Linear low density polyethylene for film applications

Patent metadata

Field	Value
Publication number	US-12534582-B2
Application number	US-202117997113-A
Country	US
Kind code	B2
Filing date	Apr 23, 2021
Priority date	May 1, 2020
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

The present disclosure generally relates to catalyst systems, polyethylene compositions, and uses of such compositions in, e.g., films. In an embodiment is provided a film that includes a polyethylene composition, comprising: ethylene and a C 3 -C 40 olefin comonomer, the polyethylene composition having at least 65 wt % ethylene content and from 0 wt % to 35 wt % of a C 3 -C 40 olefin comonomer content based upon the total weight of the composition, the film having: an average of MD and TD 1% secant modulus of 43,000 psi or greater, and a Dart Drop Impact Strength of greater than 500 g/mil. In another embodiment is provided a process for producing a polyethylene composition that includes introducing ethylene and a C 3 -C 40 alpha-olefin to a catalyst system, the catalyst system comprising a first catalyst compound, a second catalyst compound, and an activator; and forming a polyethylene composition.

First claim

What is claimed is:

1 . A film, comprising:
a polyethylene composition, comprising:
ethylene and a C 3 -C 40 olefin comonomer, the polyethylene composition having at least 65 wt % ethylene content and from 0 wt % to 35 wt % of a C 3 -C 40 olefin comonomer content based upon the total weight of the composition as determined by GPC-IR5-LS-VIS, the film having:
an average of MD and TD 1% secant modulus of 43,000 psi or greater, as determined by ASTM D882, and
a Dart Drop Impact Strength of greater than 500 g/mil, as determined by ASTM D1709;
wherein the polyethylene composition has:
a melt index ratio (I 21 /I 2 ) of 18 to 35, wherein I 21 and I 2 are determined by ASTM 1238;
a density of from 0.917 g/cm 3 to 0.94 g/cm 3 as determined by ASTM 1505;
a g′ vis of from 0.9 to 0.97, as determined by GPC-IR5-LS-VIS;
a weight average molecular weight (Mw) of from 75,000 g/mol to 200,000 g/mol, as determined by GPC-IR5-LS-VIS;
a number average molecular weight (Mn) of from 5,000 g/mol to 15,000 g/mol, as determined by GPC-IR5-LS-VIS;
a z-average molecular weight (Mz) of from 500,000 g/mol to 1,800,000 g/mol, as determined by GPC-IR5-LS-VIS; and
a molecular weight distribution (Mw/Mn) of from 2 to 8, as determined by GPC-IR5-LS-VIS.

2 . The film of claim 1 , wherein the C 3 -C 40 olefin comonomer content is from 4 wt % to 10 wt % based upon the total weight of the polyethylene composition, as determined by GPC-IR5-LS-VIS.

3 . The film of claim 1 , wherein the C 3 -C 40 olefin comonomer is propylene, 1-butene, 4-methyl-1-pentene, 3-methyl-1-pentene, 1-hexene, 1-octene, or a combination thereof.

4 . The film of claim 1 , wherein the C 3 -C 40 olefin comonomer is 1-hexene.

5 . The film of claim 1 , wherein the average of MD and TD 1% secant modulus is from 43,000 psi to 68,000 psi.

6 . The film of claim 1 , wherein the Mw/Mn is from 3 to 7.

7 . The film of claim 1 , wherein the film has one or more of the following properties:
a 1% Secant Modulus (MD) of from 38,000 psi to 58,000 psi, as determined by ASTM D882 (25.4 mm width strip); or a 1% Secant Modulus (TD) of from 50,000 psi to 80,000 psi, as determined by ASTM D882 (25.4 mm width strip).

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Xie Ru
• Holtcamp Matthew W
• Fiscus David M
• Li Dongming
• Mccullough Laughlin G
• Bedoya Matthew S
• Stevens Kevin A
• Jiang Yan
• Moebus Joseph A

Classifications

• C08J2323/08

  Copolymers of ethene (C08J2323/16 takes precedence) · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F210/14

  Monomers containing five or more carbon atoms · CPC title

• C08F210/02

  Ethene · CPC title

• C08J5/18 Primary

  Manufacture of films or sheets · CPC title