Photoelectric conversion element

Patent metadata

Field	Value
Publication number	US-12532595-B2
Application number	US-202318323287-A
Country	US
Kind code	B2
Filing date	May 24, 2023
Priority date	May 27, 2022
Publication date	Jan 20, 2026
Grant date	Jan 20, 2026

Abstract

A photoelectric conversion element includes a first electrode, a first interfacial layer, a photoelectric conversion layer, and a second electrode in this order, wherein the photoelectric conversion layer includes quantum dots and a first organic compound, the first organic compound satisfies Formula (1), an electron affinity of a material used for the first interfacial layer, an electron affinity of the quantum dots, and an electron affinity of the first organic compound satisfy Formulas (2) and (3):

E 2> E 1  (1)
E1 [eV]: energy at short-wavelength end of optical wavelength region detected by the photoelectric conversion element E2 [eV]: band gap of the first organic compound

E 3< E 4−0.2  (2)

E 4−0.4< E 5< E 4  (3)
E3 [eV]: electron affinity of material used for the first interfacial layer E4 [eV]: electron affinity of the quantum dots E5 [eV]: electron affinity of the first organic compound.

First claim

What is claimed is:

1 . A photoelectric conversion element comprising:
a first electrode; a first interfacial layer; a photoelectric conversion layer; and a second electrode disposed in this order, wherein the photoelectric conversion layer includes quantum dots and a first organic compound, the first organic compound satisfies Formula (1), and an electron affinity of a material used for the first interfacial layer, an electron affinity of the quantum dots, and an electron affinity of the first organic compound satisfy Formulas (2) and (3):
E 2> E 1  Formula (1)

where E1 (eV) is an energy at a short-wavelength end of an optical wavelength region detected by the photoelectric conversion element, where E2 (eV) is a band gap of the first organic compound,
E 3< E 4−0.2  Formula (2)

E 4−0.4< E 5< E 4  Formula (3)

where E3 (eV) is the electron affinity of the material used for the first interfacial layer, where E4 (eV) is the electron affinity of the quantum dots, and where E5 (eV) is the electron affinity of the first organic compound.

2 . The photoelectric conversion element according to claim 1 , wherein the electron affinity E3 of the material used for the first interfacial layer and the electron affinity E5 of the first organic compound satisfy Formula (4):
E 3> E 5−0.2  Formula (4).

3 . The photoelectric conversion element according to claim 1 , wherein the quantum dots have a band gap of less than 1 eV.

4 . The photoelectric conversion element according to claim 1 , wherein, when the electron affinity E5 of the first organic compound and the electron affinity E4 of the quantum dots satisfy Formula (5), Formula (6) is satisfied:
E 5< E 4−0.2  Formula (5)
μ e org1 >μe QD   Formula (6)
where μe org1 (cm 2 /Vs) is an electron mobility of the first organic compound in the photoelectric conversion layer, and where μe QD (cm 2 /Vs) is an electron mobility of the quantum dots in the photoelectric conversion layer.

5 . The photoelectric conversion element according to claim 1 , wherein the quantum dots include nanoparticles and the nanoparticles contain PbS, PbSe, PbTe, InP, InAs, CdS, CdSe, or CdTe.

6 . The photoelectric conversion element according to claim 1 , wherein the quantum dots include nanoparticles and surfaces of the nanoparticles are coordinated with at least one organic ligand species selected from the group consisting of 1,4-benzenedithiol and 1,3-benzenedithiol.

7 . The photoelectric conversion element according to claim 1 , wherein the quantum dots include nanoparticles and, to surfaces of the nanoparticles, at least one halogen selected from the group consisting of iodine, chlorine, and bromine is added.

8 . The photoelectric conversion element according to claim 1 , wherein the first interfacial layer contains at least one member selected from the group consisting of TiO 2 , ZnO, InGaZnO 4 , MoO 3 , and WO 3 .

9 . The photoelectric conversion element according to claim 1 , wherein the first electrode contains titanium or titanium nitride.

10 . The photoelectric conversion element according to claim 1 , further comprising a second interfacial layer between the photoelectric conversion layer and the second electrode.

11 . The photoelectric conversion element according to claim 10 , wherein the second interfacial layer contains at least one member selected from the group consisting of MoO 3 , NiO, and an organic material including a triarylamine moiety or a fluorene moiety.

12 . The photoelectric conversion element according to claim 10 , wherein a material used for the second interfacial layer and the quantum dots satisfy Formula (7):
μh HTL >μh QD   Formula (7)
where μh HTL (cm 2 /Vs) is a hole mobility of the material used for the second interfacial layer, and where μh QD (cm 2 /Vs) is a hole mobility of the quantum dots in the photoelectric conversion layer.

13 . The photoelectric conversion element according to claim 1 , wherein the first organic compound contains at least one member selected from the group consisting of fullerene derivative, Perylene tetracarboxylic dianhydride derivative, and hexacosa decaene tetrone derivative.

14 . The photoelectric conversion element according to claim 1 , wherein the photoelectric conversion layer further includes a second organic compound.

15 . The photoelectric conversion element according to claim 14 , satisfying Formulas (6) and (8):
μe org1 >μe QD   Formula (6)
μh org2 >μh QD   Formula (8)
where μe org1 (cm 2 /Vs) is an electron mobility of the first organic compound in the photoelectric conversion layer, where μe QD (cm 2 /Vs) is an electron mobility of the quantum dots in the photoelectric conversion layer, where μh org2 (cm 2 /Vs) is a hole mobility of the second organic compound in the photoelectric conversion layer, and where μh QD (cm 2 /Vs) is a hole mobility of the quantum dots in the photoelectric conversion layer.

16 . The photoelectric conversion element according to claim 14 , wherein a concentration of the first organic compound in the photoelectric conversion layer increases to the first interfacial layer, and a concentration of the second organic compound in the photoelectric conversion layer decreases to the first interfacial layer.

17 . The photoelectric conversion element according to claim 14 , wherein a concentration of the first organic compound in the photoelectric conversion layer is constant, and a concentration of the second organic compound in the photoelectric conversion layer decreases to the first interfacial layer.

18 . The photoelectric conversion element according to claim 14 , wherein a concentration of the second organic compound in the photoelectric conversion layer is constant, and a concentration of the first organic compound in the photoelectric conversion layer increases to the first interfacial layer.

19 . The photoelectric conversion element according to claim 14 , wherein the second organic compound contains at least one member selected from the group consisting of the following compounds:

20 . The photoelectric conversion element according to claim 1 , further comprising, on the first electrode or the second electrode, at least one layer selected from the group consisting of a sealing layer, a lens layer, and a color filter layer.

21 . An image sensor comprising a plurality of pixels and a signal processing circuit connected to the pixels, wherein the pixels include the photoelectric conversion element according to claim 1 and a readout circuit connected to the photoelectric conversion element.

22 . A light-receiving element comprising the photoelectric conversion element according to claim 1 , a readout circuit configured to read out charges from the photoelectric conversion element, and a signal processing circuit configured to receive charges from the readout circuit and to perform signal processing.

23 . An image pickup apparatus comprising an optical system including a plurality of lenses and a light-receiving element configured to receive light having been transmitted by the optical system, wherein the light-receiving element includes the photoelectric conversion element according to claim 1 .

24 . A moving object comprising a body including an image pickup apparatus an

Assignees

• Canon Kk

Inventors

• Yamaguchi Tomona

Classifications

• H10K85/30 Primary

  Coordination compounds · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• H10K85/654

  comprising only nitrogen as heteroatom (H10K85/652 takes precedence) · CPC title

• H10K85/615

  Polycyclic condensed aromatic hydrocarbons, e.g. anthracene · CPC title

• H10K85/115

  Polyfluorene; Derivatives thereof · CPC title