Glass substrate, black matrix substrate, and display panel

Patent metadata

Field	Value
Publication number	US-12528737-B2
Application number	US-202418757697-A
Country	US
Kind code	B2
Filing date	Jun 28, 2024
Priority date	Sep 18, 2018
Publication date	Jan 20, 2026
Grant date	Jan 20, 2026

Abstract

The present invention relates to a glass substrate including a pair of main surfaces and an end surface, and having a surface layer diffusion Sn atom concentration of 2.0×10 18 atomic/cm 3 or more and 1.4×10 19 atomic/cm 3 or less in at least one of the main surfaces, the surface layer diffusion Sn atom concentration being obtained by subtracting an Sn atom concentration of an inside of the glass substrate from an Sn atom concentration of a surface layer of the glass substrate, in which the Sn atom concentration of a surface layer of the glass substrate is defined as an Sn atom concentration at a depth of 0.1 to 0.3 μm from the main surface and the Sn atom concentration of an inside of the glass substrate is defined as an Sn atom concentration at a depth of 9.0 to 9.2 μm from the main surface.

First claim

The invention claimed is:

1 . A glass substrate comprising a pair of main surfaces and an end surface, wherein
the glass substrate has a surface layer diffusion Sn atom concentration of 2.0×10 18 atomic/cm 3 or more and 1.4×10 19 atomic/cm 3 or less in at least one of the main surfaces, the surface layer diffusion Sn atom concentration being obtained by subtracting an Sn atom concentration of an inside of the glass substrate from an Sn atom concentration of a surface layer of the glass substrate, the Sn atom concentration of a surface layer of the glass substrate is defined as an Sn atom concentration at a depth of 0.1 to 0.3 μm from the main surface and the Sn atom concentration of an inside of the glass substrate is defined as an Sn atom concentration at a depth of 9.0 to 9.2 μm from the main surface, the glass substrate has an Sn atom concentration gradient of a surface layer of the glass substrate of −1.0×10 23 atomic/cm 4 or more and −1.0×10 22 atomic/cm 4 or less in the at least one of the main surfaces, the Sn atom concentration gradient of a surface layer of the glass substrate is defined as an inclination of a linear function obtained by linearly approximating a depth profile of an Sn atom concentration (atomic/cm 3 ) at a depth of 0.1 to 0.5 μm from the main surface, and the glass substrate comprises an alkali-free glass comprising, in mol % on an oxide basis: 63 to 69% of SiO 2 ; 10 to 16% of Al 2 O 3 ; 0.5 to 3.5% of B 2 O 3 ; 7 to 13% of MgO; 5 to 10% of CaO; 0.5 to 4% of SrO; 0 to 3% of BaO; and 17 to 22% in total of at least one compound selected from the group consisting of MgQ, CaO, SrO and BaO.

2 . The glass substrate according to claim 1 , comprising an alkali-free glass comprising, in mol % on an oxide basis:
64 to 69% of SiO 2 ; 10 to 15% of Al 2 O 3 ; 1 to 3.5% of B 2 O 3 ; and 7 to 12% of MgO.

3 . The glass substrate according to claim 2 , comprising an alkali-free glass comprising, in mol % on an oxide basis:
65.2 to 66.9% of SiO 2 ; 10.8 to 13.5% of Al 2 O 3 ; 1.2 to 3.5% of B 2 O 3 ; ]to 12% of MgO; and 5 to 9.7% of CaO.

4 . The glass substrate according to claim 3 , wherein the alkali-free glass has a strain point of 650° C. or higher, and an average thermal expansion coefficient at 50 to 350° C. of 30×10 −7 to 45×10 −7 /° C.

5 . The glass substrate according to claim 3 , wherein the alkali-free glass has a content of alkali metal oxides of 0.5% or lower, in mol % on an oxide basis.

6 . The glass substrate according to claim 3 , being produced by a float process.

7 . The glass substrate according to claim 3 , wherein the at least one of the main surfaces is a polished surface formed by polishing.

8 . The glass substrate according to claim 7 , wherein the polished surface has an Stdi value of 0.75 or less, the Stdi value is a texture-direction index obtained with an observation visual field of 1 μm×1 μm and the number of pixels of 256×256 by an AFM (Atomic Force Microscopy).

9 . A black matrix substrate comprising the glass substrate according to claim 3 , and a black matrix film formed on at least one of the main surfaces of the glass substrate.

10 . A display panel comprising the black matrix substrate according to claim 9 .

Assignees

• Agc Inc

Inventors

• Tokunaga Hirofumi
• Kobayashi Daisuke
• Ono Kazutaka
• Takenaka Atsuyoshi
• Maeyanagi Yoshitaka

Classifications

• G02F1/133512

  Light shielding layers, e.g. black matrix (G02F1/136209 takes precedence) · CPC title

• C03C2203/10

  Melting processes · CPC title

• C03C19/00

  Surface treatment of glass, not in the form of fibres or filaments, by mechanical means (sand-blasting, grinding, or polishing glass B24) · CPC title

• C03C17/009

  Mixtures of organic and inorganic materials, e.g. ormosils and ormocers · CPC title

• C03C3/091 Primary

  containing aluminium · CPC title