Methods of making sintered articles
US-11065862-B2 · Jul 20, 2021 · US
US12528126B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-12528126-B2 |
| Application number | US-202017786278-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 11, 2020 |
| Priority date | Dec 17, 2019 |
| Publication date | Jan 20, 2026 |
| Grant date | Jan 20, 2026 |
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In one aspect, additive manufacture techniques are described herein which enable the densification of green articles prior to further article processing. In some embodiments, a method of forming an article comprises providing a powder composition, and forming the powder composition into a green article by one or more additive manufacturing techniques. The green article is contacted with a powder pressure transfer media. The green article and powder pressure transfer media are then subjected to cold isostatic pressing (CIP) or warm isostatic pressing (WIP) at a pressure less than minimum isostatic compaction pressure of the powder pressure transfer media to provide a densified green article.
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The invention claimed is: 1 . A method of forming an article comprising: providing a powder composition, and forming the powder composition into a green article by one or more additive manufacturing techniques; contacting the green article with a powder pressure transfer media that comprises an elastomeric powder and a metal powder, an alloy powder, a ceramic powder, a polymeric powder, an ionomer powder, or mixtures thereof, wherein the powder pressure transfer media has a polydisperse, bimodal, or multi-modal particle size distribution; and subjecting the green article and powder pressure transfer media to cold isostatic pressing (CIP) or warm isostatic pressing (WIP) at a pressure less than minimum isostatic compaction pressure of the powder pressure transfer media to provide a densified green article, wherein CIP is performed at temperatures less than 25° C., and WIP is performed at temperatures of 25° C. to 250° C. 2 . The method of claim 1 , wherein the densified green article is greater than 55 percent theoretical density. 3 . The method of claim 1 , wherein the densified green article is 60-69 percent theoretical density. 4 . The method of claim 1 , wherein the powder composition comprises sintered cemented carbide particles. 5 . The method of claim 1 , wherein the powder composition comprises cobalt alloy. 6 . The method of claim 1 , wherein the green article is produced by binder jetting. 7 . The method of claim 1 , wherein the powder pressure transfer media has a modulus of at least 200 GPa. 8 . The method of claim 1 , wherein the powder pressure transfer media has a modulus of 200-800 GPa. 9 . The method of claim 1 , wherein the pressure is at least 5 ksi less than the minimum isostatic compaction pressure of the powder pressure transfer media. 10 . The method of claim 1 , wherein the pressure is 5-60 ksi. 11 . The method of claim 1 , wherein the powder pressure transfer media has an average particle size of 10-200 μm. 12 . The method of claim 1 , wherein the powder pressure transfer media forms a compact during the CIP or WIP having a crush strength less than 80 pound force (lbf). 13 . The method of claim 12 , wherein a ratio of crush strength of the compact to crush 10 strength of the densified green article is less than 0.2. 14 . The method of claim 13 , wherein the ratio is 0.001 to 0.15. 15 . The method of claim 1 further comprising separating the densified green article from the powder pressure transfer media. 16 . The method of claim 1 , wherein a modulus ratio of the powder composition to the powder pressure transfer media is 0.5 to 1.5. 17 . The method of claim 15 , wherein at least a portion of the powder pressure transfer media remains in a flowable state after CIP. 18 . The method of claim 1 , wherein the powder pressure transfer media comprises a ceramic, an alloy or mixtures thereof. 19 . The method of claim 1 , wherein the powder pressure transfer media comprises an elastomeric powder and a metal powder. 20 . The method of claim 15 further comprising sintering the densified green article to provide a sintered article. 21 . The method of claim 20 , wherein the sintered article is at least 98 percent theoretical density. 22 . The method of claim 20 , wherein the sintered article is at least 99 percent theoretical density.
based on tungsten carbide · CPC title
Carbide · CPC title
Nickel or cobalt · CPC title
by warm compacting, below debindering temperature · CPC title
simultaneously · CPC title
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