Monomer for polymer gel, polymer gel and preparation therefor

Patent metadata

Field	Value
Publication number	US-12534430-B2
Application number	US-202118011433-A
Country	US
Kind code	B2
Filing date	Feb 1, 2021
Priority date	Feb 1, 2021
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

Disclosed are a monomer for a polymer gel, a polymer gel and a preparation method therefor. The preparation method includes: reacting 4,4′,4″-trihydroxytriphenylmethane with tert-butyldimethylchlorosilane to obtain TPC-OTBS; reacting 4,4′,4″-trihydroxy triphenylmethane with sulfuryl fluoride in the presence of triethylamine to prepare TPC-OSO 2 F; and dissolving the TPC-OTBS and TPC-OSO 2 F in DMF, then adding DBU and ultrasonically dispersing same until uniform, and letting same stand to obtain a polymer gel. The gel obtained by the present invention can selectively adsorb an organic solvent by means of electrostatic interaction and Van der Waals force. The surface and internal morphologies of a solid material are characterized by SEM and TEM, in which the porous morphology of the solid material is found, and most of the pores are macropores.

First claim

The invention claimed is:

1 . A method of preparing TPC-OTBS or TPC-OSO 2 F:

comprising:
in the presence of imidazole, reacting 4,4′,4″-trihydroxytriphenylmethane with tert-butyldimethylchlorosilane to prepare the TPC-OTBS; or
in the presence of triethylamine, reacting 4,4′,4″-trihydroxytriphenylmethane with sulfuryl fluoride to prepare the TPC-OSO 2 F.

2 . The method according to claim 1 , wherein a molar ratio of 4,4′,4″-trihydroxytriphenylmethane, tert-butyldimethylsilyl chloride and imidazole is 1:(3-4):(3-4); a molar ratio of 4,4′,4″-trihydroxytriphenylmethane and triethylamine is 1:(3-4); and the reaction of 4″-trihydroxytriphenylmethane and tert-butyldimethylchlorosilane and the reaction of, 4′,4″-trihydroxytriphenylmethane and sulfuryl fluoride are carried out at room temperature.

3 . The method according to claim 1 , further comprising the step of preparing a polymer gel by dissolving TPC-OTBS and TPC-OSO 2 F in dimethylformamide to form a mixture; adding 1,8-diazabicyclo(5.4.0)undec-7-ene to the mixture as a catalyst; and letting the mixture to react at room temperature to obtain a polymer gel.

4 . The method according to claim 3 , wherein a ratio of TPC-OSO 2 F, DMF and DBU is (190-210 mg):(1-4.5 mL):50 μg; and a molar ratio of TPC-OSO 2 F and TPC-OTBS is 1:(0.9-1.1).

5 . The method according to claim 4 , wherein the molar ratio of TPC-OSO 2 F and TPC-OTBS is 1:1.

Assignees

• Univ Soochow

Inventors

• Lu Jianmei
• Xu Qingfeng

Classifications

• C07F7/188 Primary

  by reactions involving the formation of Si-O linkages · CPC title

• C07F7/1804

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title

• C07C303/24

  of esters of sulfuric acids · CPC title

• C07C305/26 Primary

  Halogenosulfates, i.e. monoesters of halogenosulfuric acids · CPC title

• C08G75/24

  Polysulfonates · CPC title