Polyfunctional acrylate monomers

Patent metadata

Field	Value
Publication number	US-12528968-B2
Application number	US-202017767160-A
Country	US
Kind code	B2
Filing date	Nov 4, 2020
Priority date	Nov 8, 2019
Publication date	Jan 20, 2026
Grant date	Jan 20, 2026

Abstract

The present disclosure is related to a hydrophilic monomer, comprising (i) at least one amino moiety; (ii) at least one polyoxyalkylene unit; and (iii) at least one (meth)acrylate moiety.

First claim

The invention claimed is:

1 . A hydrophilic monomer, comprising
(i) at least one amino moiety; (ii) at least one polyoxyalkylene unit; and (iii) at least one acrylate moiety, wherein at least one amino moiety is at least one secondary amino moiety and/or at least two tertiary amino moieties.

2 . The hydrophilic monomer according to claim 1 , wherein the at least one polyoxyalkylene unit is selected from polyethers.

3 . The hydrophilic monomer according to claim 1 , wherein the monomer comprises one secondary amino moiety, two secondary amino moieties, three secondary amino moieties, or four secondary amino moieties.

4 . The hydrophilic monomer according to claim 1 , wherein the monomer comprises one tertiary amino moiety, two tertiary amino moieties, three tertiary amino moieties, or four tertiary amino moieties.

5 . The hydrophilic monomer according to claim 1 , wherein the monomer comprises acrylate moieties in an amount of from 1 to 10.

6 . The hydrophilic monomer according to claim 1 , wherein the monomer is a monomer according to any one of formulae (I), (II), (III), (IV), (V), (VI), (VII), or (VIII)

wherein R is a linear or branched alkyl or alkoxy,
wherein m an n may be different or the same,
wherein m and n may each be in a range of from 1 to 100.

7 . The hydrophilic monomer according to claim 1 , wherein the monomer is a monomer according to any one of formulae (IX to XIV) (XI to XIV)

wherein R is a linear or branched alkyl or alkoxy,
wherein m an n may be different or the same,
wherein m and n may each be in a range of from 1 to 100;
wherein x, y, z may be different or the same,
wherein x, y, z may be each in a range of from 1 to 100.

8 . The hydrophilic monomer according to claim 1 , obtained from reacting at least one polyoxyalkylamine with at least one acrylate compound.

9 . The hydrophilic monomer according to claim 8 , wherein the polyoxyalkylmine is a polyetherdiamine comprising ethoxy-units and propyloxy-units.

10 . The hydrophilic monomer according to claim 9 , wherein the ratio of ethoxy-units to propyloxy-units EO:PO is in the range of from 1 to 20.

11 . A process for producing a hydrophilic monomer, comprising reacting at least one polyoxyalkylamine with at least one acrylate compound; wherein the hydrophilic monomer comprises (i) at least one amino moiety; (ii) at least one polyoxyalkyene unit; and (iii) at least one acrylate moiety, wherein the at least one amino moiety isa at least one secondary amino moiety and/or at least two tertiary amino moieties.

12 . The process according to claim 11 , wherein the at least one polyoxyalkylamine is selected from polyetheramines.

13 . The process according to claim 11 , wherein the polyoxyalkylamine exhibits a molecular weight in the range of from 80 g/mol to 8000 g/mol.

14 . Coating obtained from the hydrophilic monomer according to claim 1 by coating hydrophilic monomer onto a substrate and curing the coating by actinic irradiation.

15 . The hydrophilic monomer according to claim 1 , wherein the at least one acrylate compound is selected from alkyldiacrylates, alkyltriacrylates, alkyltetraacrylates, alkylpentaacrylates, alkyl hexaacrylates, polyethylene glycol diacrylates, ethoxylated trimethylolpropane triacrylates, and trimethylolpropane triacrylate.

Assignees

• Solventum Intellectual Properties Company
• Thermo Fisher Bioprocessing Inc

Inventors

• Frost Sven
• Audenaert Frans A
• Nuyts Inge
• Bourgeois Pierre-Alexandre
• De Bondt Maria

Classifications

• C09D135/02

  Homopolymers or copolymers of esters (C09D135/06, C09D135/08 take precedence) · CPC title

• C09D4/00

  Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond {; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16} · CPC title

• C08G65/33303 Primary

  containing amino group · CPC title

• C08F290/062

  Polyethers · CPC title

• C08F283/06

  on to polyethers, polyoxymethylenes or polyacetals {(C08F283/004 takes precedence)} · CPC title