneration unit operable to regenerate the spent catalyst.

10 . The system of claim 1 , further comprising an FCC separation unit operable to separate at least a portion of the fluid catalytic cracking effluent into at least one light gas fraction, a light naphtha recycle fraction, an aromatic containing effluent, and a light olefin fraction, wherein the FCC separation unit is disposed downstream of the fluid catalytic cracking unit.

11 . The system of claim 10 , wherein the light gas fraction comprises at least hydrogen, methane, or both.

12 . The system of claim 10 , wherein the light naphtha recycle fraction comprises at least C 5 hydrocarbons and C 6 hydrocarbons.

13 . The system of claim 10 , wherein the aromatic containing effluent comprises at least C 7+ hydrocarbons.

14 . The system of claim 10 , wherein the light olefin fraction comprises at least ethylene, propene, butene, or combinations of these.

Assignees

• Saudi Arabian Oil Co

Inventors

• Koseoglu Omer Refa

Classifications

• C10G2400/30

  Aromatics · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G2400/02

  Gasoline · CPC title

• C10G2300/4018

  Spatial velocity, e.g. LHSV, WHSV · CPC title

• C10G2300/4012

  Pressure · CPC title