Functionalized silica nanoparticles for lead adsorption

Patent metadata

Field	Value
Publication number	US-12533653-B2
Application number	US-202519202663-A
Country	US
Kind code	B2
Filing date	May 8, 2025
Priority date	May 21, 2024
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

A method for preparing silica nanoparticles, the method comprising: adding centrimonium bromide (CTAB) to a water and ethanol to create a first reaction mixture; adding NH4OH to the reaction mixture to create a second reaction mixture; adding a first amount of tetraethyl orthosilicate (TEOS) to the second reaction mixture to create a third reaction mixture; adding ethylenediaminetetraacetic acid (EDTA) to the third reaction mixture then adding a second amount of TEOS to create a fourth reaction mixture; obtaining formed silica spheres; separating the formed silica spheres; washing the formed silica spheres with water and ethanol; and drying the formed silica spheres in an oven for at least about 8 hours to obtain silica nanoparticles.

First claim

We claim:

1 . Functionalized silica nanoparticles prepared according to a method comprising:
combining centrimonium bromide (CTAB) with water and ethanol to create a first reaction mixture; stirring the first reaction mixture; adding NH 4 OH to the first reaction mixture to create a second reaction mixture; stirring the second reaction mixture; adding a first amount of tetraethyl orthosilicate (TEOS) to the second reaction mixture to create a third reaction mixture; stirring the third reaction mixture; adding ethylenediaminetetraacetic acid (EDTA) and a second amount of TEOS to the third reaction mixture to provide a fourth reaction mixture; stirring the fourth reaction mixture to obtain formed silica spheres; separating the formed silica spheres; washing the formed silica spheres with water and ethanol; and drying the formed silica spheres in an oven to provide functionalized silica nanoparticles.

2 . The functionalized silica nanoparticles of claim 1 , wherein about 1 gram of CTAB is combined with about 200 mL water and about 100 mL ethanol.

3 . The functionalized silica nanoparticles of claim 1 , wherein about 20 mL NH 4 OH is added to the first reaction mixture.

4 . The functionalized silica nanoparticles of claim 1 , wherein the first amount of TEOS comprises about 1000 μL and the TEOS is added in about five 200 μL increments and each of the about five increments is added at least about every 10 minutes.

5 . The functionalized silica nanoparticles of claim 1 , wherein about 50 mL of EDTA having a concentration of about 1000 mg/L is added to the third reaction mixture.

6 . The functionalized silica nanoparticles of claim 1 , wherein the second amount of TEOS is about 1000 μL and is added in about two 500 μL increments and each of the about two increments is added at least about every 30 minutes.

7 . The functionalized silica nanoparticles of claim 1 , wherein the formed silica spheres are separated by centrifuge.

8 . The functionalized silica nanoparticles of claim 1 , wherein the formed silica spheres are dried in an oven for at least about 8 hours.

9 . The functionalized silica nanoparticles of claim 1 , further comprising mixing the silica nanoparticles with about 150 mL of acetonitrile and about 13 mL hydrochloric acid to create a mixture.

10 . The functionalized silica nanoparticles of claim 9 , wherein the mixture sets for at least about 12 hours and is then centrifuged to provide functionalized silica-nanoparticles in EDTA.

11 . The functionalized silica nanoparticles of claim 1 , wherein the silica nanoparticles have an oval shape.

12 . The functionalized silica nanoparticles of claim 1 , wherein the silica nanoparticles have a size ranging from about 700 nm to about 838 nm.

13 . The functionalized silica nanoparticles of claim 1 , wherein the silica nanoparticles have a diameter ranging from about 361 nm to about 580 nm.

Assignees

• Univ King Saud

Inventors

• Habila Mohamed Abdelaty
• Alobaysi Ahmad Saud Abdullah
• Aljammaz Ibrahim
• Alothman Zeid Abdullah

Classifications

• C22B13/04

  by wet processes · CPC title

• C22B3/24

  by adsorption on solid substances, e.g. by extraction with solid resins · CPC title

• B01J20/3251

  comprising at least two different types of heteroatoms selected from nitrogen, oxygen or sulphur · CPC title

• B01J20/3217

  Resulting in a chemical bond between the coating or impregnating layer and the carrier, support or substrate, e.g. a covalent bond · CPC title

• B01J20/3204

  Inorganic carriers, supports or substrates · CPC title