Heat-sensitive recording body

Patent metadata

Field	Value
Publication number	US-12528307-B2
Application number	US-202118032509-A
Country	US
Kind code	B2
Filing date	Oct 19, 2021
Priority date	Oct 20, 2020
Publication date	Jan 20, 2026
Grant date	Jan 20, 2026

Abstract

Disclosed is a heat-sensitive recording material comprising an undercoat layer and a heat-sensitive recording layer in this order on a support,
the undercoat layer containing hollow particles, a binder, and an inorganic pigment I, the heat-sensitive recording layer containing a leuco dye, a developer, and an inorganic pigment II, and the heat-sensitive recording layer containing an N,N′-diarylurea-based compound represented by the following formula (1):

wherein R 2 s may be the same or different, and each represents C 1-12 alkyl, C 7-12 aralkyl, or C 6-12 aryl, and the aralkyl and the aryl may be each substituted with C 1-12 alkyl, C 1-12 alkoxy, C 6-12 aryl, or halogen; A 1 s may be the same or different, and each represents hydrogen or C 1-4 alkyl, as the developer, and a pigment with an oil absorption of 130 ml/100 g or less as the inorganic pigment II.

First claim

The invention claimed is:

1 . A heat-sensitive recording material comprising an undercoat layer and a heat-sensitive recording layer in this order on a support,
the undercoat layer containing hollow particles, a binder, and an inorganic pigment I, the heat-sensitive recording layer containing a leuco dye, a developer, and an inorganic pigment II, and the heat-sensitive recording layer containing an N,N′-diarylurea-based compound represented by the following formula (1):

wherein R 2 s may be the same or different, and each represents C 1-12 alkyl, C 7-12 aralkyl, or C 6-12 aryl, and the aralkyl and the aryl may be each substituted with C 1-12 alkyl, C 1-12 alkoxy, C 6-12 aryl, or halogen; Ais may be the same or different, and each represents hydrogen or C 1-4 alkyl, as the developer, and a pigment with an oil absorption of 130 ml/100 g or less as the inorganic pigment II,
wherein the heat-sensitive recording layer further contains, as a second developer,
4,4′-bis(3-tosylureido)diphenylmethane.

2 . The heat-sensitive recording material according to claim 1 , wherein the inorganic pigment I has an oil absorption of 130 ml/100 g or less.

3 . The heat-sensitive recording material according to claim 1 , wherein the inorganic pigment II is at least one member selected from the group consisting of calcium carbonate, aluminum hydroxide, and clay.

4 . The heat-sensitive recording material according to claim 1 , wherein the hollow particles have a maximum particle diameter D100 of 10 to 40 μm and an average particle diameter D50 of 4.0 to 15 μm, the ratio of the maximum particle diameter D100 to the average particle diameter D50, i.e., D100/D50, is 1.8 to 3.0, and the volume % of particles with a particle diameter of 2.0 μm or less is 1% or less.

5 . The heat-sensitive recording material according to claim 1 , wherein the hollow particles have a hollow ratio of 80 to 98%.

6 . The heat-sensitive recording material according to claim 1 , wherein the binder of the undercoat layer has a glass transition temperature of −10° C. or less.

7 . The heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording layer further contains, as an additional developer, at least one member selected from the group consisting of a urea-urethane compound represented by the following formula (2);

and a crosslinked diphenylsulfone compound represented by the following formula (3):

wherein n represents an integer of 1 to 6.

8 . The heat-sensitive recording material according to claim 1 , wherein the content of the second developer is 0.2 to 3 parts by mass, per part by mass of the leuco dye.

9 . The heat-sensitive recording material according to claim 1 , wherein the N,N′-diarylurea-based compound represented by formula (1) is at least one member selected from the group consisting of N,N′-di-[3-(p-toluenesulfonyloxy)phenyl]urea, N,N′-di-[3-(o-toluenesulfonyloxy)phenyl]urea, N,N′-di-[3-(benzenesulfonyloxy)phenyl]urea, N,N′-di-[3-(mesitylenesulfonyloxy)phenyl]urea, N,N′-di-[3-(4-ethylbenzenesulfonyloxy)phenyl]urea, N,N′-di-[3-(2-naphthalenesulfonyloxy)phenyl]urea, N,N′-di-[3-(p-methoxybenzenesulfonyloxy)phenyl]urea, N,N′-di-[3-(benzylsulfonyloxy)phenyl]urea, N,N′-di-[3-(ethanesulfonyloxy)phenyl]urea, N,N′-di-[3-(p-toluenesulfonyloxy)-4-methyl-phenyl]urea, N,N′-di-[4-(p-toluenesulfonyloxy)phenyl]urea, N,N′-di-[4-(benzenesulfonyloxy)phenyl]urea, N,N′-di-[4-(ethanesulfonyloxy)phenyl]urea, and N,N′-di-[2-(p-toluenesulfonyloxy)phenyl]urea.

10 . The heat-sensitive recording material according to claim 1 , wherein the heat-sensitive recording material further comprises an adhesive layer on at least one surface of the support.

11 . The heat-sensitive recording material according to claim 1 , wherein the content of the inorganic pigment I is 50 mass % or less, based on the total solids content of the undercoat layer.

Assignees

• Oji Holdings Corp

Inventors

• Takemura Takashi
• Sugiyama Naonobu
• Watanabe Daiki

Classifications

• B41M5/426

  characterised by inorganic compounds, e.g. metals, metal salts, metal complexes · CPC title

• B41M5/44

  characterised by the macromolecular compounds · CPC title

• B41M2205/38

  Intermediate layers; Layers between substrate and imaging layer · CPC title

• B41M5/42 Primary

  Intermediate, {backcoat}, or covering layers {(B41M5/405 takes precedence; multilayer thermal transfer systems in general B41M5/38214)} · CPC title

• B41M2205/04

  Direct thermal recording [DTR] · CPC title