Preceramic interfacial and support structures for inorganic material printing and methods thereof

Patent metadata

Field	Value
Publication number	US-12533852-B2
Application number	US-202318471475-A
Country	US
Kind code	B2
Filing date	Sep 21, 2023
Priority date	Sep 21, 2023
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

A system and method of additive manufacturing includes i) forming a first layer, the first layer may include at least one material chosen from an article material, a support structure material and an interfacial material. The method also includes ii) forming an additional layer on the first layer, the additional layer may include at least one material chosen from the article material, the support structure material and the interfacial material. The method also includes iii) repeating ii) one or more times to form a three-dimensional build may include an article and at least one support structure attached to the article at an interface, the interface may include the interfacial material formed during one or more of i), ii) or iii), and the interfacial material may include a preceramic. An interfacial material may include a preceramic or further include carbon, aluminum oxide, or silicon carbide.

First claim

What is claimed is:

1 . A method of additive manufacturing, the method comprising:
i) forming a first layer, the first layer comprising at least one material chosen from an article material, a support structure material and an interfacial material; ii) forming an additional layer on the first layer, the additional layer comprising the interfacial material; iii) repeating ii) one or more times to form a three-dimensional build comprising an article and at least one support structure attached to the article at an interface, the interface comprising the interfacial material formed during one or more of i), ii) or iii), the interfacial material comprising a preceramic; and iv) conditioning the preceramic interfacial material to transform the preceramic material from an organic structure to an inorganic structure; and wherein:
the conditioning is applied layer by layer.

2 . The method of additive manufacturing of claim 1 , further comprising pyrolyzing the interfacial material after forming the additional layer.

3 . The method of additive manufacturing of claim 1 , wherein the conditioning further comprises heating in an inert environment at a temperature from about 300° C. to about 900° C.

4 . The method of additive manufacturing of claim 1 , wherein the interfacial material comprises benzoxazine.

5 . The method of additive manufacturing of claim 1 , wherein the interfacial material comprises an inorganic filler.

6 . The method of additive manufacturing of claim 5 , wherein the inorganic filler comprises aluminum oxide.

7 . The method of additive manufacturing of claim 1 , wherein the article material comprises a metal.

8 . The method of additive manufacturing of claim 1 , wherein the article material comprises a material chosen from glass, salt, or a combination thereof.

9 . The method of additive manufacturing of claim 1 , wherein the interfacial material is deposited by ejection.

10 . The method of additive manufacturing of claim 1 , further comprising removing a portion of the article from another portion of the article at an interface location.

11 . The method of additive manufacturing of claim 2 , wherein pyrolyzing the interfacial material is conducted at a higher temperature as compared to forming the article.

12 . The method of additive manufacturing of claim 1 , wherein the support structure material comprises a metal, a glass, a salt, or a combination thereof.

13 . An additive manufacturing system, comprising:
a reservoir configured to receive and melt a print material; an ejector having a nozzle that is fluidly connected to the reservoir to receive melted print material from the reservoir; a platform positioned opposite the ejector; at least one actuator operatively connected to at least one of the platform and the ejector, the at least one actuator being configured to move the at least one of the platform and the ejector relative to one another; and a controller operatively connected to the reservoir, the ejector, and the at least one actuator, the controller being configured to: i) form a first layer, the first layer comprising at least one material chosen from an article material, a support structure material and an interfacial material; ii) form an additional layer on the first layer, the additional layer comprising the interfacial material; iii) repeat ii) one or more times to form a three-dimensional build comprising an article and at least one support structure attached to the article at an interface, the interface comprising the interfacial material formed during one or more of i), ii) or iii), the interfacial material comprising a preceramic; and iv) conditioning the preceramic interfacial material to transform the preceramic material from an organic structure to an inorganic structure; and wherein:
the conditioning is applied layer by layer.

14 . The additive manufacturing system of claim 13 , wherein the controller is further configured to pyrolyze the interfacial material after forming the additional layer.

15 . The additive manufacturing system of claim 13 , wherein the interfacial material comprises benzoxazine.

16 . The additive manufacturing system of claim 13 , wherein the interfacial material comprises an inorganic filler.

Assignees

• Xerox Corp

Inventors

• Wei Junhua
• Anderson Gregory Brian
• Bullard Daniel
• Johnson David Mathew

Classifications

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• B33Y30/00

  Apparatus for additive manufacturing; Details thereof or accessories therefor · CPC title

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B29C64/40

  Structures for supporting 3D objects during manufacture and intended to be sacrificed after completion thereof · CPC title

• B29C64/295

  Heating elements · CPC title