Method for sterilizing and decontaminating post-consumer absorbent sanitary products polluted with organic compounds derived from human metabolism

Patent metadata

Field	Value
Publication number	US-12533438-B2
Application number	US-202017621729-A
Country	US
Kind code	B2
Filing date	May 20, 2020
Priority date	Jun 25, 2019
Publication date	Jan 27, 2026
Grant date	Jan 27, 2026

Abstract

A method for sterilizing and decontaminating post-consumer absorbent products polluted with organic compounds derived from human metabolism including drug residues, the post-consumer absorbent sanitary products comprising fractions of plastic, super-absorbent polymers (SAP), and optionally cellulose, the method including at least the steps of: sterilizing (SR) the absorbent sanitary post-consumer products by heating to a temperature equal to or less than 140° C., and to a pressure lower than 4 bar, decontaminating (DC) the post-consumer absorbent sanitary products of organic compounds by treating with an oxidizing composition comprising at least one compound selected from the group consisting of hydrogen peroxide, sodium percarbonate, potassium percarbonate, sodium perborate, potassium perborate, potassium monopersulfate, ammonium persulfate, sodium persulfate, potassium persulfate, and ozone. The at least one compound is contained in the oxidizing composition in an amount equal to or greater than 2% by weight with respect to the dry weight of the post-consumer absorbent sanitary products.

First claim

The invention claimed is:

1 . A method for sterilizing and decontaminating post-consumer absorbent sanitary products polluted with organic compounds derived from human metabolism comprising drug residues, said post-consumer absorbent sanitary products containing one or more fractions of plastic, super-absorbent polymers (SAP), and cellulose, the method comprising at least the steps of:
sterilizing (SR) said post-consumer absorbent sanitary products by heating to a temperature equal to or lower than 140° C. and treatment at pressure lower than 4 bar, and decontaminating (DC) said post-consumer absorbent sanitary products of said organic compounds derived human metabolism comprising drug residues by means of treatment with an oxidizing composition, wherein said oxidizing composition is an aqueous solution consisting of hydrogen peroxide and potassium monopersulfate, wherein a weight ratio of hydrogen peroxide: potassium monopersulfate is between 3:1 and 20:1, wherein said hydrogen peroxide and/or potassium monopersulfate is in said oxidizing composition in an amount equal to or greater than 2% by weight with respect to a dry weight of the post-consumer absorbent sanitary products.

2 . The method according to claim 1 , also comprising the step of:
shredding (SH) said post-consumer absorbent sanitary products and obtaining shredded post-consumer absorbent sanitary products having a particle size less than 10 cm.

3 . The method according to claim 2 , further comprising the step of drying (DR) said shredded post-consumer absorbent sanitary products, and obtaining shredded and dried post-consumer absorbent sanitary products containing at least plastic, super-absorbent polymers (SAP) from the group including plastic, super-absorbent polymers (SAP), and cellulose.

4 . The method according to claim 3 , wherein the method also comprises the step of separating plastic from said shredded and dried post-consumer absorbent sanitary products.

5 . The method according to claim 3 , wherein the method also comprises the step of separating cellulose from said shredded and dried post-consumer absorbent sanitary products.

6 . The method according to claim 3 , wherein the method also comprises the step of separating said super-absorbent polymers (SAP) from said shredded and dried post-consumer absorbent sanitary products.

7 . The method according to claim 1 , wherein the step of decontaminating (DC) of organic compounds derived from human metabolism comprising drug residues is carried out by treating the post-consumer absorbent sanitary products with the oxidizing composition simultaneously with the sterilizing step (SR).

8 . The method according to claim 2 , wherein said decontaminating (DC) step is carried out by treating the post-consumer absorbent sanitary products with the oxidizing composition simultaneously with the shredding step (SH).

9 . The method according to claim 3 wherein said decontaminating (DC) step is carried out by treating the shredded post-consumer absorbent sanitary products with said oxidizing composition simultaneously with said drying step (DR).

10 . The method according to claim 1 , wherein the post-consumer absorbent sanitary products are treated with said oxidizing composition at a temperature higher than 50° C.

11 . The method according to claim 1 , wherein said hydrogen peroxide is present in the oxidizing composition in an amount greater than 5% by weight with respect to the dry weight of said post-consumer absorbent sanitary products.

12 . The method according to claim 4 , wherein said decontaminating (DC) step is carried out by treating said plastic and/or said cellulose separated from said shredded and dried post-consumer absorbent sanitary products with said oxidizing composition.

13 . The method according to claim 12 , wherein the hydrogen peroxide and/or potassium monopersulfate is in the oxidizing composition in an amount equal to or greater than 2% by weight with respect to a weight of said plastic and/or cellulose separated from said shredded and dried post-consumer absorbent sanitary products.

14 . The method according to claim 13 , wherein said hydrogen peroxide is present in the oxidizing composition in an amount greater than 5% by weight with respect to the dry weight of said post-consumer absorbent sanitary products.

15 . The method according to claim 1 , wherein said sterilizing step (SR) is carried out by heating said post-consumer absorbent sanitary products to a temperature between 120° C. and 140° C. and to a pressure comprised between 1 and 3.6 bar.

Assignees

• Procter & Gamble

Inventors

• Somma Marcello
• Vaccaro Giorgio
• Pignalosa Giorgio
• D'Alessio Nicola
• Caruso Tonino
• Palombi Laura

Classifications

• C08J2301/02

  Cellulose; Modified cellulose · CPC title

• B29L2031/4878

  Diapers, napkins · CPC title

• B29K2001/00

  Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material · CPC title

• B29B2017/0231

  Centrifugating, cyclones · CPC title

• B29B2017/001

  Pretreating the materials before recovery · CPC title